• 한국세라믹학회지
• /
• 제31권12호
• /
• pp.1501-1506
• /
• 1994

The precipitate of FeCl2.4H2O and NaOH, Fe(OH)2 was rapidly made to oxidize by H2O2 to prepare $\delta$-FeOOH. The particle size, surface and morphology of $\delta$-FeOOH, and the shape and structure of thermally decomposed $\delta$-FeOOH were investigated by the use of high resolution STEM. $\delta$-FeOOH prepared under the condition of reaction temperature of Fe(OH)2 at 4$0^{\circ}C$, [OH-][Fe2+]=5 and aging time of 2 hr Fe(OH)2, had 630$\AA$ mean particle size, 4~5 aspect ratio, 20.8 emu/g saturation magnetization and 210 Oe coercivity. The edges of $\delta$-FeOOH were inclined to (001) about 41$^{\circ}$, 60$^{\circ}$ and coincident with (102), (101) respectively. When $\delta$-FeOOH was thermally decomposed at 25$0^{\circ}C$ for 2 hr in vacuo, which had micropores of 0.9 nm thickness and crystallites of 2.4 nm thickness. (001)hex, [10]hex. of $\delta$-FeOOH parallel with (001)hex, [100]hex. of $\alpha$-Fe2O3 respectively. This showed three dimensional topotaxial structure transition, which was investigated by SADP (Selected Area Diffraction Pattern) of STEM.

• Bulletin of the Korean Chemical Society
• /
• 제12권6호
• /
• pp.604-606
• /
• 1991

From O-glucuronyl trichloroacetimidate (4) and ${\Delta}^6$-tetrahydrocannabinol (5), the C-glucuronide of ${\Delta}^6-tetrahydrocannabinol({\Delta}^6-THC)$ (7) was obtained using mild Lewis acid catalysis. The known method for the synthesis of C-glucuronide from 1-O-unprotected glucuronide provided low chemical yields. The C-glucuronide of ${\Delta}^6-THC$ was obtained through inversion of configuration at the anomeric center in O-glucuronyl trichloroacetimidate (4).

• 한국정보처리학회논문지
• /
• 제5권11호
• /
• pp.2835-2844
• /
• 1998

대부분의 데이터 병렬 언어들은 배열을 분배하는 방법을 제공하고 있다. 이들 중 블록-순환(block-cyclic) 분배가 가장일반적인 데이터 방법이다. 블록-순환 형태로 분할된 배열 구간 A(l:h:s) 중 각 프로세서가 자신의 메모리 영역에서 접근하는 A의 지역주소를 컴파일러 또는 실시간 시스템들이 생성하는 방안에 대한 연구가 이루어지고 있다. 이 논문에서는 블록-순환 분배된 배열에 대한 두 가지 지역 주소 생성 방법을 제안한다. 하나는 가상-블록 (virtual-block)을 변형한 simple scan 방법이고, 다른 하나는 지역 메모리 접근에 대한 정보를 포함하는 ${\Delta}M$테이블을 선형시간에 생성하는 알고리즘이다. ${\Delta}M$테이블 생성과 각 프로세서가 10,000개의 지역배열 원소를 접근하는데 소요된 시간을 측정하는 실험을 하였다. 실험결과 simple scan 방법은 성능이 좋지 못하였다. 하지만 ${\Delta}M$테이블을 구성하는 다른 방법들 보다 빠른 시간에 수행이 완료되었다.

• 한국농공학회:학술대회논문집
• /
• 한국농공학회 2000년도 학술발표회 발표논문집
• /
• pp.513-518
• /
• 2000

It has been acknowledged that fertilizer, natural soil nitrogen and animal waste, municipal waste have different mass ratio of nitrogen which is presented as a symbol of $\delta^{15}$N. and that the values of $\delta^{15}$N for fertilizer and natural soil nitrogen and animal waste are placed less than +5$\textperthousand$ and higher than +10$\textperthousand$, respectively. thus, Nitrogen pollution sources and contribution can be interpreted in watershed through $\delta^{15}$N analysis and then, analysis is performed with Kjeldhl-Dumas method. In this study, The values of $\delta^{15}$N are between +1.46$\textperthousand$ and +8.97$\textperthousand$, and the nitrate concentration is placed less than 3.31mg/L and higher than 0.19mg/L, respectively. Thus, this watershed is noncontamination area at the present time. But as a result of $\delta^{15}$N, contribution of natural soil nitrogen be discovered in this watershed, presently.

