Browse > Article

Isolation and Structure of cis,fac -Dibromooxotris(2,6-dimethylphenyl isocyanide)molybdenum(IV), cis,fac-$[Mo(O)Br_2(CN-C_6H_3-2,6-Me_2)_3]$  

이범준 (성균관대학교 화학과)
한원석 (성균관대학교 화학과)
이순원 (성균관대학교 화학과)
Publication Information
Korean Journal of Crystallography / v.13, no.2, 2002 , pp. 82-85 More about this Journal
Abstract
From the reaction of cis,cis,trans- [MoBr/sub 2/(CO)/sub 2/(PPh/sub 3/)/sub 2/］with 2,6-dimethylphenyl isocyanide, a molybdenum oxohaloisocyanide compound cis,fac-[Mo(O)Br/sub 2/,(CN-C/sub 6/H/sub 3/,-2,6-Me/sub 2/)sub 3/] (1) was iso-lated. Compound 1 was characterized by spectroscopy (/sup 1/H-NMR, /sup 13/C｛/sup 1/H｝-NMR, IR) and X-ray diffraction. Crystallographic data for 1: triclinic space group P(equation omitted), a=9.172(2) (equation omitted), b ＝ 11.550(3) (equation omitted), c ＝ 15.106(3) (equation omitted), α ＝ 100.44(2)°, β＝ 107.12(2)°, γ＝ 107.83(1)°, Z ＝ 2, R(wR/sub 2/) ＝ 0.0529(0.1344).
Keywords
Citations & Related Records
연도 인용수 순위
  • Reference
1 Fehlhammer, W. P. and Fritz, M., Chem. Rev., 93, 1243 (1993)
2 Bar, E. and Fehlhammer, W. P., J. Organomet. Chem., 353, 197 (1988)
3 Colton, R. and Tomkins, I. B. Aust. J. Chem., 19, 1519 (1966)
4 Bruker, SHELXTL, Structure Determination Software Programs, Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA (1997)
5 Novotny, M. and Lippard, S. J., Inorg. Chem., 13, 823 (1974)
6 Baptista, M. B., Lemos, M. A. N. D. A., Frausto da Silva, J. J. R. and Pombeiro, A. J. L., J. Organomet. Chem., 424, 49 (1992).
7 Lee, J.-G., Yoo, B.-S., Choi, N.-S., Park, K. I., Cho, S. I., Lee, C. and Lee, S. W., J. Organomet. Chem., 589, 138 (1999)
8 Yoo, B.-S., Choi, N.-S., Shim, C. Y., Son, Y. and Lee, S. W., Inorg. Chim. Acta, 309, 137 (2000)
9 Le Maux, P., Simonneaux, G. and Jaouen, G., J. Organomet. Chem., 217, 61 (1981)
10 Baird, G. J. and Davies, S. G., J. Organomet. Chem., 262, 215 (1984)
11 Orpen, A. G., Brammer, L., Allen, A. H., Kennard, O., Watson, D. G. and Taylor, R., J. Chem. Soc., Dalton Trans., S1 (1989)
12 Nugent, W. A. and Mayer, J. M., Metal-Ligand Multiple Bonds; John Wiley & Sons: New York, 1988, pp. 156-157.