Transactions of Materials Processing (소성∙가공)

The Korean Society for Technology of Plasticity and materials processing (한국소성∙가공학회)
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Optimization of MIL-53 Metal-organic Framework Coatings for Enhanced Durability in Carbon Dioxide Capture

이산화탄소 포집 성능 향상을 위한 MIL-53 금속-유기 골격체 코팅의 최적화

  • Dae-Hyeon Kim ;
  • Sung-Jun Lee ;
  • Dong-Gyu Ahn ;
  • Chang-Lae Kim
  • 김대현 (조선대학교 기계공학과) ;
  • 이성준 (조선대학교 기계공학과) ;
  • 안동규 (조선대학교 기계공학과) ;
  • 김창래 (조선대학교 기계공학과)
  • Received : 2024.07.15
  • Accepted : 2024.07.17
  • Published : 2024.08.01
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Abstract

This study aimed to optimize the MIL-53 metal-organic framework coatings for enhanced durability in carbon dioxide capture applications. We synthesized MIL-53 powders using a hydrothermal method and deposited them on stainless-steel substrates by spin coating at various speeds, ranging from 300 to 2,000 rpm. The microstructure, surface properties, and tribological characteristics of the coatings were analyzed systematically. The results indicated that the spin speed significantly impacted the coating uniformity and defect formation. Coatings prepared at moderate speeds of 500 to 1,000 rpm exhibited optimal thickness and density, resulting in superior wear resistance. The tribological tests revealed that the coatings prepared at 700 to 1000 rpm had the lowest wear rates. These findings offer valuable insights for the development of durable MOF-based coatings for carbon dioxide capture and other applications requiring long-term stability under mechanical stress.

Keywords

Acknowledgement

This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea government(MSIT) (No. RS-2023-00219369). This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea government(MSIT) (RS-2024-00349019).

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