• Title/Summary/Keyword: ${\delta}^{13}C$

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Determination of the Origin in both Dissolved Inorganic Nitrogen and Phytoplankton at the Lake Paldang using Stable Isotope Ratios (δ13C, δ15N, δ15N-NO3 and δ15N-NH4) (질산염 및 식물플랑크톤의 안정동위원소비를 이용한 팔당호 수계내의 질소원 기원 연구)

  • Kim, Min-Seob;Lee, Eun-Jeong;Yoon, Suk-Hee;Lim, Bo-La;Park, Jaeseon;Park, Hyunwoo;Chung, Hyen-Mi;Choi, Jong-Woo
    • Korean Journal of Ecology and Environment
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    • v.50 no.4
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    • pp.452-458
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    • 2017
  • The nitrogen isotope value in both ammonium and nitrate ion were determined at 9 stations during both June and August 2016, in order to understand the origin of DIN at the Han river. ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values in 8 stations (CP, SB, MHC, P4, SJ, SBC, P2, SC) were no significant variation. However ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values in KK (Kyeongan stream) showed significant different in comparison with 8 stations, with an apparent increase of nitrogen isotope values. These results indicate that antropogenic nitrogen source influence on KK station. Also the ${\delta}^{13}C$ and ${\delta}^{15}N$ isotope ratio of phytoplankton (Diatom and Cyanobacteria) in KK (Kyeongan stream) showed heavier values, compared to other study stations. These results indicate that nitrogen isotope value in phytoplankton effects by different nitrogen source in study sites. These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the identification of dissolved inorganic nitrogen origin in aquatic environments.

A Preliminary Study of the Effect of Pelagic Organisms on the Macrobenthic Community in the Adjacent East China Sea and Korea Strait (표영생물이 동중국해 주변 해역과 대한해협의 대형저서동물 군집에 미치는 영향 파악을 위한 선행 연구)

  • Yu, Ok-Hwan;Paik, Sang-Gyu;Lee, Hyung-Gon;Kang, Chang-Keun;Kim, Dong-Sung;Lee, Jae-Hac;Kim, Wong-Seo
    • Ocean and Polar Research
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    • v.30 no.3
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    • pp.303-312
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    • 2008
  • Despite the impacts of the climate changes on the pelagic ecosystem, few studies have examined the pelagic-benthic coupling in the adjacent East China Sea and Korea Strait. Therefore, the species composition and abundance of the macrobenthic community, as well as the potential food sources of benthic fauna were investigated in the present study using stable isotope analysis (${\delta}^{13}C\;and\;{\delta}^{15}N$) for suspended particulate organic matter (SPOM), sedimentary organic matter (SOM), phytoplankton, and zooplankton. A total of 157 macrobenthic fauna were collected, and the density of the macrobenthic fauna ranged from 4 to 434 ind./0.25 $m^2$, with an average density of 149 ind./0.25 $m^2$. The density of the benthic fauna increased moving from offshore shelf sites to coastal sites adjacent to the Korea Strait. Cluster analysis showed that the macrobenthic communities consisted of three distinct groups: group A in the Korea Strait, group B in the East China Sea, and group C near Ieodo. The dominant species in group A were the amphipods Photis japonica and Ampelisca miharaensis, followed by the polychaete Scolotoma longifolia. Environmental variables, such as the temperature of the seawater and sediment, and oxygen, and chlorophyll a levels, appeared to affect the structure of the community, suggesting the importance of coupling with the pelagic system. The ${\delta}^{13}C$ values of SPOM and zooplankton ranged from -22.97 to -23.5% and -19.92 to -21.86%, respectively, showing a relatively narrow range(<1%) between the two components. The difference between the ${\delta}^{13}C$ values of SOM and pelagic organic matter was also within 1%, suggesting that the SOM originated from the pelagic system, which is an important factor controlling the macrobenthic community.

