• Title/Summary/Keyword: ${Er_2}{O_3}$

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Structural and Optical Properties of Er(III) Complex with ODA and Phen (ODA = Oxydiacetate, Phen = 1,10-Phenanthroline)

  • Kang, Jun-Gill;Kim, Tack-Jin;Park, Kwan-Soo;Kang, Sung-Kwon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.3
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    • pp.373-376
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    • 2004
  • A novel Er(III) complex with oxydiacetate and 1,10-phenanthroline was synthesized and its structure and luminescence properties were characterized. The complex of $[Er(ODA){\cdot}(phen){\cdot}4H_2O]^+$ crystallizes in the monoclinic space group $P2_1$/n with a = 12.216(4) ${\AA}$, b = 16.680(2) ${\AA}$, c = 12.627(3) ${\AA}$, ${\beta}=108.30(2)^{\circ}$, V = 2442.7(11) ${\AA}^3$, Z = 4 and ${\rho}=1.841 g/cm^3$. When the complex is excited at the He-Cd 325-nm line, it produces two broad bands spanning the regions 350-650 nm and 1200-1650 nm. The emission band of the complex is characterized by a series of spectral dips in the visible emission profile. The complex exhibits sensitized near- IR emission via two kinds of energy transfers from phen to Er(III): nonradiative and radiative energy transfers.

Electrical and Dielectric Characteristics of Zn-Pr-Co-Er-M(M=Ni, Mg, Cr) Oxides-Based Varistors (Zn-Pr-Co-Er-M(M=Ni, Mg, Cr)산화물계 바리스터의 전기적, 유전적 특성)

  • 남춘우;김명준
    • Journal of the Korean Ceramic Society
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    • v.41 no.8
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    • pp.605-609
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    • 2004
  • The microstructure, electrical and dielectric characteristics of ZnO varistors were investigated at various metal oxide (NiO, MgO, and Cr$_2$O$_3$) additives. The average grain size was increased with addition of NiO while that was decreased with addition of Cr$_2$O$_3$-Thereby, the varistor voltage was higher in Cr$_2$O$_3$-added composition. Among varistors, the varistor added with Cr$_2$O$_3$ exhibited the highest nonlinearity, with 40.5 in the nonlinear exponent and 2.7 ${\mu}$A in the leakage current and its dielectric dissipation factor was relatively low value of 0.0589.

Electrical Properties and Temperature Stability of Dysprosium and Erbium Co-doped Barium Titanate with Perovskite Structure for X7R MLCCs (Dysprosium과 Erbium이 동시 첨가된 X7R MLCC용 페로브스카이트 BaTiO3의 전기적특성과 온도안정성)

  • Noh, Tai-Min;Kim, Jin-Seong;Ryu, Ji-Seung;Lee, Hee-Soo
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.323-327
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    • 2011
  • The effects of $Dy_2O_3$ and $Er_2O_3$ co-doping on electrical properties and temperature stability of barium titanate ($BaTiO_3$) ceramics were investigated in terms of microstructure and structural analysis. The dielectric constant and the insulation resistance (IR) of 0.7 mol% $Dy_2O_3$ and 0.3 mol% $Er_2O_3$ co-doped dielectrics had about 60% and 20% higher than the values of undoped one, respectively, and the temperature coefficient of capacitance (TCC) met the X7R specification. The addition of $Dy_2O_3$ contributed to electrical properties caused by increase of tetragonality; however, preferential diffusion of $Dy^{3+}$ ions toward A site in $BaTiO_3$ grain exhibited an adverse effect on temperature stability by grain growth. On the other hand, The $Er_2O_3$ addition in $BaTiO_3$ could affect the TCC behavior and the IR with suppression of grain growth caused by reinforcement of grain boundary and electrical compensation. Therefore, the enhanced electrical properties and temperature stability through the co-doping could be deduced from the increase of tetragonality and the suppression of grain growth.

Crystal Growth and Spectroscopic Investigation of Yb,Er:$YCa_4O{(BO_3)}_3$ for 1.55$\mu m$ Laser

  • Jeong, Suk-Jong;Yu, Young-Moon
    • Proceedings of the Optical Society of Korea Conference
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    • 1999.08a
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    • pp.220-221
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    • 1999
  • Single crystals of Yttrium Calcium Oxyborate (YCOB) doped with different concentrations of Er3+ and Yb3+ ions were growth by Czochralski method. High qualities of crystals in morphology and transparency were obtained . Analysis on crystal structure and lattice parameters were performed by X-ray diffraction method. It was found that congruent melting composition is YCA4.2O1.2(BO3)3. Absorption and fluorescence properties of grown crystals were also reported.

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Mechanical Properties of Hot-Pressed SiC with Rare-Earth Oxide (희토류 산화물을 첨가한 일축가압소결 탄화규소의 기계적 특성)

  • 최철호;이충선;박광자;조덕호;김영욱
    • Journal of the Korean Ceramic Society
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    • v.37 no.2
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    • pp.158-163
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    • 2000
  • Six different SiC ceramics with SiO2-Re2O3 (Re=Yb, Er, Y, Dy, Gd, Sm) as sintering additives have been fabricated by hot-pressing the SiC-Re2Si2O7 compositions at 1850$^{\circ}C$ for 2 hr under a pressure of 25 MPa. The room temperature strneth and the fracture toughness of the hot-pressed ceramics were characterized and compared with those of the ceramics sintered with YAG (Y3Al5O12). Five SiC ceramics (Re=Yb, Er, Y, Dy, Gd) investigated herein showed sintered densities higher than 94% of theoretical. Tthe SiC-Re2Si2O7 compositions showed lower strength and comparable toughness to those from SiC-YAG composition, owing to the chemical reaction between SiO2 and SiC during sintering. SiC ceramics fabricated from a SiC-Y2Si2O7 composition showed the best mechanical properties of 490 MPa and 4.8 MPa$.$m1/2 among the compositions investigated herein.

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Crystal Growth and Color Centers of Yttria Stabilized Cubic Zirconia(YSCZ) Single Crystals (Yttria Stabilized Cubic Zirconia(YSCZ) 단결정의 결정성장과 Color Centers)

  • 정대식;오근호
    • Journal of the Korean Ceramic Society
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    • v.29 no.11
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    • pp.851-854
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    • 1992
  • It was grown ZrO2:10 mol% Y2O3 single crystals doped with 1 wt% of rare earth metal ion (Ce, Pr, Nd, Er, Eu) by Skull Method. Grown crystals showed Ce:orange-red, Pr:golden-yellow, Nd:lilac, Er:pink, Eu:light pink due to dopant effect. It was examined color centers in light absorption pattern of visible region (λ= 300~700 nm); in as grown samples, absorption by Ce4+, (Pr4+, Pr3+), Nd3+, Er3+, Eu3+ ions were important, and in samples after vacuum annealing, decrease of absorption by Pr4+ ion and increase of absorption by Pr3+ ion was important, and absorption by Ce3+, Eu2+ was important due to reduction of activator.

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