• Title/Summary/Keyword: $\textrm{NO}_3$-N

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A Study on Micro Gas Sensor Utilizing $WO_3$Thin Film Fabricated by Sputtering Method (스파터링법에 의해 제작된 $WO_3$박막을 이용한 마이크로 가스센서에 관한 연구)

  • 이영환;최석민;노일호;이주헌;이재홍;김창교;박효덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.471-474
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    • 2000
  • A flat type microgas sensor was fabricated on the p-type silicon wafer with low stress S $i_3$ $N_4$, whose thickness is 2${\mu}{\textrm}{m}$ using MEMS technology and its characteristics were investigated. W $O_3$thin film as a sensing material for detection of N $O_2$gas was deposited using a tungsten target by sputtering method, followed by thermal oxidation at several temperatures (40$0^{\circ}C$~$600^{\circ}C$) for one hour. N $O_2$gas sensitivities were investigated for the W $O_3$thin films with different annealing temperatures. The highest sensitivity when operating at 20$0^{\circ}C$ was obtained for the samples annealed at $600^{\circ}C$. As the results of XRD analysis, the annealed samples had polycrystalline phase mixed with triclinic and orthorhombic structures. The sample exhibit higher sensitivity when the system has less triclinic structure. The sensitivities, $R_{gas}$ $R_{air}$ operating at 20$0^{\circ}C$ to 5 ppm N $O_2$of the sample annealed at $600^{\circ}C$ were approximately 90. 90.

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Changes of Nitrogen-Fixation Activity and Environmental Factors of Growth in Lespedeza bicolor Turcz (싸리(Lespedeza bicolor Turcz.)의 공생 질소고정활성과 생육환경요인의 변화)

  • 송승달
    • Journal of Plant Biology
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    • v.35 no.4
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    • pp.317-322
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    • 1992
  • The nitrogen fixation activity and environmental factors of Lespedeza bicli!oy Turcz, forming annual root nodules by symbiotic Rhizobium sp. were analyzed in the field conditions during the growing period. Seasunal changes of $N_2-fixation$ activity showed the maximum value of $120\;\mu\textrm{M}\;C_2_H4{\cdot}noduie\;g\;fw^{-1}{\cdot}hr^{-1}$ during the active growing period (June) and varied significantly depending on the growth phase and environmental factors. The maximum activities were attained at the conditions of pH 7, $30^{\circ}C$ of temperature, 18 Kpa of oxygen partial pressure and inhibited by water stress and nitrogen sources. The habitat soil was weak acidic and poor in nitrogen, phosphorus and organic matter contents. The leaf area ratios and chlorophyll contents were ranged from 442 to $48;\textrm{cm}^2{\cdot}g\;dw^{-1}$ and from 33 to $38\;\mu\textrm{g}\;chI{\cdot}\textrm{cm}^2$. Nitrogen contents in each organ showed the maximum of 46, 19 and $11\;mg{\cdot}g\;dw^{-1}, respectively for leaf, rool and stem in the early period. The highest phosphorus contents were 4.2, 1.2 and $0.6\;mg{\cdot}g\;dw^{-1}$, respectively for leaf. root and stem in early growing period. The allocation ratios of nitrogen quantity showed 60% for leaves and 73% for roots during the active and late growth period, and 22% [or stems in average. The allocalion ralios o[ phosphorus quantity showed 58% for leaves during the most productive period, 70% for roots in the pre-growth stage and 26% for stems in average.verage.

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Effects of Rice Hull Addition and Bin Wall Characteristics on Pig Slurry Composting Properties (왕겨 이용 방법과 옹벽이 돈분 퇴비화에 미치는 효과)

