• Title/Summary/Keyword: $^{235}U$

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A RAPID DETERMINATION OF $U^{235}$ CONTENTS OF URANIUM SAMPLES UTILIZING HIGH RESOLUTION Ge(Li) DETECTOR (고분해능 Ge(Li) 검출기를 이용한 Uranium 시료내의 $U^{235}$ /$U^{238}$ 함유량의 신속측정)

  • 정문규;조성원;서두환
    • Nuclear Engineering and Technology
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    • v.1 no.1
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    • pp.33-38
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    • 1969
  • Determinations of the isotopic contents of U$^{235}$ and U$^{238}$ in ten uranium samples containing 0.72-89.70 at % U$^{235}$ were carried out in two ways utilizing high resolution Ge (Li) gamma-ray spectrometer. One method is based upon the fact that the intensity of 185.5 kev gamma-ray vary linearly with U$^{235}$ content for a given geometry. Another method applied for the direct determination of the U$^{235}$ / U$^{238}$ isotopic ratios is the precision gamma-ray spectrometric analysis of reactor irradiated uranium samples after allowing a fixed cooling time for one hour. The results obtained by both methods well agree with the values calculated from the isotopic contents of highly enriched original uranium samples measured by mass spectrometer. The precision obtained was well below 5% for most of the isotopic ratios investigated.

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COMPARATIVE ANALYSIS OF STRUCTURAL CHANGES IN U-MO DISPERSED FUEL OF FULL-SIZE FUEL ELEMENTS AND MINI-RODS IRRADIATED IN THE MIR REACTOR

  • Izhutov, Aleksey.L.;Iakovlev, Valeriy.V.;Novoselov, Andrey.E.;Starkov, Vladimir.A.;Sheldyakov, Aleksey.A.;Shishin, Valeriy.Yu.;Kosenkov, Vladimir.M.;Vatulin, Aleksandr.V.;Dobrikova, Irina.V.;Suprun, Vladimir.B.;Kulakov, Gennadiy.V.
    • Nuclear Engineering and Technology
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    • v.45 no.7
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    • pp.859-870
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    • 2013
  • The paper summarizes the irradiation test and post-irradiation examination (PIE) data for the U-Mo low-enriched fuel that was irradiated in the MIR reactor under the RERTR Program. The PIE data were analyzed for both full-size fuel rods and mini-rods with atomized powder dispersed in Al matrix as well as with additions of 2%, 5% and 13% of silicon in the matrix and ZrN protective coating on the fuel particles. The full-size fuel rods were irradiated up to an average burnup of ${\sim}60%^{235}U$; the mini-rods were irradiated to an average burnup of ${\sim}85%^{235}U$. The presented data show a significant increase of the void fraction in the U-Mo alloy as the U-235 burnup rises from ~ 40% up to ~ 85%. The effect of irradiation test conditions and U-235 burnup were analyzed with regard to the formation of an interaction layer between the matrix and fuel particles as well as generation of porosity in the U-Mo alloy. Shown here are changes in distribution of U fission products as the U-235 burnup increases from ~ 40% up to ~ 85%.

Oxidation Experiment of U-Ti Chip for the Treatment of Depleted Uranium Waste (감손우라늄 폐기물 처리를 위한 U-Ti 칩의 산화실험)

  • 강권호;정경환;문제선;김길정
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.103-106
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    • 1999
  • 감손우라늄(depleted uranium, DU)은 천연 우라늄에서 핵분열 물질인 U-235를 농축하는 과정에서 발생한다. U-235의 농도가 0.45%인 감손우라늄의 비방사능은 천연우라늄의 약70.8%에 분과하나 감손우라늄은 밀도가 19g/㎤으로 높고 천연우라늄에 비해 U-235의 농도가 상대적으로 낮기 때문에 외국의 경우는 방사선의 차폐체, 비행기나 헬리콥터 및 미사일의 무게중심제(counter-weight)로 사용되며 또한 플라이 휠 등 큰 내부에너지 저장을 위한 장치 등에 널리 이용되고 있다.(중략)

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COMPARISON OF NEUTRONIC BEHAVIOR OF UO2, (TH-233U)O2 AND (TH-235U)O2 FUELS IN A TYPICAL HEAVY WATER REACTOR

