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A Study on the Residual Compressive Strength of Concrete Mixed with Limestone Powder after Heating

석회석 미분말이 혼입된 콘크리트의 가열 후 잔류 압축강도에 관한 연구

  • Choi, Youn-Sung (Dept of Architectural Engineering, Chungnam University) ;
  • Kim, Gyu-Yong (Department of Smart City Architectural Engineering, Chung Nam University) ;
  • Suh, Dong-Kyun (Carbon Neutral Research Center R&D Center, Asiacement Co.) ;
  • Eu, Ha-Min (Dept of Architectural Engineering, Chungnam University) ;
  • Han, Seung-Hyeon (Dept of Architectural Engineering, Chungnam University) ;
  • Nam, Jeong-Soo (Department of Smart City Architectural Engineering, Chung Nam University)
  • Received : 2024.09.06
  • Accepted : 2024.09.30
  • Published : 2024.10.20

Abstract

In this research, the thermal properties of limestone fine powder at high temperatures were examined, followed by an analysis of its residual compressive strength when incorporated into concrete under various thermal conditions, to determine its impact on concrete subjected to high heat. The study revealed that at 900℃, limestone micropowder undergoes a decarbonization reaction, where calcium carbonate(CaCO3) decomposes into calcium oxide(CaO), accompanied by an expansion of the limestone powder as temperature increases. This expansion leads to material cracking or crushing starting at temperatures above 500℃. Further analysis on concrete mixed with limestone powder showed that heating up to 300℃ could promote the reaction of hydrates within the concrete, thereby enhancing its strength. However, exposure to temperatures beyond 500℃ causes the limestone powder within the concrete to crack or fracture, significantly reducing the concrete's strength properties. This study highlights the dual role of limestone fine powder in influencing concrete's behavior under high-temperature scenarios, demonstrating an initial strengthening effect followed by a detrimental impact at higher temperatures.

본 연구에서는 석회석 미분말의 고온 열적 특성을 분석한 이후, 석회석 미분말을 다양한 조건에서 콘크리트에 혼입하였을 때 가열 후 잔류 압축강도에 대해 분석하였다. 이를 통해 석회석 미분말이 고온에서 콘크리트에 미치는 영향을 검토하였다. 석회석 미분말의 고온 열적 특성 결과, 석회석 분말은 900℃에서 탈 탄산화 반응이 일어나면서 열에 의해 CaCO3가 CaO로 분해되는 것을 관찰했으며, 온도가 높아질수록 석회석 분말이 점차 팽창하여 500℃ 이상의 온도부터 균열 또는 파쇄가 발생하는 것을 확인하였다. 석회석 미분말 혼입 콘크리트의 가열 후 잔류 기계적 물성을 분석한 결과, 300℃ 이하에서 시험체를 가열하면 콘크리트 내 수화물의 반응이 촉진되어 강도가 증가하였지만, 500℃ 이상의 온도로 가열한 경우 석회석 분말에 균열이나 파괴가 발생하여 콘크리트의 강도 특성이 저하시키는 것을 확인하였다.

Keywords

Acknowledgement

This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea government(MSIT)(No. RS-2023-00220921).

