• 제목/요약/키워드: $(La,\

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La 농도가 PLT 박막의 전기적 및 광학적 특성에 미치는 효과 (The effects of la content on the electrical and optical properties of (Pb, La)TiO$_{3}$ thin films)

  • 강성준;류성선;윤영섭
    • 전자공학회논문지A
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    • 제33A권2호
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    • pp.87-95
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    • 1996
  • We have studied the effects of La concentration on the optical and electrical properties of lead lanthanum titanate (PLT) thin films by using sol-gel method. Both the optical and electrical properties are greatly affected by the La concentration. The refreactiv eindices of the films varied from 2.23 to 1.93 with varying La concentration in the range from 15 to 33 mol%. The dielectric constants of the films vary form 340 to 870 with varying La concentration in the range form 15 to 33 mol%. Hysteresis loop becomes slimmer with the increase of La concentration form 15 to 28mol% and little fatter again with the increase of La concentration form 28 to 33 mol%. Among the films investigated in this research, PLT(28) thin film shows the best dielectric properties for the application to the dielectrics of ULSI DRAM's. At the frequency of 100Hz, the dielectric constant and the loss tangent of PLT(28) thin films are 940 and 0.08 respectively. Its leakage current density at 1.5${\times}10^{5}$V/cm is 1${\times}10^{-6}A/cm^{2}$. The comparision between the simulated and the experimental curves for the switching transient characteristics shows that PLT (28) thin films behaves like normal dielectrics.

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치환된 $LaFeO_3$의 환원반응성에 대한 연구 (Study on the reducibility of substituted $LaFeO_3$)

  • 전현표;이상범
    • 자연과학논문집
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    • 제15권1호
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    • pp.35-46
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    • 2005
  • $LaFeO_3$ 복합산화물과 부분 치환한 $LaFeO_3$ 복합산화물을 citrate와 Cyanide 공침법으로 합성하여 공기중에서 $850^{\circ}C$로 24시간동안 열처리해 제조방법에 의한 영향을 비교하였다. XRD와 IR의 결과에 의하여면, 합성된 산화물은 Orthorhombic의 Perovskite구조를 나타냈으나 B자리에 0.5mol의 Cu가 치환된 복합산화물은 단일상을 얻지 못하였다. 또한, 이들 산화물의 환원반응은 치환하지 않은 $LaFeO_3.17$ 복합산홤루은 2단계 반응인 반면에 치환한 복합산화물은 3단계 반응으로 Dopant에 의한 새로운 환원단계가 존재함을 알았다.

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입자배향(Pb, Ba, La) $Nb_2O_6$ 압전세라믹스의 제작 및 그 전기적.광학적 특성 (Electrical and Optical Properties of Grain-Oriented (Pb, Ba, La) $Nb_2O_6$ Piezoelectric Ceramics)

  • 남효덕;조상희;영전방유
    • 한국세라믹학회지
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    • 제25권3호
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    • pp.268-276
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    • 1988
  • KCI을 사용한 용융염합성법에 의해 침상형$(Pb_{1-x}Ba_x)_{1-y}La_{2y/3}Nb_2O_6$ (PBLN)분말을 합성하고 합성분말의 형상에 미치는 Ba 및 La 치환의 영향을 조사하였다. 또 이 침상형 분말을 사용하여 doctor-blade법 및 hot-press 법에 의해 입자배향 세라믹스를 제작하고 유전적, 압전적, 광학적 성질을 조사하였다. 얻어진 PBLN 분말의 형상 및 입자배향 PBLN 세라믹스의 전기적 특성은 분말합성시의 열처리조건과 Ba 및 La 치환량에 따라 현저히 달랐다. 특히 PBLN 세라믹스의 유전율 및 전기기계결합계수는 입자배향 세라믹스 제작시의 가압방향에 따라 뚜렷한 이방성을 나타내었다.