  • ;Craig, Ian P
    • Journal of Animal Environmental Science
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    • v.10 no.1
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    • pp.47-58
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    • 2004
  • This work was carried out to investigate the effects of rice hull continuously utilized and/or replenished on the composting properties and to obtain the fundamental data between an unsupported wall and a soil supported wall during the period of composting with pig slurry in winter season. There were no the temperature holding effects in soil supported wall. New compost facility design for the temperature holding effects from a soil supported wall was required. The results were as follows; 1. Composting 1㎥ of pig slurry caused to save on 0.31㎥ of bulking agent in the unsupported wall in comparison with a soil supported wall in the rice hull single addition, and 0.45㎥ in the rice hull gradual addition. 2. The pile in the rice hull single addition had a high temperature in 4 days of composting indicating $71^{\circ}C$ and had a tendency in repeating periodically between $40^{\circ}C$ and $65^{\circ}C$ till 43 days of composting. And also the temperature of the pile was maintained between $48^{\circ}C$ and $28^{\circ}C$ after 50 days of composting. The pile of a rice hull gradual addition had the lower point of the temperature high increasingly according to adding up rice hull during the 35 days of composting. 3. The pH recorded in the rice hull single addition was higher(8.35∼10.02) compared to the rice hull gradual addition(8.6∼9.8). The pile of a rice hull single addition had a tendency in abruptly decreasing pH of the unsupported wall during the period of between 0.363$\textrm m^3$ and 0.537$\textrm m^3$ as a unit of pig slurry per rice hull. EC depending upon the way in adding rice hull was changed between 1.10 mS/$\textrm {cm}^3$ and 1.87 mS/$\textrm {cm}^3$. 4. The organic matter in an unsupported wall of the hull single addition was maintained the level of 55% during the period between 0.119㎥ and 0.363㎥ as a unit of pig slurry per rice hull while in the soil supported wall between 48 and 70. Water soluble C:N ratio was maintained between 1 and 2 in the rice hull single addition, while between 1 and 3 in the rice hull gradual addition. 5. Fertilizer constituents were detected higher level in the unsupported wall than in the soil supported wall in all treatments. This was dependant upon the input of pig slurry.

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On Some Formulae for the Radioisotope Formation (I) - When a Reactor is Operated Regularly at a Certain Time Intervals-

  • Lee, Chang-Kun;Kim, Taeyoung;Yim, Yung-Chang
    • Nuclear Engineering and Technology
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    • v.3 no.3
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    • pp.148-154
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    • 1971
  • Some formulae have been derived for the handy calculation of the formation of radioisotope when a reactor is operated regularly on a usual on-off pattern. In particular, the case of isotope production with the present operation condition of tile Korean reactor, which is in operation for 8.2 hours from Monday to Thursday and is not operated on friday and Sunday but is back in operation on Saturday only for 3.2 hours, is discussed herein with special emphasis. Should there be no secondary nuclear reaction resulting in the transformation of produced nuclide, the formula for the calculation of its activity could be derived as follows: (equation omitted) where A: activity (dps), $\Phi$: neutron flux (n cm$^{-2}$ sec$^{-1}$ ), No : number of atoms before the irradiation, $\sigma$ : activation cross section ($\textrm{cm}^2$), λ : disintegration constant of the radioactiveisotope formed (hr$^{-1}$ ), t : elapsed time of target in the reactor (hr), n : number of elasped days of target in the reactor, m : number of days from the first day of sample irradiation to Friday, s, r, q: number of weekday of Friday, Saturday and Sunday, respectively. Since the above formula consists of many invariables on the whole, the activity of each radioisotope to be produced can he easily and conveniently made available from the chart in advance which is made of the invariable terms calculated.

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Effect of Temperature, pH and Salt Concnetration on formation of N-nitrosamines during Kimchi Fermentation (김치숙성중 숙성온도, pH 및 소금 농도가 니트로스아민의 생성에 미치는 영향)