References

  1. Jeong YS, Jo SH, Moon SH, Ji CY. A study on greenhouse gas reduction scenarios in the building sector to achieve carbon neutrality by 2050. Journal of the Architectural Institute of Korea. 2021 Oct;37(10):189-97. https://doi.org/10.5659/JAIK.2021.37.10.189 
  2. Rodríguez N, Alonso M, Grasa G, Abanades JC. Process for capturing CO2 arising from the calcination of the CaCO3 used in cement manufacture. Environmental science & technology. 2008 Aug;42(18):6980-4. https://doi.org/10.1021/es800507c 
  3. Moon GD, Oh S, Jung SH, Choi YC. Effects of the fineness of limestone powder and cement on the hydration and strength development of PLC concrete. Construction and Building Materials. 2017 Mar;135:129-36. https://doi.org/10.1016/j.conbuildmat.2016.12.189 
  4. Suh DK, Kim GY, Choi JW, Kim KS, Woo JW. Effect of chemical composition and substitution amount of limestone mixture on initial properties of cement. Journal of the Korean Recycled Construction Resources Institute. 2023 Dec;11(4):440-8. https://doi.org/10.14190/JRCR.2023.11.4.440 
  5. De Weerdt K, Haha MB, Le Saout G, Kjellsen KO, Justnes H, Lothenbach B. Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash. Cement and Concrete Research. 2011 Mar;41(3):279-91. https://doi.org/10.1016/j.cemconres.2010.11.014 
  6. Lothenbach B, Le Saout G, Gallucci E, Scrivener K. Influence of limestone on the hydration of portland cements. Cement and Concrete Research. 2008 Jan;38(6):848-60. https://doi.org/10.1016/j.cemconres.2008.01.002 
  7. Kang B, Kim G, Lee T, Koo K, Lee S, Son M, .Sasui S, Eu H. Effects of blast furnace slag powder and limestone powder on the mechanical properties and durability of shotcrete using monocalcium aluminate setting accelerator. Materials. 2022 Mar;15(7):2495. https://doi.org/10.3390/ma15072495 
  8. Wang D, Shi C, Farzadnia N, Shi Z, Jia H. A review on effects of limestone powder on the properties of concrete. Construction and building materials. 2018 Dec;192:153-66. https://doi.org/10.1016/j.conbuildmat.2018.10.119 
  9. Marzouki A, Lecomte A, Beddey A, Diliberto C, Ouezdou MB. The effects of grinding on the properties of Portland-limestone cement. Construction and Building Materials. 2013 Nov;48:1145-55. https://doi.org/10.1016/j.conbuildmat.2013.07.053 
  10. Espin MJ, Duran-Olivencia FJ, Valverde JM. Role of particle size on the cohesive behavior of limestone powders at high temperature. Chemical Engineering Journal. 2020 Jul;391:123520. https://doi.org/10.1016/j.cej.2019.123520 
  11. Li C, Jiang L. Utilization of limestone powder as an activator for early-age strength improvement of slag concrete. Construction and Building Materials. 2020 Aug;253:119257. https://doi.org/10.1016/j.conbuildmat.2020.119257 
  12. Li W, An X, Li H. Limestone mechanical deformation behavior and failure mechanisms: a review. Acta Geochimica. 2018 Jan;37:153-70. https://doi.org/10.1007/s11631-017-0259-y 
  13. El-Kurdi AA, Abdel-Hakam A, El-Gohary MM. Impact of elevated temperature on properties of limestone concrete. International Journal of Innovative Technology and Exploring Engineering. 2014 Sep;4(4):1-9. 
  14. Zhang Y, Sun Q, Geng J. Microstructural characterization of limestone exposed to heat with XRD, SEM and TG-DSC. Materials Characterization. 2017 Dec;134:285-95. https://doi.org/10.1016/j.matchar.2017.11.007 
  15. Kim GY, Choe GC, Kang YW, Lee TG. Mechanical properties of concrete depending on cooling conditions after high temperature heating. Journal of Advanced Concrete Technology. 2014 Dec;12(3):82-90. https://doi.org/10.3151/jact.12.82 
  16. Cree D, Green M, Noumowe A. Residual strength of concrete containing recycled materials after exposure to fire: A review. Construction and Building Materials. 2013 Aug;45:208-23. https://doi.org/10.1016/j.conbuildmat.2013.04.005 
  17. Kim GY, Kim YS, Lee TG. Mechanical properties of high-strength concrete subjected to high temperature by stressed test. Transactions of Nonferrous metals society of China. 2009 Sep;19:s128-33. https://doi.org/10.1016/S1003-6326(10)60260-9 
  18. Ma Q, Guo R, Zhao Z, Lin Z, He K. Mechanical properties of concrete at high temperature-A review. Construction and Building Materials. 2015 Sep;93:371-83. https://doi.org/10.1016/j.conbuildmat.2015.05.131