• 한국동물학회:학술대회논문집
• /
• 한국동물학회 1999년도 한국생물과학협회 학술발표대회
• /
• pp.226.1-226
• /
• 1999

No Abstract, See Full Text

• 한국식물병리학회:학술대회논문집
• /
• 한국식물병리학회 2003년도 정기총회 및 추계학술발표회
• /
• pp.100.2-101
• /
• 2003

The global regulator, GacS (global antibiotic and cyanide sensor kinase), was required for the increased resistance to hydrogen peroxide occurring as cultures of the rhizobacterium, P. chlororaphis O6, matured. Specific stationary-phase peroxidase and catalase isozymes were absent in the GacS mutant, whereas a manganese-superoxide dismutase isozyme was expressed earlier and to a great extent than wild type. In the wild type cell, transcript accumulation of rpoS was higher in late logarithmic-phase cells than cells from mid logarithmic- or stationary-phase. Transcripts from rpoS in the GacS mutant were reduced in each of these growth phases compared to the wild type expression. The down stream sequence from rpoS lacked sequences encoding a small RNA, rsmZ, found in other pseudomonads and implicated in control of genes activated by the GacS system. These findings suggest that GacS-mediated regulation of RpoS plays role in control of oxidative stress in P. chlororaphis O6 by as yet an unknown mechanism.

• Bulletin of the Korean Chemical Society
• /
• 제33권11호
• /
• pp.3607-3617
• /
• 2012

In this paper, the study of various ortho- and meta-substituted Magnolol derivatives is presented. The reaction enthalpies related to three antioxidant action mechanisms HAT, SET-PT and SPLET for substituted Magnolols have been calculated using DFT/B3LYP method in gas-phase and water. Calculated results show that electron-withdrawing substituents increase the bond dissociation enthalpy (BDE), ionization potential (IP) and oxidation/reduction enthalpy (O/RE), while electron-donating ones cause a rise in the proton dissociation enthalpy (PDE) and proton affinity (PA). In ortho- position, substituents show larger effect on reaction enthalpies than in meta-position. In comparison to gas-phase, water attenuates the substituent effect on all reaction enthalpies. In gas-phase, BDEs are lower than PAs and IPs, i.e. HAT represents the thermodynamically preferred pathway. On the other hand, SPLET mechanism represents the thermodynamically favored process in water. Results show that calculated enthalpies can be successfully correlated with Hammett constants (${\sigma}_m$) of the substituted Magnolols. Furthermore, calculated IP and PA values for substituted Magnolols show linear dependence on the energy of the highest occupied molecular orbital ($E_{HOMO}$).

• 대한화학회지
• /
• 제37권5호
• /
• pp.503-512
• /
• 1993

역상 액체 크로마토그래피를 이용하여 페놀류를 효과적으로 분리-분석하는데 기본적으로 필요한 용리거동을 조사하고, 이를 바탕으로 머무름을 예측하는데 이 연구의 목적을 두었다. 정지상으로는 monomeric $C_{18}$ 컬럼($\mu-{Bondapak}$)과 polymeric $C_{18}$ 컬럼(201TP)을 사용하여 상호 비교하였으며, 이동상으로는 메탄올-물과 아세토니트릴-물 혼합액을 사용하고, 대상물질로는 25종의 페놀류를 선택하였다. 엔탈피-엔트로피 상쇄현상을 조사하였을 때 nitrophenols의 머무름은 이동상에 관계없이 methylphenols와 chlorophenols의 머무름과는 달랐으며, 메탄올-물 이동상에서 methylphenols와 chlorophenols는 상쇄현상이 있기 때문에 그 머무름 메카니즘은 조성과 관계없이 일정하였고, 아세토니트릴-물에서는 머무름 메카니즘이 더욱 복잡함을 알았다. Monomeric $C_{18}$ 컬럼과 polymeric $C_{18}$ 컬럼에서의 페놀류의 머무름을 비교하였을 때, polymeric $C_{18}$ 컬럼에서 정지상과 시료의 소수성 상호작용이 더 큼을 알 수 있었다. 메탄올-물 및 아세토니트릴-물 계에서 이동상의 조성 및 컬럼 온도가 변화할 때 쉽게 계산할 수 있는 $\pi$와 ${\sigma}+E_s$ 파라미터를 이용하여 페놀류의 머무름을 예측할 수 있는 관계식을 구하였다.

• 대한화학회지
• /
• 제33권3호
• /
• pp.326-331
• /
• 1989

Sol-gel법으로 고온 초전도체인 $YBa_2Cu_3O_{7-{\sigma}}$의 세선을 제작하였다. Y, Ba, Cu 질산염을 1:2:3의 몰비로 수용액을 제조한 후 구연산 수용액을 첨가하고, 암모니아 수용액을 첨가하여 pH를 $5.8{\sim}6.2$로 조절함으로써 균일한 colloid sol을 제조할 수 있었다. 이를 358K 로 가열하면 점차 점도가 증가하면서 gel화 반응이 진행되고 이 gel화 반응이 완결되기 전에 구연산염 precursor gel fiber를 임의의 길이 및 두께로 뽑을 수 있었다. 이 precursor를 1223K, $Po_2$=1atm. 하에서 8시간 열처리한 후 723K로 서냉하고 13시간 동안 annealing 하여 약 95K에서 전기저항이 급격히 감소($T_c$, onset), 약 82K에서는 저항 0($T_c$, offset)을 나타내었고 액체질소 비등점에서 Meissner-effect를 보임으로써 초전도체 임을 확인하였다.

