방사성폐기물학회지 (Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT))

  • 제22권1호
  • /
  • Pages.27-35
  • /
  • 2024
  • /
  • 1738-1894(pISSN)
  • /
  • 2288-5471(eISSN)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
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Separation and Determination of Citric Acid by Ion Chromatography in Radioactive Concrete Waste

  • Hyejin Cho (Korea Atomic Energy Research Institute) ;
  • Jai Il Park (Korea Atomic Energy Research Institute) ;
  • Tae-Hong Park (Korea Atomic Energy Research Institute) ;
  • Hye-Ryun Cho (Korea Atomic Energy Research Institute)
  • 투고 : 2023.12.06
  • 심사 : 2024.02.26
  • 발행 : 2024.03.30
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초록

During the dismantling of nuclear facilities, a large quantity of radioactive concrete is generated and chelating agents are required for the decontamination process. However, disposing of environmentally persistent chelated wastes without eliminating the chelating agents might increase the rate of radionuclide migration. This paper reports a rapid and straightforward ion chromatography method for the quantification of citric acid (CA), a commonly used chelating agent. The findings demonstrate acceptable recovery yields, linearities, and reproducibilities of the simulated samples, confirming the validity of the proposed method. The selectivity of the proposed method was confirmed by effectively separating CA from gluconic acid, a common constituent in concretes. The limits of detection and quantification of the method were 0.679 and 2.059 mg·L-1, respectively, while the recovery yield, indicative of the consistency between theoretical and experimental concentrations, was 85%. The method was also employed for the quantification of CA in a real concrete sample. These results highlight the potential of this approach for CA detection in radioactive concrete waste, as well as in other types of nuclear wastes.

키워드

과제정보

This study was supported by the KAERI Institutional Program (Project No. 521330-23).

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