Browse > Article
http://dx.doi.org/10.3740/MRSK.2014.24.12.700

Synthesis of Calcium Phosphate Minerals from Biowaste Clam Shells Using Microwave Heating  

Bramhe, Sachin (Centre for New Functional Materials Metrology, KRISS)
Ryu, Jae-Kyung (Department of Dental Technology and Science, ShinHan University)
Chu, Min Cheol (Centre for New Functional Materials Metrology, KRISS)
Balakrishnan, Avinash (Nanosolar Division, Amrita Centre for Nanosciences and Molecular Medicine)
Kim, Taik Nam (Department of Material Science and Engineering, Pai Chai University)
Publication Information
Korean Journal of Materials Research / v.24, no.12, 2014 , pp. 700-703 More about this Journal
Abstract
Calcium phosphate minerals are biologically important because of their application in the fields of orthopaedics and dentistry. Herein we have tried to synthesize calcium phosphate minerals from biowaste clam shells. A simple microwave method was used to synthesize a mixture of calcium phosphate minerals such as hydroxyapatite, tri-calcium phosphate, and monetite. The microwave induces vibration of the dipole ions in the reagent. The heating and rearrangement of ions and atoms occurs during the process. The phases obtained in the final powder were ascertained by X-ray diffraction; the morphology of each sample was checked using a scanning electron microscope. We were able to obtain a mixture of calcium phosphate minerals using the microwave method; the calcined powder showed a brick like morphology, which is different from the rod shape morphology of the hydroxyapatite obtained using the hydrothermal process.
Keywords
biowaste; hydroxyapatite; tri-calcium phosphate; microwave;
Citations & Related Records
연도 인용수 순위
  • Reference
1 C. P Yogan and, V. Selvarajan, Junshu Wu and Dongfeng Xue, Vacuum, 83, 319 (2009).
2 S. H. Kwon, Y. K. Jun, S. H. Hong and H. E. Kim, J. Eur. Ceram. Soc., 23, 1039 (2003).   DOI   ScienceOn
3 S. Joschek, B. Nies, R. Krotz and A. Gopferich, Biomaterials, 21, 1645 (2000).   DOI   ScienceOn
4 K. P. Sanosh, M. C. Chu, A. Balakrishnan, T. N. Kim and S. J. Cho, Mater. Lett. 63, 2100 (2009).   DOI   ScienceOn
5 R. Murugan and K. P. Rao, Trends Biomater. Artif. Organs, 16, 43 (2002).
6 J. H. G. Rocha, A. F. Lemos, S. Agathopoulos, P. Valerio, S. Kannan and F.N. Oktar, Bone, 37, 850 (2005).   DOI   ScienceOn
7 A. Wassila, A. Leila, A. Lydia and A. Abdeltif, Food Technol Biotechnol., 51, 12 (2013).
8 R. Kumar, K. H. Prakash, P. Cheang and K. A. Khor, Langmuir, 20, 5196 (2004).   DOI   ScienceOn
9 M. H. Fathi, and A. Hanifi, Mater. Lett., 61, 3978 (2007).   DOI   ScienceOn
10 Z. H. Zhou, P. L. Zhou, S. P Yang, X. B. Yu and L. Z. Yang, Mater. Res. Bull., 42, 1611 (2007).   DOI   ScienceOn
11 S. Bramhe, T. N. Kim, A. Balakrishnan and M. C. Chu, Mater. Lett., 135, 195 (2014).   DOI   ScienceOn
12 S. H. Rhee, Biomaterials, 23, 1147 (2002).   DOI   ScienceOn
13 X. Yang and Z. Wang, J. Mater. Chem., 8, 2233 (1998).   DOI   ScienceOn
14 J. C. Elliott, Structure and Chemistry of the Apatites and other Calcium Orthophosphates. Elsevier, Amsterdam, Netherlands, 1994.
15 Y. B. Khollam, A. S. Deshpande, A. J. Patil, H. S. Potdar, S. B. Deshpande and S. K. Date, Mater. Chem. Phys., 71, 304 (2001).   DOI   ScienceOn
16 X. Xu, Y. Bao, C. Song, W. Yang, J. Lin and L. Lin, Micropor. Mesopor. Mater, 75, 173 (2004).   DOI   ScienceOn
17 J. Liu, K. Li, H. Wang, M. Zhu and H. Yan, Chem. Phys. Lett., 396, 429 (2004).   DOI   ScienceOn
18 M. Kurkcu, M. E. Benlidayi, B. Cam and Y. Sertdemir, J. Oral Implantol., 38, 519 (2012).   DOI   ScienceOn
19 J. K. Han H.Y. Song, F. Saito and B.T Lee, Mater. Chem. Phys., 99, 235 (2006).   DOI   ScienceOn
20 T. Kanazawa, Inorganic Phosphate Materials, Kondansha Ltd, Tokyo, Japan, 1989.