• Title/Summary/Keyword: ${\alpha}$-parameter

검색결과 437건 처리시간 0.037초

The polarimetric study of (331471) 1984QY1: an asteroid in comet-like orbit

  • Kim, Jooyeon;Ishiguro, Masateru;Bach, Yoonsoo P.;Kuroda, Daisuke;Naito, Hiroyuki;Kim, Yoonyoung;Kwon, Yuna G.;Imai, Masataka;Kuramoto, Kiyoshi;Watanabe, Makoto
    • 천문학회보
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    • 제42권2호
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    • pp.50.2-50.2
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    • 2017
  • Spatial distribution of atmosphereless bodies in the solar system provides an important clue as to their origins, namely asteroids from Mainbelt or comets from outer solar system. It is, however, difficult to distinguish asteroids and dormant comets due to their similar appearances. In this study, we conducted a unique observation to differentiate asteroids and dormant comets in terms of 'polarimetry'. We observed (331471) 1984 QY1 (hereafter QY1) at large phase angles using the Multi-Spectral Imager (MSI) on the 1.6-m Pirka Telescope from UT 2016 May 25 to June 24. QY1 is a dormant comet candidate in terms of the dynamical properties (i.e. the Tisserand parameter with respect to Jupiter, TJ = 2.68). We analyzed the polarization degree of QY1 as a function of phase angle and found its maximum polarization degree, $Pmax=8.68{\pm}0.28%$ and $8.72{\pm}0.38%$, in RC-and V-band, respectively, around the phase angle of ${\alpha}=100^{\circ}$. In addition, we obtained the geometric albedo, $pV=0.16{\pm}0.02$ by means of an empirical slope-albedo law. The polarimetric properties and the albedo value we acquired are similar to those of S-type asteroids rather than cometary nuclei. In this presentation, we introduce our observation and findings. In addition, we further discuss a dynamical transportation process from Mainbelt to the current orbit.

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Force Field Parameters for 3-Nitrotyrosine and 6-Nitrotryptophan

  • Myung, Yoo-Chan;Han, Sang-Hwa
    • Bulletin of the Korean Chemical Society
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    • 제31권9호
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    • pp.2581-2587
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    • 2010
  • Nitration of tyrosine and tryptophan residues is common in cells under nitrative stress. However, physiological consequences of protein nitration are not well characterized on a molecular level due to limited availability of the 3D structures of nitrated proteins. Molecular dynamics (MD) simulation can be an alternative tool to probe the structural perturbations induced by nitration. In this study we developed molecular mechanics parameters for 3-nitrotyrosine (NIY) and 6-nitrotryptophan (NIW) that are compatible with the AMBER-99 force field. Partial atomic charges were derived by using a multi-conformational restrained electrostatic potential (RESP) methodology that included the geometry optimized structures of both $\alpha$- and $\beta$-conformers of a capped tripeptide ACE-NIY-NME or ACE-NIW-NME. Force constants for bonds and angles were adopted from the generalized AMBER force field. Torsional force constants for the proper dihedral C-C-N-O and improper dihedral C-O-N-O of the nitro group in NIY were determined by fitting the torsional energy profiles obtained from quantum mechanical (QM) geometry optimization with those from molecular mechanical (MM) energy minimization. Force field parameters obtained for NIY were transferable to NIW so that they reproduced the QM torsional energy profiles of ACE-NIW-NME accurately. Moreover, the QM optimized structures of the tripeptides containing NIY and NIW were almost identical to the corresponding structures obtained from MM energy minimization, attesting the validity of the current parameter set. Molecular dynamics simulations of thioredoxin nitrated at the single tyrosine and tryptophan yielded well-behaved trajectories suggesting that the parameters are suitable for molecular dynamics simulations of a nitrated protein.

