• Title/Summary/Keyword: $\Omega$ Type

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Synthesis and Characterization of New Thermotropic Liquid Crystalline Polyurethanes with Naphthalene Moiety (나프탈렌기를 갖는 새로운 액정폴리우레탄의 합성 및 특성)

  • Lee, Jong-Baek;Lee, Kwang-Hyun
    • Elastomers and Composites
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    • v.40 no.1
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    • pp.37-44
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    • 2005
  • Novel polyurethanes containing no mesogenic unit were synthesized by the polyaddition reaction of para-type diisocyanates such as 2,5-tolylene diisocyanate (2,5-TDI) or 1,4-phenylene diisocyanate (1,4-PDI) with 2,6-bis(${\omega}$-hydroxyalkoxy)naphthalene (BHNm; m= 5, 6, 8, 11). Intrinsic viscosities of the polymers were in the range of 0.28-0.43 dL/g. The thermal properties of these polymers were studied by differential scanning calorimetry and polarizing microscopy. Polyurethanes prepared from BHNm and 2,5-TDI haying methyl substituent on the phenylene unit exhibited monotropic liquid crystallinity. However, in the series of polyurethanes prepared from 1,4-PDI and BHNm, no explicit mesomorphic behavior was observed by differential scanning calorimetry and polarizing microscopy.

Fabrication and Characteristics of Mather Type Plasma Focus System (마더형 플라즈마 집속장치의 제작과 특성)

  • 김동환;이상수;조성국;김규욱;이민희
    • Korean Journal of Optics and Photonics
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    • v.1 no.1
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    • pp.65-72
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    • 1990
  • Mather type plasma focus system is designed and fabricated, and its electrical behaviors and the ,~haracteristics of the plasma are investigated. The discharge CUlTent is measured with a Rogowski coil, and the external resistance and inductance of the system are found to be $20m\Omega, 0.2{\mu}H respectively from the measured voltage signals and current signals, and discharge inductance, magnetic, and mechanical energy are calculated. 'i'he speed of the plasma current sheath in the acceleration phase is found to vary as $P^{-0.25}\timesV^{0.38}$ and its value is about is 106 cm/sec. The electron temperature in the plasma is determined from the measurement of the X-ray transmittance with the number of X-ray filters and its value is found to be about I keY. The size of plasma, measured using X-ray pin-hole camera, is about 17 (dia.) x 30 (length)mm2. h)mm2.

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The Design of Bandpass Filter with Improved Return Loss at the Stopband (저지대역 반사특성을 개선한 대역통과 여파기 설계)

  • 조정훈;황희용
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2002.11a
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    • pp.434-444
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    • 2002
  • 본 논문에서는 기존의 RF 여파기가 대역 내에서만 정합이 되는 특성을 개선하여 대역 외에서도 50$\Omega$ 정합 특성을 가지는 여파기 설계 기술을 제안하였다. 대역 외에서 정합 시켜 주는 방법으로 결합기와 대역 통과 여파기로 구성된 Balance Type과 결합기와 대역 저지 여파기로 대역 통과 여파기 특성을 가지는 Reflection Type을 제시하여 그 특성을 확인하였다. 각각의 형태는 광대역 90도 3-㏈ 결합기를 사용한 것으로 결합기의 대역폭과 진폭 및 위상 오차에 따라 저지 대역에서의 정합 특성이 좌우되며, 이에 광대역의 3-㏈ 결합기를 설계 및 적용하여 광대역의 반사 손실 개선 효과를 얻을 수 있었다. 제작 결과 Balance type의 경우 1.2 GHz~2.6GHz까지 대역 내에서 -10㏈에서 -15 ㏈의 반사 손실 특성을 가지고 대역 저지 특성이 우수하며, Reflection type은 DC에서 3.3GHz까지 반사손실이 -15 ㏈ 내외로 광대역 정합 특성을 가진다. 특히, 저주파 반사 특성이 우수하여 저주파 발진 가능성이 큰 회로 설계에 유용하다.

