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http://dx.doi.org/10.5806/AST.2014.27.1.22

Measurement of 1,4-dioxane in surface water by headspace GC-MS  

Hong, Seon-Haw (Geum River Environment Research Center, National Institute of Environmental Research)
Lee, Jun-Bae (Geum River Environment Research Center, National Institute of Environmental Research)
Lee, Soo-Hyung (Geum River Environment Research Center, National Institute of Environmental Research)
Lim, Hyun-Hee (Department of Environmental Science, Kongju National University)
Shin, Ho-Sang (Department of Environmental Education, Kongju National University)
Publication Information
Analytical Science and Technology / v.27, no.1, 2014 , pp. 22-26 More about this Journal
Abstract
1,4-Dioxane was classified as a Group 2B carcinogen by the International Agency for Research on Cancer. The compound was measured in surface water with a headspace gas chromatographic mass spectrometric detection. A 5 mL water sample was placed in a 10 mL headspace vial and saturated with NaCl, and the solution was spiked with 1,4-dioxane-d8 as an internal standard and sealed with a cap. Water samples were collected from twenty-two basins of Gum-River on June and September 2012, respectively. As a result, 1,4-dioxane was detected in the concentration range of $0.49-43.0{\mu}g/L$ (mean $2.0{\mu}g/L$) in the frequency of about 30% in surface water samples.
Keywords
1,4-Dioxane; surface water; headspace extraction; gas chromatography-mass spectrometry;
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