  • 김준환;장영상;신효선
    • Journal of Food Hygiene and Safety
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    • v.13 no.4
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    • pp.332-336
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    • 1998
  • The effect of ripening temperature, pH and salinity on the formation of Nnitrosamine (NA) during Kimchi fermentation and in vitro was studied, respectively. During Kimchi fermentation for six weeks at cold storage temperature ($4^{\circ}C$) and room temperature ($16{\pm}2^{\circ}C$), the contents of nitrite and dimethylamine (DMA) showed variation at room temperature but no variation at cold storage temperature. The maximum generation of nitrosodimethylamine (NDMA) resulted low content ($2.69\;\mu\textrm{g}/kg$) at cold storage temperature but started to increase after one week fermentation and reached to the 18-fold higher generation ($49.6\;\mu\textrm{g}/kg$) at room temperature. During Kimchi fermentation, no correlation was observed between the variation of nitrite and DMA content and the generation of NDMA. However, pH showed effective relation to NDMA generation such as the highest NDMA generation was obtained at lowest pH 4. During in vitro test, higher temperature and lower pH resulted more NDMA generation and generation amount was affected more by pH. Also, the salinity of Kimchi provided inhibitory effects on the formation of NDMA. NDMA was produced $5.86\;\mu\textrm{g}/kg$ at normal salinity (2.5%) but $90.9\;\mu\textrm{g}/kg$ at lower salinity (15%) after three week. The higher salinity showed lower formation of NDMA in vitro test, too.

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Removal of NOx and $SO_2$ from Combustion Flue Gases by Corona Discharge Systems (코로나 방전 시스템을 이용한 연소가스중의 NOx, $SO_2$제거)

  • 박재윤
    • Electrical & Electronic Materials
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    • v.10 no.8
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    • pp.830-835
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    • 1997
  • In this study an experimental investigation has been conducted to remove NOx and SO$_2$simultaneously from a combustion flue gases were consisted of NO-SO$_2$-$CO_2$-$N_2$-O$_2$([NO]o:200ppm and [SO$_2$]o:800ppm) and the injection gases used as radical source gases were NH$_3$-Ar-air and CH$_4$-Ar-air. NOx and SO$_2$removal efficiency and the other by-products were measured by Fourier Transform Infrared(FTIR) as well as SO$_2$, NOx and NO$_2$gas detectors. and SEM images after sampling. The results showed that a significant Nucleating Particle Counter(CNPC) and SEM images after sampling. The results showed that a significant aerosol particle formation was observed during a simultaneous NOx and SO$_2$removal operation in corona radical shower systems. The diameter of aerosol particles was in the range of 0.18 to 3.6${\mu}{\textrm}{m}$ with a maximum fraction of particles at particles diameter of 1${\mu}{\textrm}{m}$. The NOx removal efficiency significantly increased with increasing applied voltage and NH$_3$molecule ratio. The SO$_2$removal efficiency was not significantly effected by applied voltage and slightly increased with increasing NH$_3$molecule ratio. It could be found that it is possible to use CH$_4$for NOx and SO$_2$removal by corona radical shower systems.

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Characteristics of Acidic Air Pollutants and $PM_{2.5}$ Species in Seoul-Metropolitan Areas Using an ADS (Annular Denuder System을 이용한 수도권지역의 산성오염물질 및 $PM_{2.5}$ 성분농도 특성)

  • 강충민;이승일;조기철;안준영;최민규;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.3
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    • pp.305-315
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    • 1999
  • The annular denuder system(ADS) was used to determine characteristics of acidic air pollutants and $PM_{2.5}$ species in Seoul-metropolitan areas. All measurements were done simultaneously in downtown(Kwanghwamun, Mullae, Chamshil, Ssangmun dongs) and outskirts(Puch n, Kuri cities) during four seasons. The samples were analyzed using ion chromatography for gas-phase matters(HCl, $HNO_2$, $HNO_3$ and $SO^2$) and particulate phase matters($Cl^-$, $NO^{2-}$, $NO_3^-$, $SO_4^{2-}$, $Na^+$, $NH_4^-$ and $Ca^{2+}$) and was measured fine particles($PM_{2.5}$). The seasonal mean concentrations of HCl, HNO2, HNO3 and SO2 in downtown and outskirt areas were very similar. All chemical species monitored from this study showed seasonal variations. Nitric acid(HNO3) and Nitrous acid(HNO2) were showed higher concentrations during the summer. $PM_{2.5}$, $SO_4^{2-}$, $NH_4^-$, $NO_3^-$ and $Cl^-$ in the particulate phase matters were higher levels during the winter months. The concentrations of these components were 54.8, 3.82, 2.49, 1.80 and 1.02$\mu\textrm{g}$/㎥, respectively.

