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http://dx.doi.org/10.5012/bkcs.2012.33.12.4015

Surface-functionalized Hexagonal Mesoporous Silica Supported 5-(4-Carboxyphenyl)-10,15,20-triphenyl Porphyrin Manganese(III) Chloride and Their Catalytic Activity  

Zhang, Wei-Jie (The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University)
Jiang, Ping-Ping (The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University)
Zhang, Ping-Bo (The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University)
Zheng, Jia-Wei (The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University)
Li, Haiyang (The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.12, 2012 , pp. 4015-4022 More about this Journal
Abstract
Manganese(III) 5-(4-carboxyphenyl)-10,15,20-triphenyl porphyrin chloride (Mn(TCPP)Cl) was grafted through amide bond on silica zeolite Y (HY), zeolite beta ($H{\beta}$) and hexagonal mesoporous silica (HMS). XRD, ICP-AES, $N_2$ physisorption, SEM, TEM, FTIR and thermal analysis were employed to analyse these novel heterogeneous materials. These silica supported catalysts were shown to be used for epoxidation and good shape selectivity was observed. The effect of support structure on catalytic performance was also discussed. The catalytic activity remained when the catalysts were recycled five times. The energy changes about epoxidation of alkenes by $NaIO_4$ and $H_2O_2$ were also computationally calculated to explain the different catalytic efficiency.
Keywords
Manganese(III) porphyrin; Epoxidation; HMS; Alkenes; Fatty acid;
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