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Extraction of Oil from Canola Seeds with Supercritical Carbon Dioxide  

Hwang, Ah-Reum (Department of Chemical and Biochemical Engineering, The University of Suwon)
Jung, In-Il (Department of Chemical Engineering, Yonsei University)
Lim, Gio-Bin (Department of Chemical and Biochemical Engineering, The University of Suwon)
Ryu, Jong-Hoon (Department of Chemical and Biochemical Engineering, The University of Suwon)
Publication Information
KSBB Journal / v.24, no.4, 2009 , pp. 367-376 More about this Journal
Abstract
In this study, two supercritical extraction systems of different scale, analytical-scale and lab-scale, were employed to investigate the extraction efficiency of canola oil from canola seeds using supercritical carbon dioxide ($SCCO_2$) as an extraction solvent. The effects of various parameters such as extraction temperature ($40{\sim}80^{\circ}C$), pressure (200~500 bar), particle size, and $SCCO_2$ flow direction on the extraction rate and yield were examined in detail. Triglycerides and fatty acids in the extracted canola oil were analyzed quantitatively by high-performance liquid chromatography and gas chromatography. The solubility values of canola oil in $SCCO_2$ could be calculated from the experimental results. Similar extraction yields were obtained from both analytical-scale and lab-scale extraction systems. The extraction rates obtained under solvent ($SCCO_2$ ) upflow conditions were found to be higher than those of solvent downflow extraction. However, the effect of $SCCO_2$ flow direction on the extraction yield was observed to be relatively insignificant.
Keywords
Supercritical extraction; carbon dioxide; canola oil; scale-up;
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1 Thobani, M., and L. L. Diosady (1997), Two-phase solvent extraction of canola, JAOCS. 74, 207-214   DOI   ScienceOn
2 Charlotta, T., and M. Lennart (2000), Determination of vitamins A and E in milk powder using supercritical fluid extraction for sample clean-up, J. Chromatogr. A. 874, 275-283   DOI   PUBMED   ScienceOn
3 de Azevedo, A. B. A., T. G. Kieckbush, A. K Tashima， R. S. Mohamed, P. Mazzafera, and S. A. B. Vieira de Melo (2008), Extraction of green coffee oil using supercritical carbon dioxide, J. Supercrit. Fluids. 44, 186-192   DOI   ScienceOn
4 Dunford, N. T. and F. Temelli (1995), Extraction of phospholipids from canola with supercritical carbon dioxide and ethanol, JAOCS. 72, 1009-1015   DOI   ScienceOn
5 Dunford, N. T., and F. Temelli (1997), Extraction conditions and moisture content of canola flakes as related to lipid composition of supεrcritical $CO_2$ extracts, J. Food Sci. 62, 155-159   DOI   ScienceOn
6 Rezaei, K , and F. Temelli (2001), On-line exσactionreaction of canola oil using immobilized lipase in supercritical $CO_2$, J. Supercrit. Fluids. 19, 263-274   DOI   ScienceOn
7 King, J. W., A. Mohamed, S. L. Taylor, T. Megrahtu, and C. Paul (2001), Supercritical fluid extraction of Vernonia galamensis seeds, lnd. Crops Prod. 14, 241-249   DOI   ScienceOn
8 Przybylski, R., Y. C. Lee, and I. H. Kim (1998), Oxidative stability of canola oils extracted with supercritical carbon dioxide, Lebensm. Wiss. U. Technol. 31, 687-693   DOI   ScienceOn
9 Pereira, C. G., and M. A. A. MeireJes (2007), Economic analysis of rosemary, fennel and anise essential oil obtainεd by supercritical fluid extraction, Flavoar Fragr. J. 22, 407-413   DOI   ScienceOn
10 Salgin, U., A. Calimi, and E. Z. Uysal (2007), Supercritical fluid extraction of jojoba oil, JAOCS. 81, 293-296   DOI   ScienceOn
11 Kang, Y. S., S. W. Rho, and K. P. Yoo (2001), Influence of the ratio of inlet tube diameter to the extractor diameter on supercritical extraction process, Theor.Appl. Chem. Eng. 7, 3307-3310
12 Cho, Y. K., H. S. Kim, J. W. Kim, S. Y. Lee, W. S. Kim, J. H. Ryu, and G. B. Lim (2004), Extraction of glabridin from licorice using supercriticaJ carbon dioxide, KSBB J. 19, 427-432
