• Title/Summary/Keyword: ${\Delta}E^*$

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The Effect of Resin Finishing on Cotton Fabrics Dyed with Direct Dyes (직접염료 염색포의 수지가공에 대한 영향)

  • Seol Jung-Hwa;Choi Suck-Chul;Chung Doo-Jin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.9 no.2
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    • pp.13-26
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    • 1985
  • In this study, when cotton fabrics dyed with Direct dyes are treated under various resin concentration 2, 4, 8, 12, $14\%$ with ureaformaldehyde(UF) and melamineformaldehyde(MF) resin which can be imparted the crease recovery to textiles, chang of properties on lightfastness, washfastness, crease recovery, breaking strength, etc. and color changes are investigated. the results are as follows 1) Color difference(${\Delta}$E) increased but K/S value decreased according to the increase of resin cone. such tendency showed that MF treated fabrics and soaping fabrics were evident than UF treated fabrics and non-soaping fabrics. 2) In lightfastness, ${\Delta}$E and K/S value of resin treated fabrics were reduced as compared with untreated fabrics according to the increase of resin cone. The lower ${\Delta}$E and K/S value of MF than ${\Delta}$E and K/S value of UF showed low lightfastness of MF. pH of resin treted fabrics was almost unaffected with lightfastness. 3) In washfastness, ${\Delta}$E and K/S value of resin treated fabrics decreased slightly as com-pared with untreated fabricsaccording tothe increase of resin cone. The ${\Delta}$E and K/S value of MF decreased lower than UF. But in the case of the higher resin cone. than about $8\%$, they were not almost differentiated. 4) As resin cone. increased, crease recovery considerably increased but breaking strength and elongation decreased. The fabrics treated with UF were good crease recovery, whereas the fabrics treated with MF were good breaking strength. 5) Soaping appeared to improve the lightfastness, washfastness, crease recovery but appeared to work adverse effect on breaking strength.

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Quantum Chemical Calculations on the Conformational Structure of the Alanine Oligomer Model (알라닌 올리고머의 배좌구조에 관한 양자화학적 계산)

  • Sim, Jae-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.2
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    • pp.1563-1570
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    • 2015
  • Conformational change during chain propagation of alanine oligomer was investigated by quantum chemical calculation(QCC) using 2~5mers(${\times}=2{\sim}5$) models. For estimation of the end group effects, two types of end group. "amide type" ($CH_3CONH-and-CONHCH_3$) and "methyl type" ($CH_3CONH-and-CONHCH_3$), were prepared as both ends(N-and-C). Conformers optimized for 5-mer converged to three types of ${\Phi}/{\Psi}$ : ${\alpha}$-helix(g+/g+, or g-/g-), PPII-like(extended helix-like, g+/g-, or g-/g+), and ${\beta}$-extended (t+/t-, or t-/t+), in the order of lower energy, and the energies of left- and right- handed conformers were the same (5-mer. amide type ${\Delta}E=-1.05$, right type ${\Delta}E=-1.62$). Energies of the monomer unit(${\Delta}E$) of ${\alpha}$-helix decreased with increases of monomer.

Analysis of Browning Factors During Fermentation of Kochujang (고추장 발효 중 갈변 요인에 대한 분석)

  • Kim, Moon-Sook;Ahn, Yong-Seon;Shin, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.32 no.5
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    • pp.1149-1157
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    • 2000
  • To confirm the factors concerning color changes of traditional kochujang, heating, U.V. and $N_2$ gas substitution treatment were conducted on duk(rice cake) kochujang and shikhae(malt digested syrup) kochujang. The value of L, a and b value by Hunter of each kochujang were gradually decreased during fermentation and ${\delta}E$ increased. The ${\delta}E$ value of duk kochujang treated by U.V. was higher than those of the other treatments and non heated shikhae kochujang showed higher ${\delta}E$ value. The main cause of color change by factor analysis on various factors of duk kochujang and shikhae kochujang were light, and light and heat respectively. The acetone and water extracted pigments had maximum absorbance at 450-470 nm and 200-205 nm respectively.

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A STUDY THE SHADE CHANCE OF SEVERAL KINDS OF ALL CERAMIC CROWNS USED FOR METAL DOWEL CORE (금속 다우엘코어에 사용된 수종의 전부도재관의 색조변화에 관한 연구)