• 한국응용과학기술학회지
• /
• 제10권1호
• /
• pp.57-65
• /
• 1993

The fatty acid, all $cis-{\Delta}^{5,11,14}-C_{20:3}$, in the Gingko nuts oils, was isolated and, purified by urea-adduct method, silver ion silica gel chromatography and HPLC equipped with reversed phase ${\mu}-Bondapak$ $C_{18}$ column. Its structural elucidation was conducted by IR and $^1H$-, $^{13}C$-NMR technique. The fatty acid composition of seed oils mainly consists of linoleic acid(37.73%), vaccenic acid(18.30%), oleic acid(15.18%), palmitic acid(3.37%), palmitoleic acid(3.37%) and ${\Delta}^5$ NMDB fatty acids(8.50%) in which all $cis-{\Delta}^{5,11,14}-C_{20:2}$ predominates.

• 멤브레인
• /
• 제21권4호
• /
• pp.321-328
• /
• 2011

$PrBa_{0.9}Sr_{0.1}Co_2O_{5+{\delta}}$ 조성의 산화물을 고상반응법을 이용하여 합성하였다. 합성된 분말은 압축 성형 후 $1,250^{\circ}C$에서 소결하여 치밀한 세라믹 분리막을 제조하였다. 제조된 $PrBa_{0.9}Sr_{0.1}Co_2O_{5+{\delta}}$분리막은 XRD분석 결과 이중 페롭스카이트 (double perovskite)구조를 보였다. 밀봉재료로는 pyrex ring을 사용하여 가스누출 실험 및 산소투과 분석을 하였다. 산소투과량 분석은 $850{\sim}950^{\circ}C$범위에서 측정되었다. 산소투과실험 결과, 투과량은 온도증가에 따라 0.15에서 $0.32mL/cm^2{\cdot}min$로 증가하였다.

• 산업기술연구
• /
• 제18권
• /
• pp.195-202
• /
• 1998

The effect of the number of nodes on the heat loss from a rectangular fin for a finite difference method is studied. There are two ways for selecting nodes for the upper half fin in this finite difference method. In the first place, all the ${\Delta}x$ are the same and all the ${\Delta}y$ are the same for the entire upper half fin. Incremental length of x (i.e. ${\Delta}x$) is divided by two near the fin tip while all the ${\Delta}y$ are the same for another way. The results show that 1) About 30 nodes are enough to obtain the satisfactory exact analysis (relative error < 5%) on the heat loss for a given range of Biot number in case of short fin (i.e. $L{\leq}2$). 2) Under usual circumstances (Bi<0.1), the relative error of heat loss between using 30 nodes and 90 nodes is within 4% for given range of non-dimensional fin length. 3) The relative error of the calculated heat loss (the number of node=90) as compared to the expected exact heat loss is less then 1.5% for Bi=0.1 and L=10 while that is over 13% for Bi=1.0 and L=10.

• 전기화학회지
• /
• 제4권1호
• /
• pp.14-20
• /
• 2001

단결정 Pt(100)/0.5M $H_2SO_4$ 및 0.5M LiOH수용액 계면에서 저전위 수소흡착(UPD H)과 과전위 수소흡착(OPD H)에 관한 Langmuir흡착등온식을 위상이동 방법을 이용하여 연구 조사하였다. 최적 중간주파수에서 위상이동 변화$({-\varphi}\;vs.\;E)$는 Langmuir흡착등온식$(\theta\;vs.\;E)$의 추정에 적용할 수 있는 유용한 실험 방법이다. 단결정 Pt(100)/0.5M $H_2SO_4$ 수용액 계면에서 과전위 수소흡착에 기인한 흡착평형상수(K)와 흡착표준자유에너지$({\Delta}G_{ads})$는 각각 $1.5\times10^{-4}$와 21.8kJ/mol이다. 단결정 Pt(100)/0.5M LiOH 수용액 계면에서 K는 음전위에 따라 1.9(UPD H)에서 $6.8\times10^{-6}$ (OPD H)또는 그 반대로 전이한다. 마찬가지로, ${\Delta}G_{ads}$는 음전위에 따라 -1.6kJ/mol (UPD H)에서 29.5kJ/mol (OPD H) 또는 그 반대로 전이한다. 전극속도론적 패러미터$(K,\; {\Delta}G_{ads})$의 전이는 단결정 Pt(100)전극표면의 UPD H와 OPD H에 기인한다. UPD H와 OPD H는 음극 $H_2$발생 반응을 위한 순차적 과정이 아니라 전극표면의 수소 흡착부위에 기인하는 독립적 과정이다.