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알루미늄이 도핑된 후면 에미터 구조의 n-type 실리콘 태양전지 제작 및 최적화 연구

  • Kim, Yeong-Do;Lee, Gyeong-Dong;Kim, Seong-Tak;Kim, Hyeon-Ho;Bae, Su-Hyeon;Park, Seong-Eun;Tak, Seong-Ju;Kim, Dong-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.208-208
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    • 2012
  • 알루미늄이 도핑된 p+후면 에미터 구조를 갖는 n-type 결정질 실리콘 태양전지를 제작하였다. 기판으로는 n-type Cz 실리콘 웨이퍼가 사용되었으며 크기, 두께 및 비저항은 각각 6"x 6", $200{\mu}m$, $3{\sim}5{\Omega}cm$이었다. 실험을 통하여 에너지 변환 효율 17.5%를 얻었다. 모든 공정은 p-type 실리콘 상용 태양전지 제작에 쓰이는 것과 동일하게 적용하였다. 또한 PC1D 시뮬레이션을 통하여 전면 전계의 두께 및 피크 농도, 기판의 소수 운송자 수명, 후면 에미터의 도핑 농도, 실리콘 기판의 두께를 변수로 하여 후면 에미터 구조의 n-type 실리콘 태양전지의 최적화 작업을 실시하였다.

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The Fabrication and Characteristics of RTD(Resistance Thermometer Device) for Micro Thermal Sensors (마이크로 열 센서용 측온저항체 온도센서의 제작 및 특성)

  • Chung, Gwiy-Sang;Hong, Seog-Woo
    • Journal of Sensor Science and Technology
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    • v.9 no.3
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    • pp.171-176
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    • 2000
  • The physical and electrical characteristics of MgO and Pt thin-films on it, deposited by reactive sputtering and rf magnetron sputtering, respectively, were analyzed with annealing temperature and time by four-point probe, SEM and XRD. Under annealing conditions of $1000^{\circ}C$ and 2 hr, MgO thin-film had the properties of improving Pt adhesion to $SiO_2$ and insulation without chemical reaction to Pt thin-film, and the sheet resistivity and the resistivity of Pt thin-film deposited on it were $0.1288\;{\Omega}/{\square}$ and $12.88\;{\mu}{\Omega}{\cdot}cm$, respectively. We made Pt resistance pattern on $SiO_2$/Si substrate by lift-off method and fabricated thin-film type Pt-RTD(resistance thermometer device) for micro thermal sensors by Pt-wire, Pt-paste and SOG(spin-on-glass). In the temperature range of $25{\sim}400^{\circ}C$, the TCR value of fabricated Pt-RTD with thickness of $1.0{\mu}m$ was $3927\;ppm/^{\circ}C$ close to the Pt bulk value. Resistance values were varied linearly within the range of measurement temperature.

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Resistive Humidity Sensor from Copolymers Containing Quaternary Ammonium Salt (II): Four Component Copolymers (4차 암모늄염을 포함하는 공중합체를 이용한 저항형 습도센서 (II) : 4원 공중합체)

  • Lee, Dong-Geun;Lim, Tae-Ho;Jeon, Young-Min;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.302-307
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    • 2007
  • The resistive-type humidity sensors were prepared from the copolymers of [2-[(methacryloyloxy)ethyl]dimethyl]propylamonium bromide (MEPAB), [2-[(methacryloyloxy)ethyl]-2-hydroxyethyl]dimethylammonium bromide (MEHDAB), 2- [(methacryloyloxy)ethyl]trimethylammonium chloride (METAC), and n-butyl methylacrylate (MBA). Four component copolymers MEPAB/BMA/MEHDAB/METAC=4/4/1/1, 3/5/1/1, 2/6/1/1, 1/7/1/1 crosslinked with blocked-isocyanate on Ag/Pd electrode/alumina substrate showed a good durability at high humidities. The various electrical properties such as frequency dependency, temperature dependency, hysteresis, response time and water durability were examined. In the case of copolymer composed of MEPAB/BMA/MEHDAB/METAC=2/6/1/1, the resistance varied from $1.4\;M{\Omega}$ to $2.9\;k{\Omega}$ at $25^{\circ}C$ in the range of $30{\sim}90\;%RH$ and this copolymers showed a good linearity and low hysteresis.

Flexural Capacity and CO2 Reduction Evaluation for Composite Beam with Weight Reducing Steel Wire-Integrated Void Deck Plate slab (자중저감 철선일체형 중공 데크플레이트 슬래브를 사용한 합성보의 휨내력 및 CO2 감소량 평가)

  • Kim, Sang-Seop;Park, Dong-Soo;Boo, Yoon-Seob
    • Journal of Korean Society of Steel Construction
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    • v.24 no.3
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    • pp.313-323
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    • 2012
  • The purpose of this study is to evaluate $CO_2$ reduction and the flexural performance of steel wire-integrated void deck plate slabs that were inserted in omega-shaped steel plates to reduce concrete and welded H-section beams. The void deck plate slab can secure the structure, not only reducing the weight of the building but it is also eco-friendly. Therefore, this study evaluated the flexural performance of the composite beam by conducting a monotonic loading test with the use of actuators. It quantitatively evaluated the $CO_2$ emission based on earlier studies. The main test parameters are the concrete thickness of upper slabs, and the interrupted width of the omega-shaped steel plate. The result of the test showed that the welded H-section beam applied steel wire-integrated void deck plate slabs that were inserted into the omega-shaped steel plate declined in flexural performance on the composite beam after reducing concrete volume. Likewise, it is effective in reducing $CO_2$.