  • Hur Sung-Il;Lim Heon-Song;Lim Ju-Hwan;Cho In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.5
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    • pp.477-491
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    • 2001
  • The purpose of this study is to compare and analyze the shade changes(${\Delta}E^*$) about $In-Ceram^{(R)}$, $IPS-Empress^{(R)}$, $OPC^{(R)}$ by using of the spectrophotometer arising from inital status and before and after cementation of the resin cement mounted on the metal core. We used a couple of statistics such as 'One- Way ANOVA' and 'Multiple Range Test.' We could be able to verify significantly what is being discussed here up to 95%. The results drawn from our research are as follows : 1. At the time of our experiments regarding the initial shapes of all-ceramic and mounting status of all-ceramic on the metal crown(${\Delta}E^*1$), and a comparison of mounting of all ceramic on the metal crown with all-ceramic cemented on the metal core(${\Delta}E^*2$), at the time of shade change of initial shapes and after we cemented on the metal core. (1) no significant difference among all-ceramics was found. (2) no particular difference was found regarding the $In-Ceram^{(R)}$. (3) a significant difference between the ${\Delta}E^*1$ and ${\Delta}E^*2$ regarding the $IPS-Empress^{(R)}$ was found(P<0.05). (4) a significant difference between the ${\Delta}E^*1$ and ${\Delta}E^*2$ regarding the $OPC^{(R)}$ was found(P<0.05). 2. When we compared the shade changes(${\Delta}E^*$) resulted from before and after the cementation on each of the parts involved of some all-ceramic, we could be able to find shade change increase form incisal third, middle third. and cervical third in that order in $In-Ceram^{(R)}$(spinell), IPS $Empress^{(R)}$, and $OPC^{(R)}$ all. In addition. we could be able to find a significant difference between cervical third and incisal third, middle third. (P<0.05) From what we have just seen, we might conclude that there is a significant shade change difference before and after the cementation with respect to $IPS-Empress^{(R)}$ and $OPC^{(R)}$. In addition, we could also be able to find more shade change difference at the cervical third rather than incisal third and middle third depending on the parts involved.

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The Developmental Regulators, FlbB and FlbE, are Involved in the Virulence of Aspergillus fumigatus

  • Kim, Sung-Su;Kim, Young Hwan;Shin, Kwang-Soo
    • Journal of Microbiology and Biotechnology
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    • v.23 no.6
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    • pp.766-770
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    • 2013
  • Several upstream activators required for proper activation of brlA are involved in the development, vegetative growth, toxin production, and pathogenesis of Aspergillus fumigatus. In this study, we characterized the roles of two upstream developmental regulators, A. fumigatus flbB (AfuflbB) and flbE (AfuflbE), in toxin production and virulence. The deletion of AfuflbB and AfuflbE resulted in reduction of the expression of AfulaeA. Moreover, only about 8% to 10% of fumagillin was produced in the two mutants compared with that of wild type, and ${\Delta}AfuflbB$ strain produced 85% of gliotoxin compared with wild type, whereas none was produced by ${\Delta}AfuflbB$. Flow-cytometric analysis revealed decreased necrotic and apoptotic polymorphonuclear leukocytes cell death after exposure to supernatants from ${\Delta}AfuflbB$ and ${\Delta}AfuflbB$ strains compared with the wild type. These results indicate that FlbB and FlbE are necessary for the proper laeA expression, toxin production, and virulence of A. fumigatus.

Oscillation of Second-Order Nonlinear Forced Functional Dynamic Equations with Damping Term on Time Scales

  • Agwa, Hassan Ahmed;Khodier, Ahmed Mahmoud;Ahmed, Heba Mostaafa Atteya
    • Kyungpook Mathematical Journal
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    • v.56 no.3
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    • pp.777-789
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    • 2016
  • In this paper, we establish some new oscillation criteria for the second-order forced nonlinear functional dynamic equations with damping term $$(r(t)x^{\Delta}(t))^{\Delta}+q({\sigma}(t))x^{\Delta}(t)+p(t)f(x({\tau}(t)))=e(t)$$, and $$(r(t)x^{\Delta}(t))^{\Delta}+q(t)x^{\Delta}(t)+p(t)f(x({\sigma}(t)))=e(t)$$, on a time scale ${\mathbb{T}}$, where r(t), p(t) and q(t) are real-valued right-dense continuous (rd-continuous) functions [1] defined on ${\mathbb{T}}$ with p(t) < 0 and ${\tau}:{\mathbb{T}}{\rightarrow}{\mathbb{T}}$ is a strictly increasing differentiable function and ${\lim}_{t{\rightarrow}{\infty}}{\tau}(t)={\infty}$. No restriction is imposed on the forcing term e(t) to satisfy Kartsatos condition. Our results generalize and extend some pervious results [5, 8, 10, 11, 12] and can be applied to some oscillation problems that not discussed before. Finally, we give some examples to illustrate our main results.

Theoretical Study on Observed Heat of Ligation for Iron(Ⅱ) and Nickel(Ⅱ) Octahedral Complexes (팔면체형 Fe(Ⅱ)와 Ni(Ⅱ)착물의 실측 리간드화열에 관한 이론적 연구)

