• Journal of Environmental Science International
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• v.16 no.4
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• pp.393-397
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• 2007

The sonolytic decomposition of NHCs(Nitrogen Heterocyclic Compounds), such as atrazine[6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine], simazine(6-chloro-N,N'-diethyl-1,3,5-triazine-2,4-diamine), trietazine(6-chloro-N,N,N'-triethyl-1,3, 5-triazine-2,4-diamine), in water was investigated at a ultrasound frequency of 200kHz with an acoustic intensity of 200W under argon and air atmospheres. The concentration of NHCs decreased with irradiation, indicating pseudo-first-order kinetics. The rates were in the range $1.06{\sim}2.07({\times}10^{-2}min^{-1})$ under air and $1.30{\sim}2.59({\times}10^{-2}min^{-1})$ under argon at a concentration of $200{\mu}M$ of NHCs. The rate of hydroxyl radicals(${\bullet}{OH}$) formation from water is $19.8{\mu}M\;min^{-1}$ under argon and $14.7{\mu}M\;min^{-1}$ under air in the same sonolysis conditions. The sonolysis of NHCs is effectively inhibited, but not completely, by the addition of t-BuOH(2-methyl-2-propanol), which is known to be an efficient ${\bullet}{OH}$ radical scavenger in aqueous sonolysis. This suggests that the main decomposition of NHCs proceeds via reaction with ${\bullet}{OH}$ radical; a thermal reaction also occurs, although its contribution is small. The addition of appropriate amounts of Fenton's reagent $[Fe^{2+}]$ accelerates the decomposition. This is probably due to the regeneration of ${\bullet}{OH}$ radicals from hydrogen peroxide, which would be formed from recombination of ${\bullet}{OH}$ radicals and which may contribute a little to the decomposition.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.1
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• pp.83.2-83.2
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• 2012

We have carried out simultaneous 22GHz $H_2O$ and 44GHz Class I $CH_3OH$ maser survey of 112 ultra-compact HII regions (UCHIIs) twice in 2010 and 2011. We detected $H_2O$ maser and $CH_3OH$ maser emission from 76(68%) and 49(44%) UCHIIs, respectively. Among them 15 $H_2O$ masers and 32 $CH_3OH$ masers are new detections. These high detection rates suggest that the occurrence periods of both masers are significantly overlapped with the UCHII phase. $CH_3OH$ masers always have small (<10 km s-1) relative velocities with respect to the natal molecular cores, while $H_2O$ masers often show larger velocities. We find 20 UCHIIs with $H_2O$ maser lines at relative velocities >30 km s-1. The formation and disappearance of $H_2O$ masers is frequent over one-year time interval. In contrast, $CH_3OH$ masers usually do not show substantial variation in intensity, velocity, or shape. The isotropic luminosities of both masers well correlate with the bolometric luminosities of the central stars when data points of lowand intermediate-mass protostars are added: $L_{H_2O}=5.89{\times}10^{-9}{(L_{bol})^{0.69}}$ and $L_{CH_3OH}=4.27{\times}10^{-9}{(L_{bol})^{0.62}}$. They also tend to increase with the 2cm radio continuum luminosity of UCHIIs and the 850 um continuum luminosity of the associated molecular cores. We discuss some individual sources.

• Economic and Environmental Geology
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• v.27 no.3
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• pp.295-311
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• 1994

A comprehensive in-situ tests are performed to define the hydrogeologic and hydrodispersive characteristics such as hydraulic conductivities, longitudinal dispersivity, and average linear velocities as well as conducting flow-net analysis at the study area. The results show that the study area is very heterogeneous so that hydraulic conductivities range from $6.45{\times}10^{-7}$ to $1.15{\times}10^{-5}m/s$ with average linear velocities of 0.34~0.62m/day. Whole groundwater in upper-most aquifer is discharging into the sea with specific discharge rate of $7.2{\times}10^{-3}$ to $1.3{\times}10^{-2}m/day$. The longitudinal dispersivity of the aquifer is estimated about 4.8m through In-situ injection phase test. The area is highly vulnerable to potential contaminant sources due to it's high value of DRASTIC index ranging from 139 to 155 and also under water table condition with very shallow groundwater level. To delineate contaminant plumes of toxic NaOH and carcinogenic benzene when these substances are assumed to be leaked through existing TSDF at the study area by unexpected accidents or spill, Aquifer Simulation Model (ASM) including Flow and Transport Model is used. Te simulated results reveal that the size of NaOH plume after 5 years continuous leak is about $250{\times}100m$ and benzene after 10 years, $490{\times}100m$. When the groundwater is abstracted about 50 days, which is maximum continuously sustained no-precipitation period during 30 years, with pumping rate of $100m^3/day$, THWELL program shows that the groundwater is adversly affected by sea water intrusion.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.2
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• pp.249-254
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• 1998