  • MIRVAKILI, SEYED MOHAMMAD;KAVAFSHARY, MASOOMEH ALIZADEH;VAZIRI, ATIYEH JOZE
    • Nuclear Engineering and Technology
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    • v.47 no.3
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    • pp.315-322
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    • 2015
  • The research carried out on thorium-based fuels indicates that these fuels can be considered as economic alternatives with improved physical properties and proliferation resistance issues. In the current study, neutronic assessment of $UO_2$ in comparison with two $(Th-^{233}U)O_2$, and $(Th-^{235}U)O_2$ thorium-based fuel loads in a heavy water research reactor has been proposed. The obtained computational data showed both thorium-based fuels caused less negative temperature reactivity coefficients for the modeled research reactor in comparison with $UO_2$ fuel loading. By contrast, $^{235}U$-containing thorium-based fuel and $^{235}U$-containing thorium-based fuel loadings in the thermal core did not drastically reduce the effective delayed neutron fractions and delayed neutron fractions compared to $UO_2$ fuel. A provided higher conversion factor and lower transuranic production in the research core fed by the thorium-based fuels make the fuel favorable in achieving higher cycle length and less dangerous and costly nuclear disposals.

A Review on Analysis of Natural Uranium Isotopes and Their Application (우라늄 동위원소의 분석과 활용에 대한 고찰)

  • Yeongmin Kim
    • Economic and Environmental Geology
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    • v.56 no.5
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    • pp.547-555
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    • 2023
  • Due to enhanced precision in uranium isotope measurements with MC-ICP-MS, there has been a surge in studies concerning the naturally occurring uranium isotope ratio (238U/235U) and its associated fractionation processes. Several researchers have highlighted that the 238U/235U ratio, previously assumed to be constant, can vary by several per mil depending on different natural fractionation processes. This review paper outlines the uranium isotope values (δ238U) for major terrestrial reservoirs and their variations. It discusses the range of δ238U values and uranium isotope fractionation seen in uranium ore deposits, based on deposit type and ore-forming conditions. In conclusion, this paper emphasizes the importance of studies on uranium ore deposits. Such deposits serve as natural simulation models vital for designing high-level radioactive waste repository sites.

Estimation of Discharged Amounts of U and Pu Nuclides from the PWR Spent Fuels in Korea (국내 가압 경수형 원자로의 사용후 핵연료에서 잔류하는 U과 Pu핵종의 발생량 추정)

  • Lim, Chae-Jun;Kang, Chang-Sun
    • Nuclear Engineering and Technology
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    • v.20 no.3
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    • pp.165-169
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    • 1988
  • As a part of tandem fuel cycle feasibility study, the residual U and Pu nuclide contents of PWR spent fuels are computed using ORICEN2 code for each Korea Nuclear Unit and batch to investigate the potential of utilizing them as CANDU fuels. The annual and accumulated discharged amounts of U and Pu nuclides are computed for the PWRs from KNU 1 through KNU 10. The results of computation show that the spent fuels having 0.7-0.8 w/o U-235 are dominant and considerable amounts of fissile Pu are produced. The enrichment of U-235 is less than the expected 0.8-0.9 w/o U-235 since the burnups offered by KEPCO are higher than those of other PWRs.

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Sensitivity Analysis of the Criticality Evaluation Concerning Pyroprocess

  • Gao, Fanxing;Ko, Won-Il;Park, Chang-Je;Lee, Ho-Hee
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2010.05a
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    • pp.271-272
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    • 2010
  • Sensitivity analysis by TSUNAMI clarifies the complex effects of key nuclides on the criticality probability quantitatively. As discussed above, the $K_{eff}$ of $UO_2$ fuel reaches the maximum value with 42w% concentration of intrusion water. The concentration of hydrogen affects the complexity of reaching criticality by its competition between the concentrations of $^{235}U$. Approximately if the weight percent of $H_2O$ in the mixture is less than 42%, the moderation effect of hydrogen surpasses its dilution effect on $^{235}U$. However, the importance of $^{235}U$ increases dramatically when the weight percent of water is bigger than 42%. In the sensitivity evaluation of $UO_2$ fuel employing TSUMAMI, there is a similar crosspoint of the sensitivity of $^{235}U$ and the sensitivity of $^1H$ where the criticality reaches summit. And the optimal water weight percent is determined to be 50%.

