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http://dx.doi.org/10.5012/jkcs.2011.55.1.014

Esterification of Methacrylic acid with Ethylene glycol over Heteropolyacid supported on ZSM-5  

Prabhakarn, A. (Department of Chemistry, Indian Institute of Technology Hyderabad)
Fereiro, J.A. (Department of Chemistry, Indian Institute of Technology Hyderabad)
Subrahmanyam, Ch. (Department of Chemistry, Indian Institute of Technology Hyderabad)
Publication Information
Journal of the Korean Chemical Society / v.55, no.1, 2011 , pp. 14-18 More about this Journal
Abstract
Esterification of methacrylic acid with ethylene glycol was carried out over Heteropolyacids [HPA: $H_4SiW_{12}O_{40}$ (STA) and $H_3PW_{12}O_{40}$ (PTA)] supported on ZSM-5. For comparison, the same reaction was carried out over unsupported HPA, $H_2SO_4$, $BF_3$ and PTSA. Among the catalysts studied, HPA showed better activity compared to $H_2SO_4$, $BF_3$ and PTSA. Catalytic activity was compared with HPA supported ZSM-5 catalysts. Typical results indicated that 30 wt% PTA supported on ZSM-5 showed nearly the same activity as that of bulk PTA. It was found that the reaction follows first order kinetics with respect to methacrylic acid. The reaction products were identified by $^1H$-NMR and FT-IR.
Keywords
Esterification; Solid acid catalysts; Methacrylate; Heteropolyacid; Zeolites;
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1 Devassy, B. M.; Halligudi, S. B. J. Catal. 2005, 236, 313.   DOI
2 Rajkumar, T.; Rao, G. R. J. Mol Catal A: Chem. 2008, 295, 1.   DOI
3 Misono, M. Catal. Rev. Sci. Eng. 1987, 29, 269.   DOI
4 Swanmi, S.; Shin-ivhi, N.; Okuahar, T.; Misono, M. J. Catal. 1997, 166, 263.   DOI
5 Yadav, G. D. Catalysis Survey from Asia 2005, 9(2), May.
6 Kozhevnikov, I. V. Catalysis Rev. Sci. Eng. 1995, 97, 311.   DOI
7 Pankaj Sharma, Samir Vyas, Anjali Patel J. Mol Catal A: Chem. 2004, 214, 281.   DOI
8 Okuhara, T.; Kasai, A.; Hayakawa, N.; Yoneda, Y.; Misono, M. J. Catal. 1983, 121, 83.
9 Jalil, P. A.; Al-Daous, M. A.; Al-Arfaj, A. R. A.; Al- Armer, A. M.; Beltramani, J.; Barri, S. A. I. Appl. Cat. A 2001, 207(1/2), 528.
10 Teruyuki Nakato, Mutsuko Kimura, Shin-ichi Nakata and Toshio Okuhara, Langmuir 1998, 14, 319.   DOI
11 George, B.; Touyears, Y. G. F; Vebral, J. Int. J. Adhes. Adhes. 2000, 20, 245.   DOI   ScienceOn
12 Yang, Z.; Jia, W. U.S. 5,969,000, 1999.
13 Naito, K.; Fuse, T.; Tanuma, I.; Fukura, Y.; Ishikawa, H. U.S. 4,591,618, 1986.
14 Moszner, N.; Salz, U. Prog. Polymer Sci. 2001, 26, 535.   DOI
15 Meixner, J.; Pedain, J.; Hohlein, P.; Margotte, D. U.S. 4,748,269, 1988.
16 Sheldon, R. A.; Downing, R. S. Appl. Cat. A: Gen. 1999, 189, 163.   DOI
17 Wilson, K.; Clark, J. H. Pure Appl. Chem. 2000, 72, 1313.   DOI
18 Shanmugam, S.; Viswanathan, B.; Varadarajan, T. K. J. Mol. Catal A: Chem. 2004, 223, 143.   DOI
19 Swanmi, S.; Shin-ivhi, N.; Okuahar, T.; Misono, M. J. Catal. 1997, 166, 263.   DOI
20 Alsalme, A.; KKozhevnikova, E. F.; Kozhevnikov, I. V. Appl. Catal A: Gen. 2008, 349, 170.   DOI
21 Sato, S.; Sagara, K.; Furuta, H.; Nozaki, F. J. Mol. Catal A: Chem. 1996, 114, 209.   DOI
22 Mitusani, A. Catal. Today 2002, 73, 57.   DOI