Journal of Integrative Natural Science (통합자연과학논문집)

The Basic Science Institute Chosun University (조선대학교 기초과학연구원)
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Coordination Framework of [Tetrakis(4-pyridyl)porphyrinato]Sn(IV) Complex with Ag(I) Toluenesulfonate

  • Nirmal Kumar Shee (School of Chemical Materials Engineering, Kumoh National Institute of Technology) ;
  • Jonghoon Jeon (Department of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Hee-Joon Kim (School of Chemical Materials Engineering, Kumoh National Institute of Technology)
  • Received : 2025.05.26
  • Accepted : 2025.06.05
  • Published : 2025.06.30
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Abstract

A metalloporphyrin-based coordination framework material was synthesized by the reaction of Sn(OH)2(TPyP) complex (TPyP = 5,10,15,20-tetrakis(4-pyridyl)porphyrinato dianion) with Ag(OTs) (OTs = p-toluenesulfonato monoanion), and thoroughly characterized using various analytic techniques including X-ray crystallography. The X-ray crystal structural analysis revealed that peripheral coordination of pyridyl nitrogen with Ag(I) ions creates a two-dimensional network. This framework contains two different types of pore channels, with approximate edge dimensions of 21.6 × 15.2 Å and 13.7 × 7.11 Å, respectively.

Keywords

Acknowledgement

This work was supported by the RISE program of Kumoh National Institute of Technology.

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