• Title/Summary/Keyword: $[Cl^-]/[OH^-]$ ratio

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Development of Hydrogels to Improve the Safety of Yukhoe (Korean Beef Tartare) by Reducing Psychrotrophic Listeria monocytogenes Cell Counts on Raw Beef Surface

  • Oh, Hyemin;Kim, Sejeong;Lee, Soomin;Ha, Jimyeong;Lee, Jeeyeon;Choi, Yukyung;Lee, Yewon;Kim, Yujin;Seo, Yeongeun;Yoon, Yohan
    • Food Science of Animal Resources
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    • v.38 no.6
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    • pp.1189-1195
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    • 2018
  • This study developed an antimicrobial hydrogel to control Listeria monocytogenes in Yukhoe (Korean beef tartare). Four hydrogels (hydrogel 1: 5% alginate+1% chitosan+0.2% $CaCl_2$, hydrogel 2: 1% ${\kappa}$-carrageenan+1% chitosan, hydrogel 3: 2% ${\kappa}$-carrageenan+1% $CaCl_2$, and hydrogel 4: 2% ${\kappa}$-carrageenan+3% $CaCl_2$) were prepared. The hydrogels then absorbed 0.1% grapefruit seed extract (GSE) and 0.1% citrus extract (CE) for 30, 60, 120, and 240 min to be antimicrobial hydrogels. To select the most effective antimicrobial hydrogel, their swelling ratio (SR) and antilisterial activities were determined. The selected hydrogel ($2{\times}2cm$) was then placed on surface of beef (round; $3{\times}3cm$), where L. monocytogenes (ca. $10^6CFU/g$) were inoculated, and the cell counts were enumerated on PALCAM agar. Among the hydrogels, the SR of hydrogel 1 increased with absorbing time, but other hydrogels showed no significant changes. Antimicrobial hydrogel 1 showed higher (p<0.05) antilisterial activity than other antimicrobial hydrogels, especially for the one absorbed the antimicrobial for 120 min. Thus, the antimicrobial hydrogel 1 absorbed antimicrobials for 120 min was applied on raw beef at $4^{\circ}C$, and reduced (p<0.05) more than 90% of L. monocytogenes on raw beef. These results indicate that antimicrobial hydrogel 1 formulated with 0.1% GSE or 0.1% CE is appropriate to improve the safety of Yukhoe by reducing psychrotrophic L. monocytogenes cell counts on raw beef.

Stabilization of Arsenic in Paddy Soils Using Stabilizers (논토양 내 비소 불용화에 대한 안정화물질의 처리 효과)

  • Kang, Min Woo;Oh, Sejin;Kim, Sung-Chul;Lee, Sang Soo
    • Korean Journal of Environmental Agriculture
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    • v.38 no.1
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    • pp.17-22
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    • 2019
  • BACKGROUND: Soil contamination of As is a very sensitive environmental issue due to its adverse impact on human health and different characteristics with other heavy metals. With public awareness of As poisoning, there has been growing interest in developing guideline and remediation technologies for As-contaminated soil. The objective of this research was to evaluate the effectiveness of stabilizing amendments and soil dressing methods on the mobility of As in the contaminated rice paddy soils nearby mining area. METHODS AND RESULTS: Different amendments were mixed with surface and subsurface contaminated soils at a ratio of 3% (w/w) and monitored for five months. Three different extractants including 0.01M $CaCl_2$, TCLP, and PBET were used to examine As bioavailability in the soil and the concentration of As in rice grain was also measured with an inductively coupled plasma (ICP) spectroscopy. The results showed that all amendment treatments decreased As concentration compared to the control. Especially, coal mine drainage sludge (CMDS) treatment showed the highest efficiency of decreasing As concentration in the soil and rice grain. The values of Pearson correlation (r) between As concentrations in the soil and rice grain were 0.782, 0.753, and 0.678 for $CaCl_2$, TCLP, and PBET methods, respectively. Especially, $CaCl_2$ method was highly correlated between As concentrations of the soil and soil solution (r=0.719), followed by TCLP (r=0.706), PBET (r=0.561) methods. CONCLUSION: Stabilizing amendments can effectively reduce available As concentration in the soils as well as soil solution, and thereby potentially mitigating risks of crop contamination by As.

