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http://dx.doi.org/10.13160/ricns.2016.9.4.261

Crystal Structure Analysis of 4-Chloro-2{[(2-hydroxy-5-methylphenyl)amino]methyl}5-methylphenol  

Sharmila, P. (Department of Physics, Presidency College)
Rajesh, R. (Department of Chemistry, Pondicherry University)
Venkatesan, R. (Department of Chemistry, Pondicherry University)
Ganapathy, Jagadeesan (Department of Physics, Presidency College)
Aravindhan, S. (Department of Physics, Presidency College)
Publication Information
Journal of Integrative Natural Science / v.9, no.4, 2016 , pp. 261-267 More about this Journal
Abstract
The crystal structure of the saliciline derivatives 4-chloro-2{[(2-hydroxy-5-methylphenyl)amino]methyl}5-methylphenol ($C_{15}H_{15}ClNO_2$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group P21/c with unit cell dimension $a=11.5241(2){\AA}$, $b=8.733(2){\AA}$ and $c=13.649(2){\AA}$ [${\alpha}=90^{\circ}$, ${\beta}=130.876(2)^{\circ}$ and ${\gamma}=90^{\circ}$]. the title compound are essentially planar conformation. The compound lies across a crystallographic inversion centre and adopts E configurations with respect to the C-N bonds. The crystal packing of the molecules of compound is stabilized through weak O-H...O inter molecular interactions.
Keywords
Chromene; Schiff Base Ligand; Single Crystal Structure; X-ray Diffraction;
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