Thermodynamic Characteris tics of Surface Activities of N-Alkyl Pyridinium Bromide (N-Alkyl Pyridinium Bromide류의 계면활성에 대한 열역학적 특성)

  • Kim, Yeoung-Chan;Kim, Dong-Sik;Jeong, Soon-Wook;Shon, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.8 no.2
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    • pp.105-114
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    • 1991
  • In relation to the preparation of Langmuir-Blodgett thin film, four kinds of N-alkylpyridiniurn bromide were synthesized. The values of surface tensions of these materials, measured with a Traube stalagmometer, gave the relationship between the critical micells hydrophobic radical and between CMC and temperature. Values of thermodynamic properties(${\Delta}H^0_m,\;{\Delta}S^0_m,\;{\Delta}G^0_m,$) for the formatoin of micelle were also obtained. Experiments gave the following results; at the temperature range between 40 and 60$^{\circ}C, CMC of Hexadecyl-, Octadecyl-, Eicosyl-, and Docosyl-Pyridinium Bromide were $7.64{\times}10^{-4}{\sim}9.13{\times}10^{-4},\;3.85{\times}10^{-4}{\sim}4.60{\times}10^{-4},\;2.00{\times}10^{-4}{\sim}2.39{\times}10^{-4},\;and\;1.07{\times}10^{-4}{\sim}1.28{\times}10^{-4}$ mol/l, respectively. Surface tension, ${\Gamma}_{CMC}$, of those were 33.49${\sim}$36.00, 34.78${\sim}$37.61, 35.49${\sim}$37.61 and 38.76${\sim}$55.80 dyne/cm, respectively, The relationship between CMC and the mumber of carbon atoms in the hydrophobic radical, N was expressed as follows : Log(CMC)=A-BN where A and B are constants. At the temperature range between 40 and 60$^{\circ}C$, the change of Gibbs evergy (${\Delta}G_m$) for one methylene group ($-CH_2-$) were -0.65RT, respectively, The minus values of enthalpy change (${\Delta}H_m$) suggest that the formation of micelle is exothermic. Additionally, the overall increase in the entropy change (${\Delta}S_m$) with respect to the temperature increase suggests that the formation of micelle is attained by a exothermic enthalpy directed process.

A Study on the Characteristics of Fatigue Crack Growth of A516 Steel for Pressure Vessel at Low Temperatures (압력용기용 A516강의 저온피로크랙전파특성에 관한 연구)

  • Park, Kyung-Dong;Ro, Tae-Young;Kim, Young-Dae;Kim, Hyung-Ja;Son, Jae-Yun
    • Journal of Ocean Engineering and Technology
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    • v.13 no.3 s.33
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    • pp.108-113
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    • 1999
  • In this study, CT specimens were prepared from ASTM A516 Gr. 65 which was used for pressure vessel plates for moderate and lower temperature service. Fatigue crack growth test was carried out in the environment of low temperature of $10^{circ}C, -10^{circ}C, -30${circ}C\;and\;-50^{circ}C$ and in the range of stress ratio of R=0.05 and 0.3 by means of opening mode displacement. Based on these test results, the characteristics from temperature and stress ration were shown as follows. 1) As the stress ratio, R increased da/dN and ${Delta}K$ of 2nd stage gradually decreased. And as R decreased, the effect of temperature became greater and greater. 2) As the temperature descended, da/dN decreased on a certain ${Delta}K$, and ${Delta}K$ did in a same da/dN. And the stress ratio, R exerted greater influence at the lower temperature. 3) The fatigue crack growth constant, m increased at $10^{circ}C$ and $-10^{circ}C$, snd decreased at $-30^{circ}C$ and $-50^{circ}C$ following the increment of stress ratio R. And m increased along with the reduction of temperature greatly decreased at $-30^{circ}C$ to come close to two(2).

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An Experimental on the Evalution of Fatigue Crack Propagation of Carbon Steel (탄소강의 피로균열 진전거동 평가에 관한 실험적 연구)

  • 김희송;안병욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.938-946
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    • 1989
  • Using the CT specimen of carbon steel(SM45C), we estimated the fatigue crack propagation behavior in stable crack propagation range. Furthermore the fatigue crack propagation rate, Acoustic Emission(AE) count rate, and fractography characteristics were also compared among others. The following results were confirmed by experimental observation. Near-threshold stress intensity factor range(.DELTA. $K_{th}$) is influenced by stress ratio but not at the upper limit of stable crack propagation range. As stress intensity factor range(.DELTA.K) and(or) stress amplitude increase (s), both crack propagation rate(da/dN) and AE count rate(dn/dN) increase. Effective stress intensity factor range(.DELTA. $K_{off}$) determined from the crack closure point measurement by AE method is useful for the evaluation of fatigue crack propagation rate. Fractography in stable crack propagation range showed striation, and agreed with the crack propagation rate obtained either by experiment of by the results of microscopic measurements.s.