13 Louli, V., G. Folas, E. Voutsas, and K. Magoulas (2004), Extraction of parsley seed oil by supercritical $CO_2$, J. Supercrit. Fluids. 30, 163-174   DOI   ScienceOn
14 Hu A. J., S. Zhao, H. Liang, T. Q. Qiu, and G. Chen (2007), Ultrasound assisted supercritical fluid extraction of oil and coixenolide from adlay seed, Ultrason. Sonochem. 14, 219-224   DOI   ScienceOn
15 Jang, Y. S. (2002), Prospect and situation of quality improvement in oilseed rape, Korean J. Crop Sci. 47, 175-185
16 Abu-Arabil , M. K., M. A. Allawzi, H. S. AI-Zoubi, and A. Tamimi (2000), Extraction of jojoba oil by pressing and leaching, Chem. Eng. J. 76, 61-65   DOI   ScienceOn
17 Barthet, V. J., and J. K. Daun (2001), An evaluation of supercriticaJ fluid extraction as an analytical tool to determine fat in canola, flax, solin, and mustard, JAOCS. 79, 245-251
18 Salgin, U. (2007), Extraction of jojoba seed oil using supercritical $CO_2$+ethanol mixutre in green and high-tech separation process, J. Supercrit. Fluids. 39, 330-337   DOI   ScienceOn
19 Kim, B. U. and U. S. Kang (1992), Supercritical fluid extraction of unsaturated fatty acids from soybean oil, J. Korean Inst. Chem. Eng. 30, 635-640
20 Przybylski, R., and T. Mag. (2002), Canola/rapeseεd oil, In Vegetable Oils in Food Technology: Composition, Properties and Uses, F. D. Gunstone, Ed., p98, CRC Press ， Boca Roton
21 Zaidul, I. S. M., N. A. Nik Nomlaini, A. K. Mohd Omar, and R. L. Smith Jr. (2006), Supercritical carbon dioxide $$(SC-CO_2)$$ extraction and fractionation of palm kemel oil from palm kemel as cocoa butter repJacers blend, J. Food Eng. 73, 210-216   DOI   ScienceOn
22 Matthaus, B., and L. Bruhl (1999), Comparison of a supercritical fluid extraction method for the extraction of oilseeds with the DGF standard method B-I 5 (87), Fett/Lipid 101, 203-206   DOI
23 Bhupesh, C. R., and G. Motonobu, and H. Tsutomu (1996), Extraction of ginger oil with supercritical carbon dioxide: experiments and modeling, lnd Eng. Chem. Res. 35, 607-612   DOI   ScienceOn
24 Coelho, J. A. P., A. P. Pereira, R. L. Mendes, and A. M. F. Palavra (2003), Supercritical carbon dioxide extraction of Foeniculwn vulgare volatile oil, Flavour Fragr. J. 18, 316-319   DOI   ScienceOn
25 Eskin, N. A. M., B. E. McDonald, R. Przybylski, L. J. Malcolmson, R. Scarth, T. Mag, K. Ward, and D. Adolph (1996), Canola oil, Bailey 's Industrial Oil and Fat Prodiucts: Edible Oil and Fat Products : Oils and Oilseeds 2, Y. H. Hui, Ed, pl , John Wilεy & Sons, New York
26 Zaidul, I. S. M., N. A. Nik Nomlaini, A. K. Mohd Omar, and R. L. Smith Jr. (2007), Supercritical carbon dioxide $$(SC-CO_2)$$ extraction of palm kemel oil from palm kemel, J. Food Eng. 79, 1007-1014   DOI   ScienceOn
27 Bmhl, L., and B. Matthaus (1999), Extraction of oilseeds by SFE-A comparison with other methods for the determination of the oil content ， Fresenius ’ J. Anal. Chem. 364, 631-364   DOI   ScienceOn
28 Westerman, D., R. C. D. Santos, J. A. Bosely, J. S. Rogers, and B. Al-Duri (2006), Extraction of amaranth seed oil by supεrcritical carbon dioxide, J. Supercrit. Fluids 37, 38-52   DOI   ScienceOn
29 Lee, A. K. K., N. R. Bulley, and M. Fattori (1986), Modelling of supercritical carbon dioxide extraction of canola oil seεd in fixed beds, JAOCS. 63, 921-925   DOI
30 Fattori, M., N. R. Bulley, and A. Meisεn (1988), Carbon dioxide extraction of canola seed : Oil solubility and effect of seed treatment, JAOCS. 65, 968-974   DOI
31 Jεnab ， E., K. Rezaei, and Z. Emam-Djomeh (2006), Canola oil extracted by supercritical carbon dioxide and a commεrcial organic solvent, Eur. J. Lipid Sci. Technol. 108, 488-492   DOI   ScienceOn
32 Riera, E., Y. Golas, A. Blanco, J. A. Gallego, M. Blasco, and A. Mulet (2004), Mass transfer enhancement in supercritical fluids extraction by means of power ultrasound, Ultrason. Sonochem. 11, 241-244   DOI   ScienceOn
33 Mira, B., M. Blasco, and S. Subirate (1996), Supercritical $CO_2$ extraction of essential oils from orange peel, J. Supercrit. Fluids. 9, 238-243   DOI   ScienceOn