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http://dx.doi.org/10.6111/JKCGCT.2014.24.1.033

Study of surface modification and contact angle by electrospun PVdF-HFP membrane with DLC coating  

Lee, Tae Dong (Department of Nano Fusion Technology, Pusan National University)
Cho, Hyun (Department of Nanomechatronics Engineering, Pusan National University)
Yoon, Su Jong (Department of Nanomaterials Engineering, Pusan National University)
Kim, Tae Gyu (Department of Nanomechatronics Engineering, Pusan National University)
Abstract
Poly vinylidene fluoride-co-hexafluoropropylene (PVdF-HFP) membrane were prepared by the electrospinning technique. We had applied a DLC coating process and then the surface of the membrane and the contact angle change was investigated. Electrospun fibrous PVdF-HFP membrane surface became to wrinkled shape by Ar plasma treatment and treatment conditions. The wrinkled surface of PVdF-HFP membrane became super-hydrophilic. However, after DLC coating process, it became super-hydrophobic. The resulting surfaces were characterized by water contact angle measurement, X-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscopy (FE-SEM). Resultantly it was recognized that the wettability characteristics of the membrane surfaces depended on the chemical composition and surface morphology.
Keywords
PVdF-HFP; Electrospinning; RF-PECVD; DLC; Si-DLC; Water contact angle;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 S.W. Choi, J.R. Kim, Y.R. Ahn, S.M. Jo and E.J. Cairns, "Characterization of electrospun PVdF fiberbased polymer electrolytes", Chem. Mater. 19 (2007) 104.   DOI   ScienceOn
2 C. Yao, X. Li, K.G. Neoh, Z. Shi and E.T. Kang, "Antibacterial activities of surface modified electrospun poly(vinylidenefluoride-co-hexafluoropropylene) (PVDFHFP) fibrous membranes", Appl. Surf. Sci. 255 (2009) 3854.   DOI
3 G.G. Kumar, K.S. Nahm and R.N. Elizabeth, "Electro chemical properties of porous PVdF-HFP membranes prepared with different nonsolvents", J. Membr. Sci. 325 (2008) 117.   DOI   ScienceOn
4 M. Stolarska, L. Niedzicki, R. Borkowska, A. Zalewska and W. Wieczorek, "Structure, transport properties and interfacial stability of PVdF/HFP electrolytes containing modified inorganic filler", Electrochim. Acta 53 (2007) 1512.   DOI
5 D.W. Han, Y.H. Kim, D.J. Choi and H.K. Baik, "Hydrogen ion effect on the formation if DLC thin film by negative carbon ion beam", J. Korean Cryst. Growth Cryst. Technol. 10 (2000) 324.   과학기술학회마을
6 J.C. Park, O.G. Jeong, S.Y. Kim, S.J. Park, Y.H. Yun and H. Cho, "Silicon surface texturing for enhanced nanocrystalline diamond seeding efficiency", J. Korean Cryst. Growth Cryst. Technol. 23 (2013) 86.   과학기술학회마을   DOI   ScienceOn
7 B.G. Choi, J.H. Shin, C.I. Ahn and K.B. Shim, "Bonding structure of the DLC films deposited by RFPECVD", J. Korean Cryst. Growth Cryst. Technol. 14 (2004) 27.
8 Y. Rahmawan, M.W. Moon, K.S. Kim, K.R. Lee and K.Y. Suh, "Wrinkled, dual-scale structures of diamondlike carbon (DLC) for superhydrophobicity", Langmuir 26(1) (2010) 484.   DOI   ScienceOn
9 J. Robertson, "Diamond-like amorphous carbon", Mater. Sci. Eng. R 37 (2002) 129.   DOI   ScienceOn
10 P. Roach, N.J. Shirtcliffe and M.I. Newton, "Progess in superhydrophobic surface development", Soft Matter 4 (2008) 224.   DOI   ScienceOn
11 K.L. Johnson, K. Kendall and A.D. Roberts, "Surface energy and the contact of elastic solids", Proc. R. Soc. A. 324 (1971) 301.   DOI
12 D.K. Owens and R.C. Wendt, "Estimation of the surface free energy of polymers", J. Appl. Polym. Sci. 13 (1969) 1741.   DOI
13 Y. Miyauchi, B. Ding and S. Shiratori, "Fabrication of a silver-ragwort-leaf-like super-hydrophobic micro/nanoporous fibrous mat surface by electrospinning", Nanotechnology 17 (2006) 5151.   DOI
14 M.D. Duca, C.L. Plosceanu and T. Pop, "Surface modifications of polyvinylidene fluoride (PVDF) under rf Ar plasma", Polym. Degrad. Stab. 61 (1998) 65.   DOI   ScienceOn
15 J.P. Youngblood and T.J. McCarthy, "Ultrahydrophobic polymer surfaces prepared by simultaneous ablation of polypropylene and sputtering of poly(tetrafluoroethylene) using radio frequency plasma", Macromolecules 32 (1999) 6800.   DOI   ScienceOn
16 B.G. Choi, S.Y. Kim, C.W. Park, J.H. Park, Y.P. Hong and K.B. Shim, "Effect of deposition pressure on the morphology of $TiO_2$ nanoparticles deposited on $Al_2O_3$ powders by pulsed laser deposition", J. Korean Cryst. Growth Cryst. Technol. 23 (2013) 167.   과학기술학회마을   DOI
17 M.J. Jung, J.W. Lim, I.J. Park and Y.S. Lee, "Fluorination of polymethylmethacrylate (PMMA) film and its surface characterization", Appl. Chem. Eng. 21 (2010) 317.
18 T.G. Kim, J.K. Kim, H. Cho, S.J. Yoon and H.S. Kim, "Electrical, transparence and wetting properities of diamond like carbon films", Int. J. Mod. Phys. B 25 (2011) 4180.   DOI
19 R.N. Wenzel, "Resistance of solid surfaces to wetting by water", Ind. Eng. Chem. Res. 28 (1936) 988.   DOI