The etching experiments for n-GaN were done using the wet chemical, photo-enhanced-chemical and electro-chemical etching methods. The experimental results show that n-GaN is etched is diluted NaOH solution at room temperature and the removed thickness of n-GaN is linearly increased with etching times. The etching rate of the photo-enhanced-chemical and electro-chemical etching methods are several times higher than that of the wet chemical method. The maximum etching rate of n-GaN with $n{\fallingdotseq}1{\times}10^{19}cm^{-3}$ was 164 $\AA$/min under the experimental condition of the Photo-enhanced-chemical etching. The etching rates of n-GaN are very much dependant on the electron concentrations of the samples. The pattern is $100{\mu}m{\times}100{\mu}m$ rectangulars covered with $SiO_2$film. It is shown that the etched side-wall charactistics of the pattern is vertical without dependance of the n-GaN orientations, and the smoothness of etched n-GaN surface is fairly flat.

• Journal of the Korean Society of Marine Environment & Safety
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• v.17 no.2
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• pp.167-172
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• 2011

In physical engineering, the turbulent flow on the surface roughness is very important. With the welding, design and paint, the hull surface roughness at each stage in the various aspects are important factors to be considered. In this study, the hull surface roughness geometry that was generalized to the PIV was applied to the tank test. The roughness of the surface changed the distance of the interval. Experimental velocity is Re = $1.1{\times}10^4$, Re = $2.0{\times}10^4$ and Re = $2.9{\times}10^4$. The turbulent intensity at the time-average were examined The roughness coefficient occurred with increasing turbulence intensities was stronger. The turbulence intensity away from the roughness in the shape was zero. The variation of turbulence intensity at the experimental flow conditions change was not affected.

• Journal of the Korean Society of Food Science and Nutrition
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• v.36 no.2
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• pp.149-154
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• 2007

An antibacterial substance to the Streptococcus mutans, a causative bacterium for decayed teeth, was isolated from the dried sea mustard, Undaria pinnatifida, and identified by GC and GC/MS. Acetone extract from the sea mustard (10.4 kg), was evaporated and partitioned to 4 fractions such as hexane, chloroform, butanol and water. The most active chloroform fraction were further purified through basic alumina, silicic acid and ODS column, successively, and finally, 3 antibacterial substances were isolated on the HPLC attached ODS column by using 95% MeOH and guided with UV detector (254 nm). Antibacterial substances (total 160mg, yield $1.5\times10^{-3}$%) had the same Rf value (0.42) on the TLC developed hexane diethyl ether acetic acid (80:30:1) and those methyl esters moved to 0.95. They were identified as the same unsaturated fatty acid, $C_{18:4,\;n-3}$ (3,6,9,12-octadecatetraenoic acid, stearidonic acid) compared relative retention times (15.5 min) with authentic fatty acid on the GC chromatogram. It was further confirmed unambiguously on the GC/MS giving molecular ion peak at m/z 290 which coincided with its methyl ester.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.7
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• pp.649-655
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• 2010

This study investigated the degradation of phenol using sonication and/or UV-C. The effects of frequency, temperature, pH in solution, argon purging, with UV intensity were estimated in sonication-only, UV-only, and the combined reaction of sonication with UV. The optimum condition for degrading phenol in the sonication-only reaction was 35 kHz, $5^{\circ}C$, and pH 4. As this condition approximately 30% degradation of phenol was achieved within 360 min. However, phenol in the UV-only at $19.3\;mw/cm^2$ under the same condition was completely degraded within 60 min. In the combined system of sonication with UV, the degradation of phenol was well fitted to first-order rate model, and phenol was completely degraded within 360 min and 45 min at UV intensity of $7.6\;mW/cm^2$($17.3{\times}10^{-3}\;min^{-1}$) and $19.3\;mW/cm^2$($138.1{\times}10^{-3}\;min^{-1}$), respectively. Adding methanol, as a radical scavenger, in the phenol degradation in the sonication reaction indicates that OH radical is a major factor in the degradation of phenol. The order of degradation efficiencies of phenol was in the order of as follows; combined reaction of sonication with UV > UV-only > sonication-only.