• International Journal of Fluid Machinery and Systems
• /
• 제4권1호
• /
• pp.140-149
• /
• 2011

For a certain operating point of a horizontal shaft bulb turbine (i.e. volume flow, net head, blade angle, guide vane angle) the efficiency for different pressure levels (i.e. different Thoma-coefficient ${\sigma}$) is calculated using a commercial Computational Fluid Dynamics (CFD-)-code including two-phase flow and a cavitation model. The results are compared with experimental results achieved at a closed loop test rig for model turbines. The comparison of the experimentally and numerically obtained efficiency and the visual impression of the cavitation show a good agreement. Especially the drop in efficiency is calculated with satisfying accuracy. This drop in efficiency in combination with the visual impression is of high practical importance since it contributes to determine the admissible cavitation in a bulb-turbine. It is seen that the incipient cavitation in Kaplan type turbines has no major importance in determing this admissible amount of cavitation.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2003년도 학술회의 논문집 정보 및 제어부문 B
• /
• pp.890-893
• /
• 2003

In this paper, we have designed the fractional-N frequency synthesizer for bluetooth system using 0.35-um CMOS technology and 3.3-V single power supply. The designed synthesizer consist of phase-frequency detector (PFD), charge pump, loop filter, voltage controlled oscillator (VCO), frequency divider, and sigma-delta modulator. A dead zone free PFD is used and a modified charge pump having active cascode transistors is used. A Multi-modulus prescaler having CML D flip-flop is used and VCO having a tuning range from 746 MHz to 2.632 GHz at 3.3 V power supply is used. Total power dissipation is 32 mW and phase noise is -118 dBc/Hz at 1 MHz offset.

• Bulletin of the Korean Chemical Society
• /
• 제21권8호
• /
• pp.823-827
• /
• 2000

Gas-Phase reactions of methyl and ethyl nitrites with anionic nucleophiles of SH-, F- and OH- are investigated theoretically at the MP2/6-311+G* level. The SN2 processes are all highly exothermic and proceed with a typ-icaI double-weIl reaction coordinate profile. The elimination reactions of methyl nitrite with SH- and F- are double-well energy surface processes,with stabilizedproduct complexes of NO-...H2S and NO-...HF, pro-ceeding by an E1 cb-like E2 mechanism. The $\beta-elimination$ of ethyl nitrite is an E2 type process. The $\alpha-elimi-nation$ reactions of methyl and ethyl nitrites with OH- have triple-well energy profiles of Elcb pathway with an $\alpha-carbanion$ intermediate which is stabilized bythe vicinal $nc\alpha-{\sigma}*o-N$ charge transfer interactions. CompIex-ation ofmethyl carbanion with HF seems to provide a stable intermediate within a triple-well energy profile of El cb channel in the reaction of F- with methyl nitrite.

• Bulletin of the Korean Chemical Society
• /
• 제12권6호
• /
• pp.658-661
• /
• 1991

The gas-phase nucleophilic substitution reaction of pentafluoroanisole with $OH^-$ and ${NH_2}^-$ nucleophiles have been studied theoretically using the AM1 method. Three reaction channels, $S_N2$, IPSO and $S_NAr$ (scheme 1), are all very exothermic so that all are accessible despite the varying central energy barriers which are much lower than the reactants level. In the IPSO and $S_NAr$ channels, the reactants form directly a stable ,${\sigma}$-anion complex which proceeds to form a proton transfer complex via a transition barrier corresponding to a loose ${\pi}$-type complex with the F-(or ${OCH_3}^-$) leaving group. Due to a greater number of probable reaction sites available for $S_NAr$ compared to the other two processes, the $S_NAr$ channel is favored as experimentally observed.

• 한국양식학회지
• /
• 제7권4호
• /
• pp.239-249
• /
• 1994

본 연구는 수질관리를 위한 양식장 순환수 처리를 위하여 유동층공법을 이용할 시, 수리학적 모델인자를 결정하기 위하여 반응기의 혼합특성과 산소전달 특성을 파악하는 연구이다. 삼상유동층 반응기의 dye test에서 얻은 결과 분산$(\sigma^2)$, 분산수 $(D/{\mu}L)$를 살펴보면 분산은 0.47이상이고 분산수는$0.35\~\infty$로 높은분산상태를 나타내는 이상적인 완전혼합반응기로 판단된다. 총괄산소전달계수 값을 측정한 결과 공기주입율이 클수록, 메디아농도가 작을수록, 메디아 입경크기가 작을수록 큰 값을 나타내었다. 총괄산소전달계수$(K_{La})$가 반응조 직경과 draft tube 직경비, 공기주입율, 메디아 농도, 메디아 입경크기에 따른 의존성을 파악하면 아래와 같이 표현된다. $$K_{La}\;=\;44.9(D_i/D_c)^{-0.4611}\;A_f^{0.8622}\;C_m^{-0.0746}\;d_p^{-0.4302}$$