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http://dx.doi.org/10.5012/bkcs.2012.33.2.601

Synthesis and Photoluminescence of Colloidal Solution Containing Layered Rare-earth Hydroxide Nanosheets  

Lee, Byung-Il (Department of Applied Chemistry, College of Applied Science, Kyung Hee University)
Bae, Jung-Soo (Department of Applied Chemistry, College of Applied Science, Kyung Hee University)
Lee, Eun-Su (Department of Applied Chemistry, College of Applied Science, Kyung Hee University)
Byeon, Song-Ho (Department of Applied Chemistry, College of Applied Science, Kyung Hee University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.2, 2012 , pp. 601-607 More about this Journal
Abstract
An aspect of organophilic modification for the delamination is described for the layered rare-earth hydroxides in this paper. The interlayer property of $RE_2(OH)_5NO_3{\cdot}nH_2O$, where RE=Eu (LEuH) and Tb (LTbH), was modified by the exchange reaction of nitrate ion with oleate anion that is one of the representative dispersion agents in nonpolar solvents. The bilayer arrangement of long oleate anions in the gallery of $RE_2(OH)_5NO_3{\cdot}nH_2O$ could effectively weaken the stacking of the hydroxide layers. Highly organophilic environment of the interlayer space promoted the introduction of toluene to delaminate the layered structure into their individual sheets. When irradiated with 365 nm UV, the resulting transparent colloidal solutions of toluene containing LEuH and LTbH nanosheets yielded typical red and green emissions, respectively, which are visible to the naked eye.
Keywords
Colloidal solution; Rare-earths; Photoluminescence; Layered hydroxides; Nanosheets;
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  • Reference
1 Lee, B.-I.; Lee, K. S.; Lee, J. H.; Lee, I. S.; Byeon, S.-H. Dalton Trans. 2009, 2490.
2 Lee, K.-H.; Byeon, S.-H. Eur. J. Inorg. Chem. 2009, 4727.
3 Lee, K.-H.; Lee, B.-I.; You, J.-H.; Byeon, S.-H. Chem. Commun.2010, 46, 1461.   DOI   ScienceOn
4 Yoon, Y.-S.; Lee, B.-I.; Lee, K. S.; Im, G. H.; Byeon, S.-H.; Lee, J. H.; Lee, I. S. Adv. Funct. Mater. 2009, 19, 3375.   DOI   ScienceOn
5 Birjega, R.; Pavel, O. D.; Costentin, G.; Che, M.; Angelescu, E. Appl. Catal. A 2005, 288, 185.   DOI   ScienceOn
6 Guo, Y.; Zhang, H.; Zhao, L.; Li, G. D.; Chen, J. S.; Xu, L. J. Solid State Chem. 2005, 178, 1830.   DOI   ScienceOn
7 Trujillano, R.; Holgado, M. J.; Pigazo, F.; Rives, V. Physica B 2006, 373, 267.   DOI   ScienceOn
8 Kloprogge, J. T.; Frost, R. L. J. Solid State Chem. 1999, 146, 506.   DOI   ScienceOn
9 Williams, G. R.; O'Hare, D. Solid State Sciences 2006, 8, 971.   DOI   ScienceOn
10 Jimenez de Haro, M. C.; Perez-Rodriguez, J. L.; Poyato, J.; Perez- Maqueda, L. A.; Ramirez-Valle, V.; Justo, A.; Lerf, A.; Wagner, F. E. Appl. Clay Sci. 2005, 30, 11.   DOI   ScienceOn