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.638-643
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• 1992

The analytical response properties of two types of continuous flow-through electrode system as fulfide ion detectors are examined and directly compared their reponse characteristics under the optimal conditions. In both detection systems, observed peak potentials are logarithmically related to the sulfide ion concentration and at least twenty samples per hour can be determined. In the pH electrode method, the pH of the flowing recipient stream leaving the dialyzer was monitored. The designed system involves the use of continuous flow gas dialyzer in conjunction with the tubular polymer membrane electrode. In this method, optimal experimental conditions are recipient of mixture of $5.0 {\times} 10^{-5} M NaOH ＋ 5.0 {\times} 10^{-3} M$ NaCl and diluent of 0.10 M $H_2SO_4$, and all flow rates of recipient stream, diluent stream, and sample are 1.0 ml/min. In the sulfide ion electrode method, a commercially available sulfide ion-selective electrode was used to detect sulfide ion in the flow-through cell. The optimal flow rates of sulfide anti-oxidant buffer (3.5 g ascorbic acid and 7.6 g $Na_2EDTA$ dissolved in 1.0 M NaOH solution 1 l) and sample were 1.4 ml/min and 1.0 ml/min, respectively.

• Journal of the Korean Chemical Society
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• v.39 no.4
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• pp.237-243
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• 1995

The measurments of neutral semiquinone radicals, which were formed from the laser flash photolysis of anthraquinone (AQ) in the mixed solvents were carried out by the time resolved electron spin resonance (trESR) spectroscopy. The chemically induced dynamic electron polarization (CIDEP) spectra of the neutral semiquinone radical (AQH${\cdot}$) and semiquinone radical anion (AQ${\cdot}$-) were successively detected in the laser flash photolysis of AQ in the mixtures of 2-propanol (PrOH) and triethylamine (TEA). The neutral semiquinone radical was short-lived with the half-life of 0.8 ${\mu}sec$, whereas the semiquinone radical anion was relatively stable and then its cwESR could be observed. The rate constant of the spin-depolarization of semiquinone radical anion was $2.6{\times}10^5 sec^{-1}$ and the decay of the radical anion was the first order reaction with the rate constant of $3.0{\times}10^2\; sec^{-1}$. No CIDEP of semiquinone radical anion was observed in the mixture of PrOH and the lower concentration of TEA than 2 percent. The CIDEP spectrum of the neutral semiquinone radical was detected in the mixture of benzene and TEA with the half-life of 3.0 ${\mu}sec$. The neutral semiquinone radical could not be detected by cwESR. Neither CIDEP nor ESR absorption could be observed in PrOH, TEA or benzene only.

• Journal of the Korea Institute of Military Science and Technology
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• v.12 no.1
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• pp.80-87
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• 2009

The purpose of this study is to analyze the MAUP's effect in visibility analysis using GIS. MAUP normally occurs in the process in terrain spatial analysis including visibility analysis. There are two different types of grid data(based on digital map and Digital Terrain Elevation Data) and 10 different types of areal units are made for modeling, such as $5m{\times}5m,\;10m{\times}10m,\;15m{\times}15m,\;20m{\times}20m,\;25m{\times}25m,\;30m{\times}30m,\;35m{\times}35m,\;40m{\times}40m,\;45m{\times}45m,\;50m{\times}50$. By analyzing the result, it was possible to observe varying viewshed areas according to different grid cell sizes and the viewshed area did not varied linearly as expected. From a general point of view, smaller unit data map out the real world in more detail, but the results of modeling do not always reach a good conclusion when data are used in modeling for terrain analysis because of the MAUP' effect. The grid cell sizes of 30m or less seems to be adequate for visibility analysis, including terrain analysis considering vegetation heights.