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Preparation of $\textrm{BaTiO}_3$ Thin Films by Electrochemical Method (전기화학법을 이용한 $\textrm{BaTiO}_3$박막의 제조)

  • Gong, Pil-Gu;Yoo, Young-Sung;Lee, Jong-Kook;Kim, Hwan;Park, Soon-Ja
    • Korean Journal of Materials Research
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    • v.7 no.2
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    • pp.114-120
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    • 1997
  • Perovskite $BaTiO_3$ thin films on stainless steel substrate were prepared by using electrochemical reduction method in solution of $TiCl_4\;and\;Ba(N0_3)_2$. According to current density and electrolysis time. the morphology and thickness of film were varied. Ra/'Ti atomic ratio in $BaTiO_3$ film was controlled by Ha/Ti atomic ratio in solution. Although the excess $TiO_2{\cdot}nH_2O$ film was coated in initial stage of electrolysis. UiilTi atomic ratio in film was nearly constant in later stage. $BaTiO_3$ film precursor was obtained under the condition of $1OmA/cm^2$ current density and Smin electrolysis time. $BaTiO_2$ thin films with perovskite phase were formed 11,. the heat treatment above $500^{\circ}$.

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Production of Purplish-red Pigment in Mixed Culture of Streptomyces propurpuratus ATCC 21630 and Bacillus sp. R-89 (Streptomyces propurpuratus ATCC 21630 Bacillus sp. R-89의 혼합배양에 의한 적자색 색소의 생산)

  • Ho, Ryu-Beung;Park, Bub-Gyu;Chi, Young-Eh;Lee, Ju-Hwa
    • Microbiology and Biotechnology Letters
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    • v.17 no.4
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    • pp.327-333
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    • 1989
  • The purplish-red pigment was formed on agar plate by superimposed streaking of Streptomyces propurpuratus ATCC 21630 and strain R-89, The strain No.89 was ascribable to the genus Bacillus and designated as Bacillus sp. R-89. Both strain did not produced such pigment when cultivated independently. For hyperpigment production, we selected the mutant S.P-6 from Streptomyces propurpuratus ATCC 21630 by MNNG (N-methyl-N'-nitro-N-nitrosoguanidine) treatment. Maximum purplish-red pigment 1420 mg/$m\ell$ were produced, when the mutant of R-16 and Bacillus sp. R-89 were mixed cultured at 3$0^{\circ}C$ for 72 hr.

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Protective Effect of Coptidis Rhizoma on SNAP-Induced Cytotoxicity in Pancreatic RINm5F Cells (SNAP 유도성 RINm5F 세포 독성에 대한 황연 추출물의 방어효과)

  • 류도곤;권강범;양정예;김은경;김강산
    • The Journal of Korean Medicine
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    • v.24 no.2
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    • pp.159-165
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    • 2003
  • Objectives : Coptidis rhizoma (CR) is an oriental medicine that has been used in many traditional prescriptions against diabetes mellitus in Korea for centuries. Our purpose was to determine the protective effect and its action mechanism of CR on the cytotoxicity of pancreatic -cell line (RINm5F cell). Methods : In this experiment, we used methods such as MTT assay for detection of cytotoxicity, DNA fragmentation assay for detection of apoptotic cell death, LDH activity assay for detection of necrotic cell death, and measurement of $DiOC_{6}$ (3) retention for detection of mitochondrial membrane potential (MMP). Background : Nitric oxide (NO) is believed to playa key role in the process of pancreatic -cell destruction leading to insulin-dependent diabetes mellitus (IDDM). Results : Exposure of RINm5F cells to chemical NO donor such as S-nitroso-N-acetylpenicillamine (SNAP) induced cytotoxic events such as DNA fragmentation and lactate dehydrogenase (LDH) release into medium. However, pretreatment of RINm5F cells with CR extract ($10~50{\mu\textrm{g}}/ml$) for 3 hours prevented SNAP-induced DNA fragmentation and LDH release into medium through the inhibition of MMP disruption. Conclusions : These results suggest that CR may be a candidate for a therapeutic or preventing agent against IDDM.

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