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http://dx.doi.org/10.11629/jpaar.2014.10.2.053

Preparation of Graphene-Palladium Composite by Aerosol Process and It's Characterization for Glucose Biosensor  

Kim, Sun Kyung (Rare Metals Utilization Research Team, Korea Institute of Geoscience and Mineral Resources)
Jang, Hee Dong (Rare Metals Utilization Research Team, Korea Institute of Geoscience and Mineral Resources)
Chang, Hankwon (Rare Metals Utilization Research Team, Korea Institute of Geoscience and Mineral Resources)
Choi, Jeong-Woo (Interdisciplinary Program of Integrated Biotechnology, Sogang University)
Publication Information
Particle and aerosol research / v.10, no.2, 2014 , pp. 53-59 More about this Journal
Abstract
Palladium (Pd) nanoparticles attached graphene (GR) composite was synthesized for an enhanced glucose biosensor. Aerosol spray pyrolysis (ASP) was employed to synthesize the GR-Pd composite using a colloidal mixture of graphene oxide (GO) and palladium chloride ($PdCl_2$) precursor. The effects of the weight ratio of the Pd/GR on the particle properties including the morphology and crystal structure were investigated. The morphology of GR-Pd composites was generally the shape of a crumpled paper ball, and the average composite size was about $1{\mu}m$. Pd nanoparticles less than 20 nm in diameter were deposited on GR sheets and the Pd nanoparticles showed clear crystallinity. The characteristic of the glucose biosensor fabricated with the as-prepared GR-Pd composite was tested through cyclic voltammetry measurements. The biosensor exhibited a high current flow as well as clear redox peaks, which resulted in a superior ability of the catalyst in terms of an electrochemical reaction. The highest sensitivity obtained from the amperometric response of the glucose biosensor was $14.4{\mu}A/mM{\cdot}cm^2$.
Keywords
Aerosol spray pyrolysis; Glucose biosensor; GR-Pd composite; Cyclic voltammetry;
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1 Singh, V., Joung, D., Zhai, L., Das, S., Khondaker, S.I., and Seal, S. (2011). Graphene based materials: Past, present and future, Progress in Materials Science, 56, 1178-1271.   DOI   ScienceOn
2 Wang, J. (2008). Electrochemical Glucose Biosensors, Chemical Reviews, 108, 814-825.   DOI   ScienceOn
3 Wu, B., Kuang, Y., Zhang, X., and Chen, J. (2011). Noble metal nanoparticles/carbon nanotubes nanohybrids: synthesis and applications, Nano Today, 6, 75-90.   DOI   ScienceOn
4 Yang, M.H., Choi, B.G., Park, H., Hong, W.H., Lee, S.Y., and Park, T.J. (2010). Development of a glucose biosensor using advanced electrode modified by nanohybrid composing chemically modified graphene and ionic liquid, Electroanalysis, 22, 1223-1228.   DOI   ScienceOn
5 Yang, J., Deng, S., Lei, J., Ju, H., and Gunasekaran, S. (2011). Electrochemical synthesis of reduced graphene sheet-AuPd alloy nanoparticle composites for enzymatic biosensing, Biosensors and Bioelectronics, 29, 159-166.   DOI   ScienceOn
6 Zeng, Q., Cheng, J.S., Liu, X.F., Bai, H.T., and Jiang, J.H., (2011). Palladium nanoparticle/chitosangrafted graphene nanocomposites for construction of a glucose biosensor, Biosensors and Bioelectronics, 26, 3456-3463.   DOI   ScienceOn
7 Zhou, K., Zhu, Y., Yang, X., Luo, J., Li, C., and Luan, S. (2010). A novel hydrogen peroxide biosensor based on Au-graphene-HRP-chitosan biocomposites, Electrochimica Acta, 55, 3055-3060.   DOI   ScienceOn
8 Jang, H.D., Kim, S.K., Chang, H., Choi, J.W., and Huang, J. (2013). Synthesis of graphene based noble metal composites for glucose biosensor, Materials Letters, 106, 277-280.   DOI   ScienceOn
9 Cote, L.J., Silva, R.C., and Huang, J. (2009). Flash reduction and patterning of graphite oxide and its polymer composite, Journal of the American Chemical Society, 131, 11027-11032.   DOI   ScienceOn
10 Hummers, W.S. and Offeman, R.E. (1958). Preparation of graphitic oxide. Journal of the American Chemical Society, 80, 1339.   DOI
11 Jang, H.D., Kim, S.K., Chang, H., Roh, K.M., and Choi, J.W. (2012). A glucose biosensor based on $TiO_{2}$-graphene composite, Biosensors and Bioelectronics, 38, 184-188.   DOI
12 Jia, F., Shan, C.S., Li, F.H., and Niu, L., (2008). Carbon nanotube/gold nanoparticles/polyethyleniminefunctionalized ionic liquid thin film composites for glucose biosensing, Biosensors and Bioelectronics. 24, 945-950.   DOI   ScienceOn
13 Kim, S.K., Chang, H., Choi, J.W., Huang, J., and Jang, H.D. (2014). Aerosol processing of graphene and its application to oil absorbent and glucose biosensor, KONA Powder and Particle Journal, 31, 111-125.   DOI
14 Kuila, T., Bose, S., Khanra, P., Mishra, A.K., Kim, N.H., and Lee, J.H. (2011). Recent advances in graphene-based biosensors, Biosensors and Bioelectronics, 26, 4637-4648.   DOI   ScienceOn
15 Kuila, T., Bose, S., Mishra, A.K., Khanra, P., Kim, N.H., and Lee, J.H. (2012). Chemical functionalization of graphene and its applications, Progress in Materials Science, 57, 1061-1105.   DOI
16 Shan, C., Yang, H., Han, D., Zhang, Q., Ivaska, A., and Niu, L. (2010). Graphene/AuNPs/chitosan nanocomposites film for glucose biosensing, Biosensors and Bioelectronics, 25, 1070-1074.   DOI   ScienceOn
17 Lim, S.H., Wei, J., Lin, J., Li, Q., and You, J.K. (2005). A glucose biosensor based on electrodeposition of palladium nanoparticles and glucose oxidase onto Nafion-solubilized carbon nanotube electrode, Biosensors and Bioelectronics, 20, 2341-2346.   DOI   ScienceOn
18 Lu, J., Do, I., Drzal, L.T., Worden, R.M., and Lee, I. (2008). Nanometal-decorated exfoliated graphite nanoplatelet based glucose biosensors with high sensitivity and fast response, ACS Nano, 2, 1825-1832.   DOI   ScienceOn
19 O'eill, R.D., Chang, S.C., Lowry, J.P., and McNeil, C.J. (2004). Comparisons of platinum, gold, palladium and glassy carbon as electrode materials in the design of biosensors for glutamate, Biosensors and Bioelectronics, 19, 1521-1528.   DOI   ScienceOn
20 Chen, Y., Li, Y., Sun, D., Tian, D., Zhang, J., and Zhu, J.J. (2011). Fabrication of gold nanoparticles on bilayer graphene for glucose electrochemical biosensing, Journal of Materials Chemistry, 21, 7604-7610.   DOI   ScienceOn