Overexpression, Crystallization, and Preliminary X-Ray Crystallographic Analysis of the Alanine Racemase from Enterococcus faecalis v583

  • Priyadarshi, Amit;Lee, Eun-Hye;Sung, Min-Woo;Kim, Jae-Hee;Ku, Min-Je;Kim, Eunice Eun-Kyeong;Hwang, Kwang-Yeon
    • Journal of Microbiology and Biotechnology
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    • 제18권1호
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    • pp.55-58
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    • 2008
  • Alanine racemase, a bacterial enzyme belonging to the fold-type III group of pyridoxal 5'-phosphate (PLP)-dependent enzymes, has been shown to catalyze the interconversion between L- and D-alanine. The alanine racemase from the pathogenic bacterium Enterococcus faecalis v583 has been overexpressed in E. coli and was shown to crystallize an enzyme at 295 K, using polyethylene glycol (PEG) 8000 as a precipitant. X-ray diffraction data to $2.5{\AA}$ has been collected using synchrotron radiation. The crystal is a member of the orthorhombic space group, $C222_1$ with unit cell parameter of a=94.634, b=156.516, $c=147.878{\AA},\;and\;{\alpha}={\beta}={\gamma}=90{\AA}$. Two or three monomers are likely to be present in the asymmetric unit, with a corresponding $V_m\; of\;3.38{\AA}^3\;Da^{-1}\;and\;2.26{\AA}^3\;Da^{-1}$ and a solvent content of 63.7% and 45.5%, respectively.

Analysis of Volatile Compounds and Enantiomeric Separation of Chiral Compounds of Dried Sancho (Zanthoxylum schinifolium Siebold & Zucc)

  • Seo, Hye-Young;Shim, Sung-Lye;Ryu, Keun-Young;Jung, Min-Seok;Hwang, In-Min;Shin, Dong-Bin;Kwon, Joong-Ho;Schreier, Peter;Kim, Kyong-Su
    • Food Science and Biotechnology
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    • 제18권1호
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    • pp.18-24
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    • 2009
  • The volatile compounds of dried sancho (Zanthoxylum schinifolium), an aromatic plant were extracted by simultaneous distillation and extraction (SDE) method and identified by gas chromatograph-mass spectrometry (GC-MS). Selected chiral constituents of sancho oil were characterized by enantiodifferentiation using multidimensional gas chromatograph (MDGC)-MS. A total of 57 compounds were identified and quantified, and the major compounds were identified estragole, nonanoic acid, octanoic acid, $\beta$-phellandrenene, and limonene. Among them, estragol (63.9%) was found as the predominantly abundant component of sancho. $\alpha$-pinene and nerolidol, and $\beta$-pinene and linalool were determined to be enantiomerically pure (100%) for their (S)-form and (R)-form, respectively. The enantiomeric composition of limonene in sancho revealed 83.9% purity for the (S)-enantiomer, whereas (E)- and (Z)-rose oxides showed mixtures of both enantiomers. The enantiomeric excess (%) for citronellal was 22.6% with the (R)-enantiomer as major enantiomer. The enantiomeric composition of these compounds can be used as parameter for authenticity control of sancho.

Consumers attitude towards Internet banking services in an underdeveloped country: A case of Pokhara, Nepal

  • Shrestha, Deepanjal;Wenan, Tan;Rajkarnikar, Neesha;Jeong, Seung Ryul
    • 인터넷정보학회논문지
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    • 제21권5호
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    • pp.75-85
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    • 2020
  • The application of Internet technology has created enormous impact on banking sector with the implementation of many techno-oriented services like Internet banking, EFT, branchless banking, Automated Clearing House (ACH) transactions etc. Study of customer's attitude in terms of trust, perceived risk and ease of use of a particular technology is as an important parameter for acceptance or rejection of a technology. To explore the customers'attitude for Internet banking this research is undertaken. The research is carried out in Pokhara valley which is the second largest city and tourism capital of Nepal. The study employs descriptive research design with stratified sampling procedure for eight top commercial banks. A set of 25 customers is taken from each selected 8 banks making a sample size of 200 respondents. A fixed set of question related to demographic factors is provided personally or by visiting the location of the customers of Internet banking service and collected accordingly. Reliability test is performed using Cronbach's alpha and data is analyzed using inferential statistics to present the results of the study. This study provides knowledge on the current scenario of Internet banking and helps banks in cost saving, mass customization, product innovation, improved marketing and communication. This study is very important for financial institutions like banks, government agencies and business houses to understand the perception of customers towards Internet banking and technology as a whole. The study also supplements the gap in literature on technology and banking in Nepal and serves as an important knowledge base.

How will surface treatments affect the translucency of porcelain laminate veneers?

