한국섬유공학회지 (Textile Science and Engineering)

  • 제61권1호
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  • Pages.24-32
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  • 2024
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  • 1225-1089(pISSN)
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  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
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붕화물 섬유 소재를 위한 (Zr1-xMx)B2 및 (Hf1-xMx)B2 (M=Ti, V, Cr, Zr, Nb, Mo, Hf, Ta 및 W) 기계적 특성 조사: 제1원리 계산

Mechanical Properties of (Zr1-xMx)B2 and (Hf1-xMx)B2 (M=Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W) for Diboride Fiber Materials: Ab Initio Calculations

  • 이하은 (숭실대학교 신소재공학과) ;
  • 김효경 (숭실대학교 신소재공학과) ;
  • 곽종욱 (숭실대학교 신소재공학과) ;
  • 경수아 (숭실대학교 신소재공학과) ;
  • 김지웅 (숭실대학교 신소재공학과)
  • Haeun Lee (Department of Materials Science and Engineering, Soongsil University) ;
  • Hyokyeong Kim (Department of Materials Science and Engineering, Soongsil University) ;
  • Jongwook Kwak (Department of Materials Science and Engineering, Soongsil University) ;
  • Sooah Kyung (Department of Materials Science and Engineering, Soongsil University) ;
  • Jiwoong Kim (Department of Materials Science and Engineering, Soongsil University)
  • 투고 : 2023.12.02
  • 심사 : 2024.01.30
  • 발행 : 2024.02.29
⟨ 이전 논문 다음 논문 ⟩

초록

Zirconium diboride (ZrB2) and hafnium diboride (HfB2) fibers have not been studied as extensively as metal carbides and nitrides for transition metal solid solutions due to a lack of processing technology. However, their remarkable physical properties make them ideal for high-temperature applications. In this study, we investigated the mechanical properties of solid solution diboride using ab initio calculations. Specifically, we focused on the (Zr1-xMx)B2 and (Hf1-xMx)B2 (M=Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, and W) compositions. Our findings revealed that ZrB2 and HfB2 have high Young's moduli of 524.12 and 551.41 GPa, respectively. Additionally, the solid solutions of (Zr0.25Ti0.75)B2 and (Hf0.25Ti0.75)B2 showed superior shear and Young's modulus. We also compared the mechanical properties of titanium-doped diboride solid solutions with undoped ZrB2 and HfB2 at high temperatures. Our study provides valuable insights into the potential development of diborides as ceramic fibers tailored for high-temperature applications.

키워드

과제정보

이 논문은 2022년도 정부(방위사업청)의 재원으로 국방기술진흥연구소의 지원을 받아 수행된 연구임(KRIT-CT-22-028, 극초음속 비행체용 고내열 및 전자파제어 복합소재 기술(하이브리드 구조 초고내열 세라믹섬유강화 복합소재 제조), 2022).

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