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A 235U mass measurement method for UO2 rod assembly based on the n/γ joint measurement system

  • Yang, Jianqing;Zhang, Quanhu;Su, Xianghua;Li, Sufen;Zhuang, Lin;Hou, Suxia;Huo, Yonggang;Zhou, Hao;Liu, Guorong
    • Nuclear Engineering and Technology
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    • v.52 no.5
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    • pp.1036-1042
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    • 2020
  • Fast-Neutron Multiplicity Counter based on Liquid Scintillator Detector can directly measure the fast neutron multiplicity emitted by UO2 rod. HPGe gamma spectrometer; which has superior energy resolution; is routinely used for the gamma energy spectrum measurement. Combing Fast-Neutron Multiplicity Counter and HPGe γ-spectrometer, the n/γ joint measurement system is developed. The fast neutron multiplicity and gamma energy spectrum of UO2 rod assemblies under different conditions are measured by the n/γ joint measurement system. The induced fission rate and the 235U abundance, thereby the 235U mass; can be obtained for UO2 rod assemblies. The 235U mass deviation of the measured value from the reference value is less than 5%. The results show that the n/γ joint measurement system is effective and applicable in the measurement of the 235U mass in samples.

Reference Spent Nuclear Fuel for Pyroprocessing Facility Design (파이로공정 시설 개념설계를 위한 기준 사용후핵연료 선정)

  • Cho, Dong-Keun;Yoon, Seok-Kyun;Choi, Heui-Joo;Choi, Jong-Won;Ko, Won-Il
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.3
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    • pp.225-232
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    • 2008
  • An estimation has been made for inventories and characteristics of spent nuclear fuel(SNF) to be generated from existing and planned nuclear power plants based on the 3rd Basic Plan for Electric Power Demand and Supply. The characteristics under consideration in this study are dimensions, a fuel rod array, a weight, $^{235}U$ enrichment, and the discharge burnup in terms of fuel assembly. These are essentially needed for designing a pyroprocessing facility. It is appeared that the anticipated quantity by the end of 2077 is about 23,000 tU for PWR spent nuclear fuel. It is revealed that the proportion of SNF with the initial $^{235}U$ enrichment below 4.5 weight percent(wt.%) is approximately 95 % in total. For SNF with 16$\times$16 fuel rod array the proportion is expected approximately 74% in total. It appears that the average burnup of SNF will be 55 GWd/tU after the medium and/or latter part of 2010s while the average burnup is 45 GWd/tU at present. Finally, a requirement in terms of reference SNF for designing the pyroprocessing facility has been derived from the above-mentioned results. The anticipated SNF seems to be 16$\times$16 Korean Standard Fuel Assembly with a cross section of 21.4 cm$\times$21.4 cm, a length of 453 cm, a mass of 672 kg, the initial $^{235}U$ enrichment of 4.5 wt.%, and the discharge burnup of 55 GWd/tU.

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Investigation of a novel on-site U concentration analysis method for UO2 pellets using gamma spectroscopy

  • Lee, Haneol;Park, Chan Jong
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1955-1963
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    • 2021
  • As the IAEA has applied integrated safeguards and a state level approach to member states, the importance of national inspection has increased. However, the requirements for national inspection for some member states are different from the IAEA safeguards. In particular, the national inspection for the ROK requires on-site U concentration analysis due to a domestic notification. This research proposes an on-site U concentration analysis (OUCA) method for UO2 pellets using gamma spectroscopy to satisfy the domestic notification requirement. The OUCA method calculates the U concentration of UO2 pellets using the measured net X-ray counts and declared 235U enrichment. This research demonstrates the feasibility of the OUCA method using both MCNP simulation and experiment. It simulated and measured the net X-ray counts of different UO2 pellets with different U concentrations and 235U enrichments. The simulated and measured net X-ray counts were fitted to polynomials as a function of U concentration and 235U enrichment. The goodness-of-fit results of both simulation and experiment demonstrated the feasibility of the OUCA method.