• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1995년도 추계학술발표회논문집(2)
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• pp.747-752
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• 1995

핵융합로 증식재용 ${\gamma}$-LiAlO$_2$ 분말을 자발착화 연소반응법을 적용하여 합성하였다. LiAlO$_2$분말을 합성하는데 이 방법을 적용하면 다른 분말 합성법과 달리 짧은 시간 내에 미세한 ${\gamma}$상을 쉽게 형성할 수 있었다. 최적의 ${\gamma}$-LiAlO$_2$ 분말을 합성하려면 구연산과 우레아의 혼합연료가 가장 적절하다고 판단되며, 이 연료로 합성된 ${\gamma}$-LiAlO$_2$ 분말을 24시간 볼분쇄하면 비표면적 값이 15.8 m$^2$/g인 미세한 분말을 얻을 수 있었다.

• 한국세라믹학회지
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• 제34권3호
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• pp.303-313
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• 1997

용융탄산염 연료전지(Molten Carbonate Fuel Cell) 메트릭스의 성형성 및 강도 증진을 위한 알루미나/${\gamma}$-LiAlO2 화이버 강화 매트릭스에 대하여 연구하였다. ${\gamma}$-LiAlO2 입자에 10~30wt%의 화이버를 첨가한 슬러리를 테이프캐스팅 한 후 $650^{\circ}C$까지 열처리하여 두께가 500~600$\mu\textrm{m}$인 MCFC 매트릭스를 제조하였다. 화이버의 첨가량이 증가할수록 매트릭스의 기공율은 감소하였으나 입자크기가 대략 50$\mu\textrm{m}$인 ${\gamma}$-LiAlO2 분체의 첨가비를 50wt%까지 증가시킴으로써 MCFC 매트릭스에 적합한 기공율(50~60%)을 얻을 수 있었다. 알루미나 화이버의 첨가량이 20wt% 이고 길이가 250$\mu\textrm{m}$이하인 화이버를 사용하였을 때 매트릭스내의 분산성 및 강도 증진 효과가 가장 우수하였다. 반면에 본 연구에서 제조한 ${\gamma}$-LiAlO2 화이버를 이용한 강화 매트릭스의 강도(156 gf/$\textrm{mm}^2$)는 알루미나 화이버 강화 매트릭스에 비해 20~40% 정도 증진되었다. 또한 알루미나 화이버 강화 매트릭스는 용융탄산염에 의하여 부식되지만 ${\gamma}$-LiAlO2 화이버 강화 매트릭스는 전혀 부식되지 않음을 알 수 있었다.

• 한국세라믹학회지
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• 제32권2호
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• pp.197-208
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• 1995

${\gamma}$-LiAlO2 fibers for fiber reinforced molten carbonate fuel cell (MCFC) matrix have been produced from LiAlO2 complex polymeric sols using the sol-gel process. The stable and spinnable LiAlO2 sols could be synthesized by mixing LiNO3 alcohol solutions in aluminum complex polymeric sols prepared through the condensationpolymerization reaction of 1 more of aluminum tri-sec-butoxide with 0.55 mole of mixed chelates (mole ratio of acetylaceton/triethanolamine=0.25/0.3). It was found that the viscosity range for fiber-spinning should be higher than 30 poise. The defect-free flexible ${\gamma}$-LiAlO2 fibers with the average tensile strength of 350 MPa could be obtained when the spinned fibers were heat-treated to 120$0^{\circ}C$ on the specified heating schedule after dried at room temperature.

• 한국세라믹학회지
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• 제31권11호
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• pp.1271-1282
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• 1994

The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${\gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${\gamma}$-LiAlO2 sol was completely transformed into the ${\gamma}$-LiAlO2 at $600^{\circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${\gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{\circ}C$.

