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http://dx.doi.org/10.12925/jkocs.2002.19.3.2

Alkaline Hydrolysis of Alkyl Alkylphosphinate and Alkyl Phenylphosphinates  

Yang, Il-Woo (Department of Chemistry, Korea Military Academy)
Chung, Yeong-Jin (Division of Chemistry, Samchok National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.19, no.3, 2002 , pp. 161-166 More about this Journal
Abstract
The alkaline hydrolysis of alkyl alkylphosphinate and alkyl phenylphosphinates have been studied at room temperature. The hydrolysis proceeded as an one-stage reaction($S_{N}$ 2) and involved a nucleophilic attack of the hydroxyl ion on the phosphorus atom. And the length of the alkoxy group in the phosphinate esters affected on hydrolysis. Therefore, the alkaline hydrolysis may be used as a method to decompose the chemical agents.
Keywords
alkaline hydrolysis; phophinate ester; one-stage reaction; chemical agent;
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