Browse > Article

Preparation of Palladium on Carbon for Hydrogenation Catalyst Using [Bmim][$CF_3SO_3$] as an Effective Solvent  

Tae, Hyunman (Department of Chemical Engineering, Seoul National University of Science & Technology)
Jeon, Seung Hye (Department of Chemical Engineering, Seoul National University of Science & Technology)
Yoo, Kye Sang (Department of Chemical Engineering, Seoul National University of Science & Technology)
Publication Information
Applied Chemistry for Engineering / v.24, no.1, 2013 , pp. 82-86 More about this Journal
Abstract
Palladium particles were synthesized with 1-buthyl-3-methylimidazolium trifluoromethanesulfonate ([Bmim][$CF_3SO_3$]) as an effective solvent during the synthesis. The morphology of the particles was affected by the concentration of [Bmim][$CF_3SO_3$]. Furthermore, the palladium on carbon powder was prepared with various [Bmim][$CF_3SO_3$] concentrations and calcinations temperatures as a catalyst for hexafluoropropylene hydrogenation. Catalytic activity was varied by both conditions significantly. Under the identical condition, the catalyst prepared by the same mole ratio of [Bmim][$CF_3SO_3$] and palladium, and calcined at $500^{\circ}C$ was the most active in this reaction.
Keywords
palladium catalyst; hydrogenation; [Bmim][$CF_3SO_3$]; effective solvent;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Y. Li, X. M. Hong, D. M. Collard, and M. A. El-Sayed, Org. Lett., 2, 2385 (2000).   DOI   ScienceOn
2 S.-W. Kim, M. Kim, W. Y. Lee, and T. Hyeon, J. Am. Chem. Soc., 124, 7642 (2002).   DOI   ScienceOn
3 R. Narayanan and M. A. El-Sayed, Nano Lett., 4, 1343 (2004).   DOI   ScienceOn
4 S. E. Habas, H. Lee, V. Radmilovic, G. A. Somorjai, and P. Yang, Nat. Mater., 6, 692 (2007).   DOI   ScienceOn
5 K. M. Bratlie, H. Lee, K. Komvopoulos, P. Yang, and G. A. Somorjai, Nano Lett., 7, 3097 (2007).   DOI   ScienceOn
6 C. Wang, H. Daimon, T. Onodera, T. Koda, and S. Sun, Angew. Chem, Int. Ed., 47, 3588 (2008).   DOI   ScienceOn
7 P. Wasserscheid and W. Keim, Angew. Chem. Int. Ed., 39, 3773 (2000).
8 T. Welton, Chem. Rev., 99, 2071 (1999).   DOI   ScienceOn
9 K. Avril, B. Collier, US patent 0021849 A1 (2011).
10 C. S. Kim, H. Tae, S. H. Jeon, and K. S. Yoo, Res. Chem. Intermed (in press).
11 G. S. Fonseca, G. Machado, S. R. Teixeira, G. H. Fecher, J. Morais, M. C. M. Alves, and J. Dupont, J. Colloid Interface Sci., 301, 193 (2006).   DOI   ScienceOn
12 M. Fernandez-Garcia, A. Martinez-Arias, L. N. Salamanca, J. M. Coronado, J. A. Anderson, J. C. Conesa, and J. Soria, J. Catal., 187, 474 (1999).   DOI   ScienceOn
13 Y. Nishihata, J. Mizuki, T. Akao, H. Tanaka, M. Uenishi, M. Kimura, T. Okamoto, and N. Hamada, Nature, 418, 164 (2002).   DOI   ScienceOn
14 J. M. Thomas, B. F. G. Johnson, R. Raja, G. Sankar, and P. A. Midgley, Acc. Chem. Res., 36, 20 (2003).   DOI   ScienceOn
15 L. Schlapbach and A. Zuttel, Nature, 414, 353 (2001).   DOI   ScienceOn
16 M. T. Reetz and E. Westermann, Angew. Chem, Int. Ed., 39, 165 (2000).   DOI   ScienceOn