  • Kim, Jung Sung;Choi, Jin Tae;Song, Young Dae;Cho, Tae Sub
    • Journal of the Korean Chemical Society
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    • v.43 no.2
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    • pp.141-149
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    • 1999
  • The correlation was investigated between the observed heat of ligation and calculated quantum chemical quantities for octahedral $[M(H_2O)_{6-x}(NH_3)_x]^{2+} (M=Fe(II),\;Ni(II))$ complexes by EHMO(Extended Huckel Molecular Orbital) and ZINDO/1(Zerner's Intermediate Neglected of Differential Overlap)method. The net charge of $Fe^{2+}$ and $Ni^{2+}$ ion of octahedral $[M(H_2O)_{6-x}(NH_3)_x]^{2+}(M=Fe(II),\;Ni(II))$ complexes(x=O, 1, …, 6) decreased with substituting $NH_3$ for $H_2O$ molecules. It has found that a good correlation exists between the observed heat of ligation and the calculated quantum chemical quantities such as net charge of central atom, enthalpy of formation, and total dissociation energy. From this finding, we have obtained the following semiempirical linear equation ${\Delta}H_{obs}=-0.2858_{qFe}+0.8813(r=0.97),\;{\Delta}H_{obs}=-0.8981_{qNi}+1.7929(r=0.95),\;{\Delta}H_{obs}=-0.0031H_{f(Fe)}+0.5725(r=0.97),\;{\Delta}H_{obs}=-0.0095H_{f(Ni)}+0.9193(r=0.97),\;{\Delta}H_{obs}=0.0476E_{diss(Fe)}+0.6434(r=0.94),\;{\Delta}H_{obs}=0.1401E_{diss(Ni)}+1.1393(r=0.93)$.

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Surface reactive micro/nano particles on inorganic oxygen separation membrane

  • Lee, Kee-Sung;Shin, Tae-Ho;Lee, Shiwoo;Woo, Sang-Kuk;Yang, Jae-Kyo;Choa, Yong-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.94-97
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    • 2004
  • Micro/nano-sized L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ particles are considered to improve oxygen permeability in highly selective inorganic oxygen separation membrane. A L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membrane with perovskite structure is fabricated by a conventional solid-state reaction. As the oxygen permeation flux of the L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membrane was lower than commercial gas separation membranes, we coated the L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ particles to enhance the oxygen permeation flux. It has been demonstrated that the effective area of reactive free surface is an important factor in determining the effectiveness of the introduction of coating layer for oxygen permeation. The introduction of micro/nano L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ particles was very effective for increasing oxygen flux, as the flux was as much as 2 to 6 times higher than that of an uncoated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membrane.\delta$/ membrane.>/ membrane.brane.

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EDGE COVERING COLORING OF NEARLY BIPARTITE GRAPHS

  • Wang Ji-Hui;Zhang Xia;Liu Guizhen
    • Journal of applied mathematics & informatics
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    • v.22 no.1_2
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    • pp.435-440
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    • 2006
  • Let G be a simple graph with vertex set V(G) and edge set E(G). A subset S of E(G) is called an edge cover of G if the subgraph induced by S is a spanning subgraph of G. The maximum number of edge covers which form a partition of E(G) is called edge covering chromatic number of G, denoted by X'c(G). It is known that for any graph G with minimum degree ${\delta},\;{\delta}-1{\le}X'c(G){\le}{\delta}$. If $X'c(G) ={\delta}$, then G is called a graph of CI class, otherwise G is called a graph of CII class. It is easy to prove that the problem of deciding whether a given graph is of CI class or CII class is NP-complete. In this paper, we consider the classification of nearly bipartite graph and give some sufficient conditions for a nearly bipartite graph to be of CI class.

The effect of different drinks on the color stability of different restorative materials after one month

  • Tekce, Neslihan;Tuncer, Safa;Demirci, Mustafa;Serim, Merve Efe;Baydemir, Canan
    • Restorative Dentistry and Endodontics
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    • v.40 no.4
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    • pp.255-261
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    • 2015
  • Objectives: The aim of this study was to evaluate the effect of three different drinks on the color parameters of four different restorative materials. Materials and Methods: Three different composites (Filtek Ultimate Universal Restorative, Filtek Ultimate Flowable, and Filtek Silorane, 3M ESPE) and a polyacid-modified composite resin material (Dyract XP, Dentsply DeTrey GmbH) were evaluated. Eighty-four disc-shaped specimens of 8 mm in diameter and 2 mm in thickness were prepared (n = 21 each). Color coordinates ($L^*a^*b^*$, ${\Delta}L^*$, ${\Delta}a^*$, ${\Delta}b^*$, and ${\Delta}E^*$) were measured using a $V{\dot{I}}TA$ Easyshade Compact ($V{\dot{I}}TA$ Zahnfabrik) after 24 hr of storage (baseline) and after 30 day of storage in three different beverages of black tea, Coca cola, or water (control) (n = 7). In each beverage, the specimens were stored three times a day, one hr each, for 30 day. The color changes (${\Delta}E$) were calculated and were analyzed by Kruskal-Wallis and Dunn multiple comparison test. Results: The color difference (${\Delta}E^*$) of the resin materials ranged between 1.31 and 15.28 after 30 day of immersion in the staining solutions. Dyract XP in Coca cola ($15.28{\pm}2.61$) and black tea ($12.22{\pm}2.73$) showed the highest mean ${\Delta}E^*$ value after 30 day, followed by Filtek Ultimate Universal Restorative ($5.99{\pm}1.25$) and Filtek Ultimate Flowable ($4.71{\pm}1.40$) in black tea (p < 0.05). Conclusions: The compomers displayed unacceptable color changes at the end of 30 day in all beverages. Among resin composites, the silorane based composite exhibited relatively good color stability than the others. Filtek Ultimate Universal Restorative and Filtek Flowable showed similar color changes in all beverages.