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http://dx.doi.org/10.6564/JKMRS.2021.25.4.045

A Calix[4]pyrrole Bearing a Quaternary Ammonium Group: A Fluoride-Selective Anion Receptor  

Oh, Ju Hyun (Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University)
Lee, Joon Hwa (Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University)
Kim, Sung Kuk (Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University)
Publication Information
Journal of the Korean Magnetic Resonance Society / v.25, no.4, 2021 , pp. 45-50 More about this Journal
Abstract
A calix[4]pyrrole (1) bearing a quaternary ammonium pendant via its meso phenoxy linker has been synthesized as the bromide salt form. It was revealed by 1H NMR spectroscopic analyses performed in DMSO-d6 that receptor 1 binds F- with high affinity and selectivity over other halide anions. The binding of receptor 1•Br- with F- and Cltakes place by anion metathesis with the anions including F- and Cl-.
Keywords
Anion receptor; Fluoride; Selectivity; Anion metathesis; Calix[4]pyrrole;
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