Application of Response Surface Methodology for Optimization of Nature Dye Extraction Process (천연색소 추출공정 최적화를 위한 반응표면분석법의 적용)

  • Lee, Seung Bum;Lee, Won Jae;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.29 no.3
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    • pp.283-288
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    • 2018
  • As the use of environmentally friendly and non-disease natural pigments grows, various methods for extracting natural pigments have been studied. The natural color was extracted from parsley, a vegetable ingredient containing natural dyes. Target color codes of green series of natural dyes extracted as variables #50932C (L = 55.0, a = -40.0, b = 46.0) were set with the pH and temperature of extracted natural color coordinates (of the extracted), and the quantitative intensities of natural dyes were analyzed. During the colorimetric analysis predicted by the reaction surface analysis method, a color coordinate analysis was conducted under the optimal conditions of pH 8.0 and extraction temperature of $60.9^{\circ}C$. Under these conditions, predicted figures of L, a, and b were 55.0, -36.3, and 36.8, respectively, while actual experimental ones confirmed were 69.0, -35.9, and 31.4, respectively. In these results, the theory accuracy and actual error rate were confirmed to be 73.0 and 13.8%, respectively. The theoretical optimization condition of the color difference (${\Delta}E$) was at the pH of 9.2 and extraction temperature of $55.2^{\circ}C$. Under these conditions the predicted ${\Delta}E$ figure was 12.4 while the experimental one was 13.0. The difference in color analysis showed 97.5% of the theoretical accuracy and 4.5% of the actual error rate. However, the combination of color coordinates did not represent a desired target color, but rather close to the targeted color by means of an arithmetic mean. Therefore, it can be said that when the reaction surface analysis method was applied to the natural dye extraction process, the use of color coordinates as a response value can be a better method for optimizing the dye extraction process.

Eliashberg Calculation of the Momentum-Resolved Self-Energy for the Cuprate Superconductors Induced by the Spin Fluctuations (구리 산화물 계열 초전도체에서의 스핀 요동에 의한 자체 에너지의 엘리아시버그 계산)

  • Hong, Seung-Hwan;Choi, Han-Yong
    • Progress in Superconductivity
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    • v.13 no.3
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    • pp.146-150
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    • 2012
  • We solve the momentum resolved d-wave Eliashberg equation employing the magnetic excitation spectrum from the inelastic neutron scattering on the LSCO superconductors reported by Vignolle et al. The magnetic excitation spectrum exhibits 2 peaks: a sharp incommensurate peak at 18 meV at momentum (${\pi}$, ${\pi}{\pm}{\delta}$) and (${\pi}{\pm}{\delta}$, ${\pi}$) and another broad peak near 40~70 meV at momentum (${\pi}$, ${\pi}$). Above 70 meV, the magnetic excitation spectrum has a long tail that is shaped into a circle centered at (${\pi}$, ${\pi}$) with ${\delta}$. The sign of the real part of the self-energy is determined by the momentum position of the peaks of the magnetic excitation spectrum and bare dispersion. We will discuss the effects of the each component of the magnetic excitation spectrum on the self-energy, the pairing self-energy.

ON RADICALLY-SYMMETRIC IDEALS

  • Hashemi, Ebrahim
    • Communications of the Korean Mathematical Society
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    • v.26 no.3
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    • pp.339-348
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    • 2011
  • A ring R is called symmetric, if abc = 0 implies acb = 0 for a, b, c ${\in}$ R. An ideal I of a ring R is called symmetric (resp. radically-symmetric) if R=I (resp. R/$\sqrt{I}$) is a symmetric ring. We first show that symmetric ideals and ideals which have the insertion of factors property are radically-symmetric. We next show that if R is a semicommutative ring, then $T_n$(R) and R[x]=($x^n$) are radically-symmetric, where ($x^n$) is the ideal of R[x] generated by $x^n$. Also we give some examples of radically-symmetric ideals which are not symmetric. Connections between symmetric ideals of R and related ideals of some ring extensions are also shown. In particular we show that if R is a symmetric (or semicommutative) (${\alpha}$, ${\delta}$)-compatible ring, then R[x; ${\alpha}$, ${\delta}$] is a radically-symmetric ring. As a corollary we obtain a generalization of [13].