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http://dx.doi.org/10.5012/bkcs.2003.24.10.1465

Synthesis and Selective Recognition of Dihydrogen Phosphate by Urea-Anthraquinone  

Jeon, Seung-Won (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Park, Duck-Hee (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Lee, Hyo-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Park, Jin-Young (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Kang, Sung-Ok (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Nam, Kye-Chun (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Publication Information
Bulletin of the Korean Chemical Society / v.24, no.10, 2003 , pp. 1465-1469 More about this Journal
Abstract
A neutral ligand is synthesized and studied for the binding properties with anions by electrochemical methods. The binding of 1,8-bis[(N'-phenylureido)ethyloxy]anthraquinone (BPUA) with $H_2PO_4^-$ makes cathodic shift of its electrochemical potentials and red shift of absorption band. This novel neutral anion receptor BPUA binds anions through hydrogen bonding and show high selectivity with $H_2PO_4^-$ over $CH_3CO_2^-,CI^-,{\;}and{\;}HSO_4^-$. The selecivity of H_2PO_4^-$ over $CH_3CO_2^-,CI^-,{\;}and{\;}HSO_4^-$ may be attributed to the stronger hydrogen bonding with urea moiety and also with anthraquinone moiety of BPUA receptor, and also the higher complementarity of the cavity of BPUA for tetrahedral H_2PO_4^-$.
Keywords
Receptor; Urea-anthraquinone; Dihydrogen phosphate ion; Binding;
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