  • Turgut, Sedanur;Bagis, Bora;Ayaz, Elif Aydogan;Korkmaz, Fatih Mehmet;Ulusoy, Kivanc Utku;Bagis, Yildirim Hakan
    • The Journal of Advanced Prosthodontics
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    • 제6권1호
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    • pp.8-13
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    • 2014
  • PURPOSE. The purpose of this study was to evaluate whether surface treatments affect the translucency of laminate veneers with different shades and thicknesses. MATERIALS AND METHODS. A total of 224 disc-shaped ceramic veneers were prepared from A1, A3, HT (High Translucent) and HO (High Opaque) shades of IPS e.max Press (Ivoclar Vivadent) with 0.5 mm and 1.0 mm thicknesses. The ceramics were divided into four groups for surface treatments. Group C: no surface treatments; Group HF: etched with hydrofluoric acid; Group SB: sandblasted with 50-${\mu}m$ $Al_2O_3$; and Group L; irradiated with an Er;YAG laser. A translucent shade of resin cement (Rely X Veneer, 3M ESPE) was chosen for cementation. The color values of the veneers were measured with a colorimeter and translucency parameter (TP) values were calculated. A three-way ANOVA with interactions for TP values was performed and Bonferroni tests were used when appropriate (${\alpha}=0.05$). RESULTS. There were significant interactions between the surface treatments, ceramic shades and thicknesses (P=.001). For the 0.5-mm-thick specimens there were significant differences after the SB and L treatments. There was no significant difference between the HF and C treatments for any shades or thicknesses (P>.05). For the 1-mm-thick ceramics, there was only a significant difference between the L and C treatments for the HT shade ceramics (P=.01). There were also significant differences between the SB and C treatments except not for the HO shades (P=.768). CONCLUSION. The SB and L treatments caused laminate veneers to become more opaque; however, HF treatment did not affect the TP values. When the laminate veneers were thinner, both the shade of the ceramic and the SB and laser treatments had a greater effect on the TP values.

수평이동방식 입체카메라의 입체영상의 결상 위치 추정 방법 (The Method for Estimating Stereoscopic Object Position with Horizontal-Moving Camera)

  • 임영태;김남;권기철
    • 한국광학회지
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    • 제17권6호
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    • pp.532-536
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    • 2006
  • 입체영상 획득시 입체영상 결상 위치는 입체감을 유발하는 중요한 요인이 된다. 평행방식과 교차방식 카메라는 주시각 제어가 불가능하고 획득 영상의 왜곡이 심한 단점에도 불구하고 구조가 간단하여 결상 위치 추정방법에 대한 다양한 연구가 진행되고 있다. 수평이동방식 카메라는 왜곡이 적고 주시각 제어가 가능하여 평행방식과 교차방식보다 많은 장점을 가지고 있지만 구조의 복잡성 때문에 연구가 부족하다. 본 논문에서는 입체영상의 촬영과 디스플레이의 기하학적 모델을 이용하여 수평이동방식 입체카메라의 입체영상 결상 거리 추정 방법을 제안하였다. 기존의 추정방법을 이용한 입체영상 결상거리는 ${\alpha}_2$가 1과 0.75 일 때 587.64mm에서 791.16mmn, 639.53mm에서 809.50mm 사이의 분포를 가지고 있다. 수평이동전과 수평이동후의 결상 위치 차이는 1.08mm에서 0.11mm까지의 범위를 가지고 있고 거리에 따른 수평이동량과 같은 형태임을 알 수 있었다.

Crystal Structures of the Two Isomorphous A-DNA Decamers d(GTACGCGTAC) and d(GGCCGCGGCC)

  • Kim, Tae-gyun;Kwon, Taek-Hun;Jung, Hye-sun;Ku, Ja-Kang;Sundaralingam, Muttaiya;Ban, Chang-ill
    • Bulletin of the Korean Chemical Society
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    • 제27권4호
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    • pp.568-572
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    • 2006
  • To study the effect of sequence on DNA structure, the two decamer crystal structures one alternating,d(GTACGCGTAC), and the other non-alternating, d(GGCCGCGGCC), were solved. Crystals of both decamers belong to the hexagonal space group $P6_122$, with one strand in the asymmetric unit. The unit cell constants of the alternating decamer are a = b = 39.26 $\AA$, c = 77.70 $\AA$. The structure was refined with 1,828 reflections from 8.0 to 2.0 Aresolution to an R value of 21.3% with all DNA atoms and 63 water molecules. The isomorphous non-alternating decamer had unit cell dimensions of a = b = 39.05 $\AA$, c = 82.15 $\AA$. The structure was refined with 2,423 reflections from 8.0 to 2.0 $\AA$ resolution to a final R value of 22.2% for all DNA atoms and 65 water molecules. Although the average helical parameters of the decamers are typical of A-DNAs, there are some minor differences between them. The helical twist, rise, x-displacement, inclination and roll alternate in the alternating decamer, but do not in the non-alternating decamer. The backbone conformations in both structures show some differences; the residue G(7) of the alternating decamer is trans for $\alpha$ and $\gamma$ while the trans conformations are observed at the residue G(8) of the non-alternating decamer.