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PMN/PT[0.9 Pb$(Mg_{1/3}Nb_{2/3})O_3-0.1\;PbTiO_3$에 La이 첨가된 광섬유 전왜변환기를 이용한 간섭계형 광섬유 전계센서의 특성분석 (Fiber optic interferometric electric field sensor with La-doped PMN/PT PMN/PT[0.9 Pb$(Mg_{1/3}Nb_{2/3})O_3-0.1\;PbTiO_3$] electrostrictive ceramics)

  • 강원석;이영탁;강현서;정래성;이경식;장현명
    • 한국광학회지
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    • 제7권2호
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    • pp.162-166
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    • 1996
  • 전왜재질 0.9 PMN/0.1PT에 각각 조성비율이 1%, 2%, 3%의 La이 첨가된 3종류의 재질을 광섬유에 부착하여 광섬유 전왜변환기를 제작하였다. 실험결과 La 3% 첨가된 재질의 전왜계수가 3.38kHz에서 3.87*$10^{-16}$(m/V)$^{2}$로 가장 크다는 것을 알 수 있었으며 La을 첨가함으로 해서 이력이 줄어듬을 알 수 있었다. La 3%인 재질로 구현된 광섬유 전계센서의 최소감지전계는 2.08(V/m).root.Hz였으며 가변영역 40dB 이상에 걸쳐서 선형성이 우수하였다.

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$CaTiO_3-LaAIO_3$계 세라믹스의 마이크로파 유전특성 (Microwave dielectric properties of $CaTiO_3-LaAIO_3$ ceramics)

  • 여동훈;김현재;송준태
    • E2M - 전기 전자와 첨단 소재
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    • 제9권4호
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    • pp.379-384
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    • 1996
  • The microwave dielectric properties of (I-x)CaTiO$_{3}$-xLaAIO$_{3}$ were investigated. The solid solution of (1-x)CaTiO$_{3}$-xLaAIO$_{3}$ had the perovskite structure in the range of all compositions. The crystal system of (1-x)CaTiO$_{3}$-xLaAIO$_{3}$ was transformed to orthorhombic(x.leq.0.4), psudo-cubic(x=0.5), and rhombohedral (x.geq.0.7) in turn, as the amount of LaAIO$_{3}$ increased. The dielectric constant and temperature coefficient of resonant frequency of solid solution were decreased with the content of LaAIO$_{3}$, whereas, the value of Q . f$_{o}$ was increased. The microwave dielectric material having Q . f$_{o}$ = 32, 500, .epsilon.$_{r}$ = 42, and .tau.$_{f}$ = 5 ppm/.deg. C was obtained from the 0.35CaTiO$_{3}$-0.65LaAIO$_{3}$ composition sintered at 1600.deg. C for 4hrs.hrs.hrs.

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양이온 교환된 Faujasite형 Zeolite 촉매에서의 1-Butene의 반응 (Reaction of 1-Butene on Cation-Exchanged Faujasite Type Zeolite Catalysts)

  • 전학제;홍용기
    • 대한화학회지
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    • 제21권2호
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    • pp.89-93
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    • 1977
  • 고령토를 사용하여 합성한 faujasite형 zeolite를 $Zn^{2+},\;La^{3+},\;H^+(NH_4^+)$로 양이온 교환하고 Na-, Zn-, La- 및 H-faujasite의 1-butene의 분해 및 이성화반응에 대한 촉매활성을 조사하였다. $1-Butene{\rightarrow}2-butene$ 반응은 강한 산점이 별로 없는 zeolite에서도 쉽게 일어난다. Isobutene생성에 대한 활성은 La > H > Zn > Na-faujasite의 순으로 La-faujasite가 가장 컸다. Propylene 생성에 대한 활성도 같은 경향을 나타냈으나 여기서는 La-와 H-faujasite의 활성이 거의 같은 정도이었다. 본 실험결과를 보면 zeolite의 산성도(산의 강도 및 량)는 1-butene의 분해 및 이성화 반응에 대한 활성과 직접적인 관계가 있는 것 같다.

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우우 유청으로부터 분리한 $\alpha$-락트알부민의 기능적 특성 (Functional Properties of $\alpha$-Lactalbumin Separated from Bovine Whey)

  • 홍윤호
    • 한국축산식품학회지
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    • 제18권1호
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    • pp.9-18
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    • 1998
  • This study was performed to obtain a large quantity of $\alpha$-lactalbumin ($\alpha$-LA) from milk by an improved separation and purification method. Functional properties-solubility viscosity, emulsifying activity, foamability surface hydrophobicity and gelation-of the purified $\alpha$-LA were investigated, $\alpha$-LA was purified in a large quantity by DEAE-Sephacel chromatography using 0.15M NaCl in 20mM Tris-HCl buffer(pH 7.2), as an eluent. The yield and purity of the purified $\alpha$-LA were 23.6%, 92.5%, respect-ively. The solubility viscosity and emulsifying activity of the purified $\alpha$-LA were 92.2$\pm$2% 3.46$\pm$0.19 cP and 345$\pm$5.0m^2$-/g respecively. The foamability of $\alpha$ -LA was 762 after 5min whipping which was lower than that of WPC and showed decreasing tendency with whipping time. The relative surface hydrophobicity of the $\alpha$-LA was formed when a 10% $\alpha$-LA solution containing 100mM NaCl and 20 mM $CaCl_2$ was heated at 92$^{\circ}C$for 40min. The $\alpha$-LA gel showed 31.5 as hardness and showed low springiness and cohesiveness.

