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Degradation Characteristics of Non-biodegradable Matters using Pre-Coagulation and Fenton Oxidation Process in Livestock Wastewater  

Cho, Chang-Woo (Public Health Environment Institute of Jeollabuk-do)
Kim, Boung-Young (Public Health Environment Institute of Jeollabuk-do)
Chae, Soo-Choen (Public Health Environment Institute of Jeollabuk-do)
Kim, Sun-Ae (Public Health Environment Institute of Jeollabuk-do)
Chung, Paul-Gene (Department of Environmental Engineering, Chonbuk National University)
Publication Information
Journal of Korean Society on Water Environment / v.22, no.1, 2006 , pp. 66-73 More about this Journal
Abstract
The purpose of this study was done to evaluate degradation characteristics of non-biodegradable organic matters including aromatic compounds in livestock wastewater using CFZ process. The CFZ process is consisted of coagulation/sedimentation, Fenton oxidation and zeolite adsoption process. degradation charateristics of each treatment water including livestock wastewater were analyzed by UV scanning, FT-IR and GC/MS. After coagulation/sedimentation process as 1st treatment, non-biodegradable matters remained after 1st treatment were removed by using OH radical produced in Fenton oxidation process. As a result of treatment using these processes, NBDCOD removal efficiency was over 90%. Increase of $E_2/E_3$ ratio (absorbance at 250 and 365 nm) in each treatment water means that aromaticity of livestock wastewater decreased. In case of GC/MS, most aromatics or polynuclear aromatics like benzene, phenol and scatol in livestock wastewater almost wasn't detected after oxidation using OH radical.
Keywords
$E_2/E_3$ ratio; GC/MS; NBDCOD; OH radical; UV scanning;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 김동현, 이경혁, Fenton 산화반응을 이용한 유기산 세정약품 처리, 한국수질보전학회지, 14(1), pp. 13-19 (1998)
2 안병준, 백색부후균의 변이주인 Phanerochaete Chrysosporium PSBL-1 을 이용한 축산폐수내 질소제거 및 난분해성 물 질 분해특성에 관한연구, 전북대학교 일반대학원 석사학 위논문 (2003)
3 정용순 등, 기기분석(기초와 실험), 반도출판사, pp. 129-178 (1998)
4 조성호, 오존발생장치 및 오. 폐수 처리 적용현안(2), 환경기술, 3, pp. 24-32 (1997)
5 De Haan, H., De Boer, T., Kremer, H. A. and Voerman, J., Applicability of Light Absorbance as a Measure of Organic Carbon in Humic Lake Water, Wat. Res., 16(6), pp. 1047-1050 (1982)   DOI   ScienceOn
6 WADE, L. G. JR., Organics Chemistry, Fourth Edition, pp. 588-620 (1999)
7 전라북도 보건환경연구원 , Fenton 산화와 Zeolite 를 이용한 난분해정 폐수처리공법에 관한 연구(중간보고서), pp. 81-147 (2005)
8 Reynolds, D. M. and Ahmad, S. R., Rapid and Direct Determination of Wastewater BOD Values using a Fluorescence Technique, Wat. Res., 31(8), pp. 2012-2018 (1997)   DOI   ScienceOn
9 Dobbs, R. A., Wise, R. H. and Dean, R. B., The Use of Ultraviolet Absorbance for Monitoring the Total Organic Carbon Content of Water and Wastewater, Wat. Res., 6(10), pp. 1173-1180 (1972)   DOI   ScienceOn
10 Gulyas, H., Processes for the Removal of Recalcitrant Organics from Industrial Wastewater, Water Sci. Tech., 36, pp. 9-16 (1997)
11 Christian, H. M., Wastewater Biofilters used for Advanced Treatment of Papermill Effulent, Water Science and Technology, 40(11-12), pp. 101-108 (1999)
12 Kim, S. M. and Vogelpohl, A., Degradation of Organic Pollutants by the Photo-Fenton Oxidation Technology Chemosphere, 41, pp. 1287-1297 (2000)   DOI   ScienceOn
13 간은성, Fenton 및 $H_20_2/UV $ 공정을 이용한 제지폐수의 처리 특성, 한국폐기물학회지, 16(5), pp. 474-947 (1999)
14 김명철, 오존처리에 따른 부식산의 특성변화연구, 강원대학 교 대학원 석사학위 논문 (1997)
15 Chen, Y, Senesi, N. and Schnitzer, M., Soil Sci. Am. J., 41, p. 352 (1994)   DOI
16 APHA, Standard Methods for the Examination of Water and Wastewater, 19th ed.s, New York (1995)
17 원종철, 이종윤, 안웅현, 납궁원, 윤조희, Fenton 산화공정을 이용한 매립지 침출수 처리, 한국폐기물학회지, 16(3), pp. 314-321 (1999)
18 Fenton, H. J. H., Oxidation of Tartanic Acid in the Presence of Iron, J. Chem. Soc.(Brit), 65, p. 899 (1894)
19 Bowers, A. R. et al., Evaluating Chemical Oxidation of Toxic Industrial Wastewater, Presented at the 60th Annual Conference of the Water Pollution Control Federation, Philadelphia, PA., October, pp. 4-7 (1987)
20 Peuravuori, J. and Pihlaja, K., Anal. Chim. Acta., 337, p. 133 (1997)   DOI   ScienceOn
21 Samuel, J. T., Jeff, N. and Neil, E. S., An Ultraviolet Absorbance Method of Estimating the Percent Aromatic Carbon Content of Humic Acids, J. Environ. Qual., 19, pp. 151-153 (1990)   DOI
22 환경부, 수질오염공정시험방법 (2000)
23 환경부, 환경통계연감, 제16호, pp. 39-40 (2004)