Mn을 첨가한 ZnO-TeO2 세라믹스의 소결과 전기적 특성 (Sintering and Electrical Properties of Mn-doped ZnO-TeO2 Ceramics)

  • 홍연우;신효순;여동훈;김종희;김진호
    • 한국전기전자재료학회논문지
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    • 제22권1호
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    • pp.22-28
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    • 2009
  • We investigated the sintering and electric properties of ZnO-1.0 at% $TeO_2$ (ZT1) and 1.0 at% Mn-doped ZT1(ZT1M1) system. $TeO_2$ itself melts at $732^{\circ}C$ in air but forms the $ZnTeO_3$ or $Zn_2Te_3O_8$ phase with ZnO as increasing temperature and therefore retards the densification of ZnO to $1000^{\circ}C$. In ZT1M1 system, also, the densification of ZnO was retarded up to $1000^{\circ}C$ and then reached > 90% of theoretical density above $1100^{\circ}C$. It was found that a good varistor characteristics(nonlinear coefficient $a{\sim}60$) were developed in ZT1M1 system sintered at $1100^{\circ}C$ due to Mn which known as improving the nonlinearity of ZnO varistors. The results of C-V characteristics such as barrier height (${\Phi}_b$), donor density ($N_D$), depletion layer (W), and interface state density ($N_t$) in ZT1M1 ceramics were $1.8{\times}10^{17}cm^{-3}$, 1.6 V, 93 nm, and $1.7{\times}10^{12}cm^{-2}$, respectively. Also we measured the resistance and capacitance of grain boundaries with temperature using impedance and electric modulus spectroscopy. It will be discussed about the stability and homogeneity of grain boundaries using distribution parameter ($\alpha$) simulated with the Z(T)"-logf plots.

자장중 열처리에 의한 $Nd_{2}Fe_{14}B/Fe_{3}B$ 초미세립 복합자성상의 자기특성 향상 (The Effect of Magnetic Field Treatment on Enhanced Exchange Coupling of $Nd_{2}Fe_{14}B/Fe_{3}B$ Magnet)

  • 박언병;양충진
    • 한국자기학회지
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    • 제6권2호
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    • pp.80-85
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    • 1996
  • $Nd_{2}Fe_{14}B/Fe_{3}B$ 복합자성상을 근간으로 한 급냉제조된 합금을 외부 자장중에서 열처리를 함으로써 자기특성이 월등하게 좋아짐을 확인하였다. $Nd_{4}Fe_{73.5}Co_{3}(Hf_{1-x}-Ga_{x})B_{18.5}$ 조성 합금을 1~5 kOe 자장중에서 열처리함으로써 연자성의 기지상$(Fe_{3}B)$ 및 강자성상$(Nd_{2}Fe_{14}B)$의 결정입도가 20% 감소하였고, 그 결과 잔류자속밀도 $(B_{r})$ 및 최대자기에너지적, ${(B.H)}_{max}$가 30% 이상 증가하였다. 이러한 증가는 입도의 감소 뿐만 아니라 미세입도의 고른 분포에도 기인한 것으로 판단되었다. 보자력의 극대점은 잔류자속밀도와는 달리 특정결정입도에서 발생하며, 이러한 기구를 교환상호작용변수 와 연관하여 설명한다. $Nd_{4}Fe_{73.5}Co_{3}Hf_{0.5}Ga_{0.5}B_{18.5}$ 합금을 자장중 열처리한 결과 ${(B.H)}_{max}=15.8$ MGOe의 고에너지적을 얻을 수 있음을 확인하였다.

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