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La2O3 Addition Influence on Electrical Characteristics of Pr6O11-based ZnO Varistors

  • Nahm, Choon-Woo
    • Transactions on Electrical and Electronic Materials
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    • 제7권3호
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    • pp.123-128
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    • 2006
  • The microstructure and electrical properties of the varistors, which are composed of $ZnO-Pr_6O_{11}-CoO-Cr_2O_3-La_2O_3-based$ ceramics, were investigated for different $La_2O_3$ contents. The increase of $La_2O_3$ content led to more densified ceramics, whereas abruptly decreased the nonlinear properties by incorporating beyond 1.0 mol%. The highest nonlinearity was obtained from 0.5 mol% $La_2O_3$, with the nonlinear coefficient of 81.6 and the leakage current of $0.2{\mu}A$. The increase of sintering time and temperature greatly decreased the nonlinear properties. As the $La_2O_3$ content increased, the donor density increased from $0.64\times10^{18}/cm^3\;to\;16.89\times10^{18}/cm^3$ and the barrier height greatly decreased with increasing $La_2O_3$ content, reaching a maximum (1.47 eV) in 0.5 mol% $La_2O_3$.

Electrical Properties of Metal-Ferroelectric-Insulator-Semiconductor Field-Effect Transistor Using an Au/$(Bi,La)_4Ti_3O_{12}/LaZrO_x$/Si Structure

  • Jeon, Ho-Seung;Lee, Gwang-Geun;Kim, Joo-Nam;Park, Byung-Eun;Choi, Yun-Soo
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.171-172
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    • 2007
  • We fabricated the metal-ferroelectric-insulator-semiconductor filed-effect transistors (MFIS-FETs) using the $(Bi,La)_4Ti_3O_{12}\;and\;LaZrO_x$ thin films. The $LaZrO_x$ thin film had a equivalent oxide thickness (EOT) value of 8.7 nm. From the capacitance-voltage (C-V) measurements for an Au/$(Bi,La)_4Ti_3O_{12}/LaZrO_x$/Si MFIS capacitor, a hysteric shift with a clockwise direction was observed and the memory window width was about 1.4 V for the bias voltage sweeping of ${\pm}9V$. From drain current-gate voltage $(I_D-V_G)$ characteristics of the fabricated Fe-FETs, the obtained threshold voltage shift (memory window) was about 1 V due to ferroelectric nature of BLT film. The drain current-drain voltage $(I_D-V_D)$ characteristics of the fabricated Fe-FETs showed typical n-channel FETs current-voltage characteristics.

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Fluoxetine affects cytosolic cAMP, ATP, Ca2+ responses to forskolin, and survival of human ovarian granulosa tumor COV434 cells

  • Nguyen, Thi Mong Diep;Klett, Daniele;Combarnous, Yves
    • The Korean Journal of Physiology and Pharmacology
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    • 제25권3호
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    • pp.189-195
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    • 2021
  • Fluoxetine (FLX), a selective serotonin reuptake inhibitor antidepressant, exhibits various other mechanisms of action in numerous cell types and has been shown to induce cell death in cancer cells, paving the way for its potential use in cancer therapy. The aim of this study was to determine the off-target effects of the anti-depressant drug FLX, on the human ovarian granulosa tumor COV434 cells stimulated by forskolin (FSK), by measuring the real-time kinetics of intracellular cyclic AMP (cAMP), ATP level, cytoplasmic calcium ([Ca2+]cyt) and survival of COV434 cells. We show that incubating COV434 cells with FLX (between 0.6 and 10 μM) induces a decrease in intracellular cAMP response to FSK, a drop in ATP content and stimulates cytoplasmic Ca2+ accumulation in COV434 cells. Only the highest concentrations of FLX (5-10 μM) diminished cell viability. The present report is the first to identify an action mechanism of FLX in human tumor ovarian cells COV434 cells and thus opening the way to potential use of fluoxetine as a complementary tool, in granulosa tumor treatments.