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http://dx.doi.org/10.5012/bkcs.2008.29.2.339

Trimerization of Isobutene over Solid Acid Catalysts: Comparison between Cation-exchange Resin and Zeolite Catalysts  

Yoon, Ji-Woong (Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology)
Jhung, Sung-Hwa (Department of Chemistry, Kyungpook National University)
Chang, Jong-San (Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.2, 2008 , pp. 339-341 More about this Journal
Abstract
Catalytic trimerization of isobutene to produce triisobutenes has been performed over cation-exchange resin and zeolite catalysts. Resin catalysts have the advantage of long lifetime and high trimers selectivity even though the regeneration of an aged catalyst is not satisfactory. On the contrary, zeolite catalysts can be regenerated facilely by simple calcination in air even though the lifetime is short and trimers selectivity is low probably due to small pore size and strong acidity, respectively. It is, therefore highly desirable to develop an inorganic acid catalyst with macro- or meso-pores to show catalytic performances similar or superior to those of macroporous resin catalysts.
Keywords
Isobutene; Trimerization; Zeolite; Cation-exchange resin
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 4  (Related Records In Web of Science)
Times Cited By SCOPUS : 1
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1 Yoon, J. W.; Chang, J.-S.; Lee, H.-D.; Kim, T.-J.; Jhung, S. H. J. Mol. Catal. A 2006, 260, 181   DOI   ScienceOn
2 Japanese Patent JP 2005015383 (assigned to Idemitsu Kosan)
3 Japanese Patent JP 2005015384 (assigned to Idemitsu Kosan)
4 Yoon, J. W.; Lee, J. H.; Chang, J.-S.; Choo, D. H.; Lee, S. J.; Jhung, S. H. Catal. Commun. 2007, 8, 967   DOI   ScienceOn
5 Yoon, J. W.; Jhung, S. H.; Choo, D. H.; Lee, S. J.; Chang, J.-S. Chem. Lett. 2007, 36, 1504   DOI   ScienceOn
6 Yoon, J. W.; Jhung, S. H.; Choo, D. H.; Lee, S. J.; Lee, K.-Y.; Chang, J.-S. Appl. Catal. A 2008, 337, 73   DOI   ScienceOn
7 Yoon, J. W.; Jhung, S. H.; Lee, J. S.; Kim, T.-J.; Lee, H.-D.; Chang, J.-S. Bull. Kor. Chem. Soc. 2007, 28, 2075   DOI   ScienceOn
8 Sharma, M. M. Reactive Funct. Polymer 1995, 26, 3   DOI   ScienceOn
9 Mantilla, A.; Tzompantzi, F.; Ferrat, G.; Lopez-Ortega, A.; Alfaro, S.; Gomez, R.; Torres, M. Catal. Today 2005, 107-108, 707   DOI   ScienceOn
10 Mantilla, A.; Tzompantzi, F.; Ferrat, G.; Lopez-Ortega, A.; Romero, E.; Ortiz-Islas, E.; Gomez, R.; Torres, M. Chem. Commun. 2004, 1498
11 Mantilla, A.; Ferrat, G.; Lopez-Ortega, A.; Romero, E.; Tzompantzi, F.; Torres, M.; Ortiz-Islas, E.; Gomez, R. J. Mol. Catal. A 2005, 228, 333   DOI   ScienceOn
12 Alcantara, R.; Alcantara, E.; Canoira, L.; Franco, M. J.; Herrera, M.; Navarro, A. Reactive Funct. Polymer 2000, 45, 19   DOI   ScienceOn
13 www.axens.net
14 Burnes, E.; Wichelns, D.; Hagen, J. W. Energy Policy 2005, 33, 1155   DOI   ScienceOn
15 Yoon, J. W.; Jhung, S. H.; Chang, J.-S. et al. Unpublished Results
16 Yoon, J. W.; Lee, J. H.; Chang, J.-S.; Choo, D. H.; Lee, S. J.; Jhung, S. H. J. Catal. 2007, 245, 253   DOI   ScienceOn
17 Chiche, B.; Sauvage, E.; Renzo, F. D.; Ivanova, I. I.; Fajula, F. J. Mol. Catal. A 1998, 134, 145   DOI   ScienceOn
18 Girolamo, M. D.; Lami, M.; Marchionna, M.; Percarollo, E.; Tagliabue, L.; Ancillotti, F. Ind. Eng. Chem. Res. 1997, 36, 4452   DOI   ScienceOn
19 Jeon, J.-K.; Park, S.-K.; Park, Y.-K. Catal. Today 2004, 93-95, 467   DOI   ScienceOn
20 Honkela, M. L.; Krause, A. O. Ind. Eng. Chem. Res. 2004, 43, 3251   DOI   ScienceOn
21 Marchionna, M.; Girolamo, M. D.; Patrini, R. Catal. Today 2001, 65, 397   DOI   ScienceOn
22 Girolamo, M. D.; Marchionna, M. J. Mol. Catal. A 2001, 177, 33   DOI   ScienceOn
23 Yoon, J. W.; Jhung, S. H.; Lee, J. S.; Kim, T.-J.; Lee, H.-D.; Chang, J.-S. Bull. Kor. Chem. Soc. 2008, 29, 57   DOI   ScienceOn