• 한국세라믹학회지
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• 제33권10호
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• pp.1079-1088
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• 1996

Discontinuous ${\gamma}$-LiAlO2 fibers for fiber-reinforcing MCFC matrixes have been produced by the sol-gel process using the centrifugal spinning apparatus of the Rotary type. Gel fibers could be obtained through spinning of stable LiAlO2 complex polymetric sols under the optimum spinning conditions (hollow-disc rotating velocity 9000 rpm sol feeding rate of 4ml/min flowing N2 temperature of 4$0^{\circ}C$ and flowing N2 pressure of 4 bar). It was found that defect free and densified ${\gamma}$-LiAlO2 fibers with the relative density of 98% and the mean diameter of 4.7${\mu}{\textrm}{m}$ were prepared when the spinned fibers were heat-treated to 100$0^{\circ}C$ on the specified heating schedule. in particular the mean diameter and length of fibers could be controlled by the pressure of flowing N2 and the chopping-sieving method respectively.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2005년도 수소연료전지공동심포지움 2005논문집
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• pp.115-122
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• 2005

• 한국세라믹학회지
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• 제36권4호
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• pp.360-365
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• 1999

The combustion process was applied to synthesize the LiAlO2 powder with high specific surface area and pure crystalline ${\gamma}$-phase. For the combustion synthesis of LiAlO2 which is a binary-component oxide in-cluding lithium and aluminum ions the mixture of citric acid and urea with stoichiometric composition was selected as a promising fuel. The highest combustion temperature was measured in the reaction using the mixed fuel with a stoichiometric composition. The synthesized powder was very fine and its specific surface area was more than 15 m2/g.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
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• pp.25.2-25
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• 2003

• 한국세라믹학회지
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• 제46권3호
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• pp.282-287
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• 2009

Rod-shaped particle reinforced $LiAlO_2$ matrices for MCFC were fabricated by an aqueous tape-casting technique. The hydrolysis reaction and agglomeration of $\gamma-LiAlO_2$ particles in aqueous slurries were inhibited by additions of $LiOH{\cdot}H_2O$ and glycerin to the aqueous $\gamma-LiAlO_2$ slurry. The tape-casting, performed using the aqueous slurry containing protein albumin, was fast and led to an effective drying at casting temperature range of $60{\sim}65^{\circ}C$. The strength of the particle reinforced matrix was improved about 4 times compared to that of matrix without reinforcement. Pore size distribution ($0.1{\sim}0.4{\mu}m$) and porosity ($50{\sim}60%$) of the reinforced matrices were determined to be appropriate for the MCFC matrix. The aqueous tape casting process is not only environmental-friendly but also efficient for fabricating MCFC matrices compared to non-aqueous tape casting.

• 한국의학물리학회지:의학물리
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• 제5권2호
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• pp.13-20
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• 1994

본 연구에서는 감마선 조사, 전자선 조사방법에 의한 전자만의 주업 및 이온 주업 후 전자선조사 방법으로 전자들이 주입된 $\alpha$-$Al_2O_3$의 열자극 발광(Thermoluminescence : TL)에 관련된 결함 형태를 조사하였다. 감마선 조사된 $\alpha$-$Al_2O_3$의 열자극 발광 곡선은 380K, 415K, 440K, 460K 및 475K에서 TL peak가 나타났다. 광흡수 스펙트럼과 자외선 photobleaching 결과로부터 감마선 조사된 $\alpha$-$Al_2O_3$의 380K와 475K TL peak는 F center에, 415K TL peak는 $F^{+}$ center에 기인함을 알았다. 전자선 조사방법에 의하여 전자 주입된 $\alpha$-$Al_2O_3$의 열자극 발광 곡선은 380K, 415K, 440K 및 460K TL peak를 가졌고, $Li^{+}$ 이온 주입 후 전자선 조사방법으로 전자들이 주입된 $\alpha$-$Al_2O_3$는 440K에서 TL peak가 나타났다. 전자선 조사방법에 의한 전자만의 주입과 $Li^{+}$ 이온 주입 후 전자선 조사방법으로 전자들이 주입된 $\alpha$-$Al_2O_3$의 열자극 발광 특성은 380K TL peak는 F center에, 440K TL peak는 $F^{+}$ center에 기인함을 보였다.