• 대한임상검사과학회지
• /
• 제37권2호
• /
• pp.65-70
• /
• 2005

Those specifications of the CLIA analytical tolerance limits are consistent with the performance goals in Six Sigma Quality Management. Six sigma analysis determines performance quality from bias and precision statistics. It also shows if the method meets the criteria for the six sigma performance. Performance standards calculates allowable total error from several different criteria. Six sigma means six standard deviations from the target value or mean value and about 3.4 failures per million opportunities for failure. Sigma Quality Level is an indicator of process centering and process variation total error allowable. Tolerance specification is replaced by a Total Error specification, which is a common form of a quality specification for a laboratory test. The CLIA criteria for acceptable performance in proficiency testing events are given in the form of an allowable total error, TEa. Thus there is a published list of TEa specifications for regulated analytes. In terms of TEa, Six Sigma Quality Management sets a precision goal of TEa/6 and an accuracy goal of 1.5 (TEa/6). This concept is based on the proficiency testing specification of target value +/-3s, TEa from reference intervals, biological variation, and peer group median mean surveys. We have found rules to calculate as a fraction of a reference interval and peer group median mean surveys. We studied to develop total error allowable from peer group survey results and CLIA 88 rules in US on 19 items TP, ALB, T.B, ALP, AST, ALT, CL, LD, K, Na, CRE, BUN, T.C, GLU, GGT, CA, phosphorus, UA, TG tests in chematology were follows. Sigma level versus TEa from peer group median mean CV of each item by group mean were assessed by process performance, fitting within six sigma tolerance limits were TP ($6.1{\delta}$/9.3%), ALB ($6.9{\delta}$/11.3%), T.B ($3.4{\delta}$/25.6%), ALP ($6.8{\delta}$/31.5%), AST ($4.5{\delta}$/16.8%), ALT ($1.6{\delta}$/19.3%), CL ($4.6{\delta}$/8.4%), LD ($11.5{\delta}$/20.07%), K ($2.5{\delta}$/0.39mmol/L), Na ($3.6{\delta}$/6.87mmol/L), CRE ($9.9{\delta}$/21.8%), BUN ($4.3{\delta}$/13.3%), UA ($5.9{\delta}$/11.5%), T.C ($2.2{\delta}$/10.7%), GLU ($4.8{\delta}$/10.2%), GGT ($7.5{\delta}$/27.3%), CA ($5.5{\delta}$/0.87mmol/L), IP ($8.5{\delta}$/13.17%), TG ($9.6{\delta}$/17.7%). Peer group survey median CV in Korean External Assessment greater than CLIA criteria were CL (8.45%/5%), BUN (13.3%/9%), CRE (21.8%/15%), T.B (25.6%/20%), and Na (6.87mmol/L/4mmol/L). Peer group survey median CV less than it were as TP (9.3%/10%), AST (16.8%/20%), ALT (19.3%/20%), K (0.39mmol/L/0.5mmol/L), UA (11.5%/17%), Ca (0.87mg/dL1mg/L), TG (17.7%/25%). TEa in 17 items were same one in 14 items with 82.35%. We found out the truth on increasing sigma level due to increased total error allowable, and were sure that the goal of setting total error allowable would affect the evaluation of sigma metrics in the process, if sustaining the same process.

• 한국지반공학회논문집
• /
• 제22권8호
• /
• pp.77-88
• /
• 2006

본 연구에서는 말뚝-지반의 상호작용을 고려한 Pile-Bent 구조물의 수평하중 해석기법을 제안하였다. 특히, 수평하중이 작용하는 Pile-Bent 구조물의 특성을 고려한 재료의 항복거동과 기하학적 비선형 거동인 $P-{\Delta}$ 효과를 해석기법에 도입하였다. 개발한 해석기법상의 현장타설 말뚝은 보-기둥 모델을 적용하였으며 지반은 비선형 하중전이 함수를 이용하였다. 본 연구결과, 강하부 일체형인 Pile-Bent 구조물의 경우 해석방법(재료의 탄성 또는 비탄성)에 따라 수평변위의 차가 크게 발생하였다. 재료의 항복거동만 고려할 경우 최대 휨 모멘트($M_{max}$)는 지표 아래의 약 3.5D(D는 말뚝직경) 깊이에서 발생되었으며, 재료의 항복거동과 $P-{\Delta}$ 효과를 모두 고려할 경우 $M_{max}$의 지점이 다소 상승하여 지표 아래 약 1.5D 깊이에서 발생하였다. 세장비에 따른 재료의 항복 및 $P-{\Delta}$ 효과는 단주일 경우에는 재료의 항복거동이, 장주일 경우에는 $P-{\Delta}$ 효과에 의한 기하학적 비선형 거동이 수평변위의 주요 영향인자임을 확인하였다.