A Study for Chemical Resistance of Polymer Cement Concrete Using Tailing (폐석 미분말을 혼입한 폴리머 시멘트 콘크리트의 내약품성에 관한 연구)

  • 전철수;연규석;이윤수;이필호
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.355-360
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    • 1999
  • Polymer cement is made by the modifying ordinary cement concrete with polymer additive. Until now polymer cement concrete is not used for the structural member, but it is growing to be considered as developing uses such as a waterproof of roof slab, the structural member for protecting corrosion, and a road pavement. The plymer cement concrete, being used for those uses, is superior to the cement concrete against the inorganic, organic acid, salt of acetic acid and organic solvents generally. In this paper, the polymer cement concrete was made by the ratio of 1:1 of sands and tailing in fine aggregate in order to solve the environmental pollution which causes the social problem by the tailing, It was measured for the compressive strength, flexural strength, and chemicals resistance was tested by dealing with 10% HCI, 20% NaOH and 10% NaCl aqueous solution.

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The Effect of Salinity on Biological Nutrient Removal in SBR (SBR공정에서 영양염류 제거에 대한 염분의 영향)

  • Song, Changsoo;Oh, Junseung
    • Journal of Korean Society on Water Environment
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    • v.18 no.3
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    • pp.237-243
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    • 2002
  • The effect of a salinity on the performance of a biological nutrient removal system was investigated using a model SBR(Sequencing Bach Reactor) system. The system was operated at a 12hr, 18hr, 24hr, and 36hr HRT with a salinity level of 20,000mg/L and compared with a system similarly operated with fresh water. The influent salinity level of 8,000 mg/L does not have a significant effect on BOD removal efficiency, there is a noticeable decrease in BOD removal rate from 10,000 mg Cl-/L. The Nitrogen could be removed from the saline wastewater with the same efficiency as for the fresh water because of low C/N ratio in anoxic period. The excess biological phosphorous removal is highly affected by the increase in the influent salinity. The efficiency is decreased from 96.6% to 43.4% when the influent salinity is increased from 0 to 20,000mg/L.

Preparation of Calcium Sulfate Hemihydrate Using Stainless Refinery Sludge and Waste Sulfuric Acid

  • Eun, Hee-Tai;Ahn, Ji-Whan;Kim, Hwan;Kim, Jang-Su;Sung, Ghee-Woong
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.432-436
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    • 2001
  • In this study, calcium sulfate(gypsum) powder was obtained using waste sulfuric acid and stainless refinery sludge by- produced from chemical reagent and the iron industry, by the neutralization of waste sulfuric acid. As variables for the experiment the mole ratio of the H$_2$SO$_4$ : Ca(OH)$_2$, the pH, the reaction temperature and time, the amount of catalyst were used. The crystal shape and microstructure of obtained powder were observed by XRD and SEM, and the thermal property was investigated by DTA. As the NaCl is added 0~20wt% as a catalyst to the H$_2$SO$_4$ : Ca(OH)$_2$, system it can be found that the crystal shape goes through the processes as follows : gypsum dihydratlongrightarrowgypsum hemihydrate+gypsum dihydratelongrightarrowgypsum hemihydrate. And gypsum hemihydrate is $\beta$-type as the result of DTA. As waste sulfuric acid and stainless refinery sludge were used, the pH of reacted solution (which was 0.8) was rapidly raised up to 8~9 by the addition of stainless sludge and gypsum dihydrate was produced as a by-product. Therefore, it was found that stainless refinery sludge is sufficiently applicable for the neutralization of waste sulfuric acid.