Resistive Humidity Sensor from Copolymers Containing Quaternary Ammonium Salt (I): Three Component Copolymers (4차 암모늄염을 포함하는 공중합체를 이용한 저항형 습도센서(I) : 3원 공중합체)

  • Lee, Dong-Geun;Lim, Tae-Ho;Jeon, Young-Min;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.194-200
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    • 2007
  • The resistive-type polymeric humidity sensors were prepared from the copolymers of [2- [(methacryloyloxy)ethyl] dimethyl] propylammonium bromide(MEPAB), [2- [(methacryloyloxy)ethyl]-2-hydroxyethyl]dimethylmonium bromide (MEHDAB), n-butyl methylacrylate(MBA), 2-hydroxyethyl methylacrylate(HEMA) and styrene. Four kinds of copolymers, ie, MEPAB/styrene/MEHDAB MEHDAB/BMA/HEMA, MEPAB/BMA/MEHDAB, and MEPAB/styrene/HEMA crosslinked with blocked-isocyanate on the Ag/Pd electrode/alumina substrate showed good durability at high humidities. The various electrical properties such as frequency dependency, temperature dependency, hysteresis, response time and water durability were examined. In the case of copolymer MEPAB/BMA/MEHDAB= 3/6/1, the resistance was varied from $2.9 M{\Omega}$ to $1.84k{\Omega}$ at $25^{\circ}C$ in the range of $30{\sim}90%RH$ and this copolymers showed a good linearity and low hysteresis.

Mechanism on the Hydrolysis of Cinnamonitrile in Strong Acid (强酸性 溶液中에서 Cinnamonitrile의 加水分解 反應메카니즘)

  • Ki-Sung Kwon;Nack-Do Sung;Tae-Rin Kim;Jeon, Yong Gu
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.418-424
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    • 1984
  • Rate constants for the hydrolysis of cinnamonitrile in the concentration range of 1 ∼ 5M of perchloric acid at 25$^{\circ}$C have been determined by UV spectrophotometry and from the Bunnett equations, hydration parameters (${\omega}$ = 9.8, ${\omega}^*$ = 0.42 & ${\phi}$=1.6) were obtained. CNDO/2 MO calculations were performed to determine relative stability, net charges, and overlap population of various conformational isomers. The results show that the (E)-planar is more stable than the (Z)-planar and protonation is favored on the nitrogen atom. On the basis of above findings, the acid hydrolysis is initiated by the protonation of the nitrogen atom of cinnamonitrile and then water molecule acting as nucleophile and as a proton transfer agent in the rate determining step. In the transition state of the acid hydrolysis, nucleophilic addition of water molecule occurs by sigma approach to the positively charged $C_7({\alpha}$) atom of the conjugate acid. As the results, we may conclude that the hydrolysis of cinnamonitrile in the strong acidic media proceeds through the A-2 type mechanism.

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Quantum Interference Experiments with Frequency Entangled Photon Pairs at 1.5 ㎛ Telecommunication Band (1.5 ㎛ 통신파장대역 진동수 얽힘 광자쌍의 양자간섭)

  • Kim, Heon-Oh;Kim, Yong-Soo;Youn, Chun-Ju;Cho, Seok-Beom
    • Korean Journal of Optics and Photonics
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    • v.22 no.6
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    • pp.276-282
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    • 2011
  • We performed experiments on Hong-Ou-Mandel type two-photon interference with frequency entangled photon pairs at 1.5 ${\mu}m$ telecommunication band generated through femtosecond pulsed spontaneous parametric down-conversion. Two different angular frequencies ${\omega}_1$ and ${\omega}_2$ were selected using CWDM(coarse wavelength division multiplexing) filters at the output ports of the interferometer. The coincidence counting rates were measured with varying path-length difference between the two interferometer arms to observe the two-photon interference patterns of spatial beating. The obtained visibilities in the net coincidence were close to the theoretical limit of 100%.