11 Saunders, J. M.; Goodwin, J. W.; Richardson, R. M.; Vincent, B. J. Phys. Chem. B 1999, 103, 9211.   DOI   ScienceOn
12 Thostenson, E. T.; Li, C.; Chou, T.-W. Composites Sci. Technol. 2005, 65, 491.   DOI   ScienceOn
13 Tenne, R. Angew. Chem. Int. Ed. 2003, 4, 5124.
14 Alberti, G.; Cavalaglio, S.; Dionigi, C.; Marmottini, F. Langmuir 2000, 16, 7663.   DOI   ScienceOn
15 Divigalpitiya, W. M. R.; Frindt, R. F.; Morrison, S. R. Science 1989, 246, 369.   DOI   ScienceOn
16 Osada, M.; Sasaki, T. J. Mater. Chem. 2009, 19, 2503.   DOI   ScienceOn
17 Shukoor, M. I.; Therese, H. A.; Gorgishvili, L.; Glasser, G.; Kolb, U.; Tremel, W. Chem. Mater. 2006, 18, 2144.   DOI   ScienceOn
18 Albiston, L.; Franklin, K. R.; Lee, E.; Smeulders, J. B. A. F. J. Mater. Chem. 1996, 6, 871.   DOI   ScienceOn
19 O' Leary, S.; O'Hare, D.; Seeley, G. Chem. Commun. 2002, 1506.
20 Leroux, F.; Adachi-Pagano, M.; Intissar, M.; Chauviere, S.; Forano, C.; Besse, J. P. J. Mater. Chem. 2001, 11, 105.   DOI   ScienceOn
21 Adachi-Pagano, M.; Forano, C.; Besse, J. P. Chem. Commun. 2000, 91.
22 Liu, Z.; Ma, R.; Osada, M.; Iyi, N.; Ebina, Y.; Takada, K.; Sasaki,T. J. Am. Chem. Soc. 2006, 128, 4872.   DOI   ScienceOn
23 Wu, Q. L.; Olafsen, A.; Vistad, O. B.; Roots, J.; Norby, P. J. Mater. Chem. 2005, 15, 4695.   DOI   ScienceOn
24 Okamoto, K.; Sasaki, T.; Fujita, T.; Iyi, N. J. Mater. Chem. 2006, 16, 1608.   DOI   ScienceOn
25 Xu, Z. P.; Braterman, P. S.; Yu, K.; Xu, H.; Wang, Y.; Brinker, C. J. Chem. Mater. 2004, 16, 2750.   DOI   ScienceOn
26 Li, B.; He, J. J. Phys. Chem. C 2008, 112, 10909.   DOI   ScienceOn
27 Xu, Z. P.; Braterman, P. S. J. Mater. Chem. 2003, 13, 268.   DOI   ScienceOn
28 Carlino, S. Solid State Ionics 1997, 98, 73.   DOI   ScienceOn
29 Ida, S.; Shiga, D.; Koinuma, M.; Matsumoto, Y. J. Am. Chem. Soc. 2008, 130, 14038.   DOI   ScienceOn
30 Blasse, G.; Grabmaier, B. C. Luminescence Materials; Springer: Berlin, Heidelberg, 1994.
31 Judd, B. R. Phys. Rev. 1962, 127, 750.   DOI
32 Ofelt, G. S. J. Chem. Phys. 1962, 37, 511.   DOI
33 Vicentini, G.; Zinner, L. B.; Zukerman-Schpector, J.; Zinner, K. Coord. Chem. Rev. 2000, 196, 353.   DOI   ScienceOn
34 Gandara, F.; Perles, J.; Snejko, N.; Iglesias, M.; Gomez-Lor, B.; Gutierrez-Puebla, E.; Monge, M. A. Angew. Chem. Int. Ed. 2006, 45, 7998.   DOI   ScienceOn
35 Qiu, L.; Qu, B. J. Colloid Interface Sci. 2006, 301, 347.   DOI   ScienceOn
36 Moujahid, E. M.; Besse, J.-P.; Leroux, F. J. Mater. Chem. 2002, 12, 3324.   DOI   ScienceOn
37 Li, L.; Ma, R.; Iyi, N.; Ebina, Y.; Takada, K.; Sasaki, T. Chem. Commun. 2006, 3125.
38 McIntyre, L. J.; Jackson, L. K.; Fogg, A. M. Chem. Mater. 2008, 20, 335.   DOI   ScienceOn
39 Lee, K.-H.; Byeon, S.-H. Eur. J. Inorg. Chem. 2009, 929.
40 Poudret, L.; Prior, T. J.; McIntyre, L. J.; Fogg, A. M. Chem. Mater. 2008, 20, 7447.   DOI   ScienceOn
41 Geng, F.; Matsushita, Y.; Ma, R.; Xin, H.; Tanaka, M.; Izumi, F.; Iyi, N.; Sasaki, T. J. Am. Chem. Soc. 2008, 130, 16344.   DOI   ScienceOn
42 Geng, F.; Ma, R.; Sasaki, T. Acc. Chem. Res. 2010, 43, 1177.   DOI   ScienceOn