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Methanol oxidation behaviors of PtRu nanoparticles deposited onto binary carbon supports for direct methanol fuel cells

  • Park, Soo-Jin;Park, Jeong-Min;Lee, Seul-Yi
    • Carbon letters
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    • v.14 no.2
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    • pp.121-125
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    • 2013
  • In this study, PtRu nanoparticles deposited on binary carbon supports were developed for use in direct methanol fuel cells using carbon blacks (CBs) and multi-walled carbon nanotubes (MWCNTs). The particle sizes and morphological structures of the catalysts were analyzed using X-ray diffraction and transmission electron microscopy, and the PtRu loading content was determined using an inductively coupled plasma-mass spectrometer. The electrocatalytic characteristics for methanol oxidation were evaluated by means of cyclic voltammetry with 1 M $CH_3OH$ in a 0.5 M $H_2SO_4$ solution as the electrolyte. The PtRu particle sizes and the loading level were found to be dependent on the mixing ratio of the two carbon materials. The electroactivity of the catalysts increased with an increasing MWCNT content, reaching a maximum at 30% MWCNTs, and subsequently decreased. This was attributed to the introduction of MWCNTs as a secondary support, which provided a highly accessible surface area and caused morphological changes in the carbon supports. Consequently, the PtRu nanoparticles deposited on the binary support exhibited better performance than those deposited on the single support, and the best performance was obtained when the mass ratio of CBs to MWCNTs was 70:30.

Characterization and Preparation of Al-Pillared Clay (Aluminium-Pillared Clay의 제조 및 특성)

  • Park, Se-Jun;Ha, Baik-Hyon;Jeong, Soon-Yong;Suh, Jeong-Kwon;Lee, Jung-Min
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.304-309
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    • 1999
  • Aluminum-pillared clay was prepared by the intercalation of Al-hydroxy oligomer into domestic bentonite. The solid products are characterized by XRD, nitrogen adsorption/desorption, EDX, and SEM. The solid products show relatively high specific surface areas in the range of $104{\sim}228m^2/g$, and their specific surface area, micropore surface area, and micropore volume increase with increasing the mole ratio of OH/Al. From the results of pore size distribution calculated by BJH equation, it was found that aluminum-pillared clay also contains much mesopore near $40{\AA}$. These results indicate that Al-hydroxy oligomer was intercalated into bentonite, and aluminum oxide was pillared among the layers of bentonite, and micropore and mesopore was finally developed into layers. As OH/Al mole ratio increases, the thermal stability of aluminum-pillared clay increases. This result can be explained by the fact that the density of layers is increased due to the formation of aluminum pillars.

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Combination Effect of ʟ-Arginine and ʟ-Aspartic acid on Saltiness Enhancement of NaCl Solution (ʟ-아르기닌과 ʟ-아스파라긴산 혼합이 NaCl 짠맛 향상에 미치는 영향)

  • Kim, Yong-Duk;Park, Jung-Ha;Park, Bok-Jun;In, Man-Jin;Park, Dong-Chel;Oh, Nam-Soon
    • Journal of Applied Biological Chemistry
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    • v.57 no.3
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    • pp.251-254
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    • 2014
  • In order to investigate the combination effect of $\small{L}$-arginine and $\small{L}$-aspartic acid on salt enhancement, the saltiness and bitterness of various mixtures of $\small{L}$-arginine and $\small{L}$-aspartic acid were evaluated using the electronic tongue and sensory tests. Increasing the molar ration of $\small{L}$-arginine against $\small{L}$-aspartic acid enhanced the salty taste of NaCl, whereas increasing the molar ration of $\small{L}$-aspartic acid against $\small{L}$-arginine significantly suppressed the bitter taste of $\small{L}$-arginine. Therefore, combination of $\small{L}$-arginine and $\small{L}$-aspartic acid can be utilized as a saltiness enhancer and its suitable combination ratio was showed as $\small{L}$-arginine : $\small{L}$-aspartic acid = 1.00:0.98-1.00 on basis of molar concentration.

Mineralogical studies and extraction of some valuable elements from sulfide deposits of Abu Gurdi area, South Eastern Desert, Egypt

  • Ibrahim A. Salem;Gaafar A. El Bahariya;Bothina T. El Dosuky;Eman F. Refaey;Ahmed H. Ibrahim;Amr B. ElDeeb
    • Analytical Science and Technology
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    • v.37 no.1
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    • pp.47-62
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    • 2024
  • Abu Gurdi area is located in the South-eastern Desert of Egypt which considered as volcanic massive sulfide deposits (VMS). The present work aims at investigating the ore mineralogy of Abu Gurdi region in addition to the effectiveness of the hydrometallurgical route for processing these ores using alkaline leaching for the extraction of Zn, Cu, and Pb in the presence of hydrogen peroxide, has been investigated. The factors affecting the efficiency of the alkaline leaching of the used ore including the reagent composition, reagent concentration, leaching temperature, leaching time, and Solid /Liquid ratio, have been investigated. It was noted that the sulfide mineralization consists mainly of chalcopyrite, sphalerite, pyrite, galena and bornite. Gold is detected as rare, disseminated crystals within the gangue minerals. Under supergene conditions, secondary copper minerals (covellite, malachite, chrysocolla and atacamite) were formed. The maximum dissolution efficiencies of Cu, Zn, and Pb at the optimum leaching conditions i.e., 250 g/L NaCO3 - NaHCO3 alkali concentration, for 3 hr., at 250 ℃, and 1/5 Solid/liquid (S/L) ratio, were 99.48 %, 96.70 % and 99.11 %, respectively. An apparent activation energy for Zn, Cu and Pb dissolution were 21.599, 21.779 and 23.761 kJ.mol-1, respectively, which were between those of a typical diffusion-controlled process and a chemical reaction-controlled process. Hence, the diffusion of the solid product layer contributed more than the chemical reaction to control the rate of the leaching process. High pure Cu(OH)2, Pb(OH)2, and ZnCl2 were obtained from the finally obtained leach liquor at the optimum leaching conditions by precipitation at different pH. Finally, highly pure Au metal was separated from the mineralized massive sulfide via using adsorption method.

Evaluation of Characteristic for SS400 and STS304 steel by Weld Thermal Cycle Simulation - 2nd Report: Corrosion Characteristics (용접열사이클 재현에 의한 SS400강 및 STS304강의 특성 평가 -제2보: 부식특성)

  • Ahn, Seok-Hwan;Choi, Moon-Oh;Kim, Sung-Kwang;Son, Chang-Seok;Nam, Ki-Wook
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.33-38
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    • 2007
  • The welding methods have been applied in the most structural products from multi-field of automobile, ship construction and construction, and so on. The structure steel must have enough strength of structure. In this study, SS400 steel and STS304 steel were used to estimate the corrosion characteristics of the weld thermal cycle simulated HAZ. To evaluate the corrosion characteristics, also, the materials with two conditions were used in 3.5% NaCl. The one is to the drawing with diameter of ${\Phi}10$ and the other is to the residual stress removal treatment. The electrochemical polarization test and immersion test were carried out. From test results, corrosion potential, corrosion current density, weight loss ratio and corrosion rate were measured. In the kinds of SS400 steels, corrosion potential of weld thermal cycle simulated specimens after the heat treatment showed somewhat the direction of noble potential. And in the base metal to be drawing weight loss ratio and corrosion rate occurred higher than the other kinds. In the kinds of STS304 steels, the result of base metal to be drawing was similar to results of SS400 steels, too. Two kinds of $750^{\circ}C$ and $1300^{\circ}C$ of weld thermal cycle simulation after the heat treatment were rather higher than the other kinds in weight loss ratio and corrosion rate.