한국식품위생안전성학회지 (Journal of Food Hygiene and Safety)

  • 제38권5호
  • /
  • Pages.311-318
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  • 2023
  • /
  • 1229-1153(pISSN)
  • /
  • 2465-9223(eISSN)
한국식품위생안전성학회 (The Korean Society of Food Hygiene and Safety)
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유통 조미건어포 중 프로피온산, 안식향산, 소브산 함유량 조사

Determination of Propionic, Benzoic, and Sorbic Acids in Dried Seasoned Seafood Products in Korea

  • 장우진 (중앙대학교 식품생명공학과) ;
  • 최종윤 (중앙대학교 식품생명공학과) ;
  • 김성재 (중앙대학교 식품생명공학과) ;
  • 하상도 (중앙대학교 식품생명공학과) ;
  • 이지현 (중앙대학교 식품생명공학과)
  • Woojin Jang (Department of Food Science and Biotechnology, Chung-Ang University) ;
  • Jongyoon Choi (Department of Food Science and Biotechnology, Chung-Ang University) ;
  • Seongjae Kim (Department of Food Science and Biotechnology, Chung-Ang University) ;
  • Sang-Do Ha (Department of Food Science and Biotechnology, Chung-Ang University) ;
  • Jihyun Lee (Department of Food Science and Biotechnology, Chung-Ang University)
  • 투고 : 2023.07.05
  • 심사 : 2023.07.31
  • 발행 : 2023.10.30
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초록

본 연구는 국내 유통 조미건어포 27건 중 프로피온산, 안식향산, 소브산 함량을 분석하였다. 식품의약품안전처 식품공전의 분석 방법으로 GC-FID를 이용하여 프로피온산을 분석하였고 HPLC-DAD를 이용하여 안식향산과 소브산을 분석하였다. 그 결과 총 27건 중 프로피온산은 16건(검출률 59%), 안식향산은 불검출, 소브산은 7건(검출률 26%)이 검출되었다. 조미건어포에서 프로피온산은 ND-125.10 mg/kg의 농도로 검출이 되었으며 이는 미생물 최소저해농도 이하의 수치로 보존 효과를 나타낼 수 없는 농도로 보여 의도적으로 첨가되지는 않았을 것으로 사료된다. 또한, 소브산의 경우 소르빈산 칼륨이 표기된 시료에서만 검출되었으며 표기된 시료 8건 중 7건에서만 검출이 되었다. 소브산 검출 시료의 경우 658.18 mg/kg의 농도까지 검출이 되었으며, 이는 그 사용 기준에 적합한 수치였다. 본 연구는 향후 조미건어포에 대한 안전 관리를 위한 기초자료로 사용될 수 있을 것으로 사료된다.

This study was performed to determine the contents of propionic, benzoic, and sorbic acids in dried seasoned seafood products (n=27) sold in Korea. Propionic acid was determined using a gas chromatogramphy-flame ionization detector. Benzoic and sorbic acid were analyzed by using a high-performance liquid chromatography-diode array detector. Benzoic acid was not detected in the dried seasoned seafood products; however, propionic and sorbic acid were detected in some samples. The concentrations of propionic acid and sorbic acid were up to 125.10 mg/kg and 658.18 mg/kg in dried seasoned seafood products, respectively. Of eight samples labeled with potassium sorbate, sorbic acid was detected in seven of them. The detected sorbic acid levels in these samples met the regulations for sorbic acid usage in Korea. The propionic, benzoic, and sorbic acid contents of dried seasoned seafood products determined in this study can provide basic data for safety management of dried seasoned seafood products in future.

키워드

과제정보

본 연구는 2023년 식품의약품안전처 지원 과제 (21162MFDS013, 201153MFDS605)에 의해 수행되었으며 이에 감사드립니다.

참고문헌

  1. Msagati, T.A.M., 2013. The chemistry of food additives and preservatives, John Wiley & Sons, Hoboken, NJ, USA, pp 128-129.
  2. Luck, E., Jager, M., 1997. Antimicrobial Food Additives, Propionic acid, Springer, Berlin, Germany, pp 145-151.
  3. Luck, E., Jager, M., 1997. Antimicrobial Food Additives: Benzoic acid, Springer, Berlin, Germany, pp 174-182.
  4. Luck, E., Jager, M., 1997. Antimicrobial Food Additives, Sorbic Acid, Springer, Berlin, Germany, 152-167.
  5. Ministry of Food and Drug Safety (MFDS), (2023, May 15). Standards for use by item. Retrieved from http://www.foodsafetykorea.go.kr/foodcode/04_03.jsp?idx=820
  6. Ministry of Food and Drug Safety (MFDS), (2023, May 15). Notice of partial revision of "Standard and specifications for food additives". Retrieved from https://www.mfds.go.kr/brd/m_99/down.do?brd_id=ntc0021&seq=44090&data_tp=A&file_seq=1
  7. Ministry of Food and Drug Safety (MFDS), (2023, May 15). Notice of partial revision of "Standard and specifications for food additives" Retrieved from https://www.mfds.go.kr/brd/m_99/down.do?brd_id=ntc0021&seq=44822&data_tp=A& file_seq=1
  8. U.S. Food and Drug Administration (FDA), (2023, May 15). Food additives status list. Retrieved from https://www.fda.gov/food/food-additives-petitions/food-additive-status-list
  9. Minister for Health, Labour and Welfare, (2023, May 15). Standards for use, according to use categories. Retrieved from https://www.ffcr.or.jp/en/upload/StandardsforUseFeb32021.pdf
  10. Australia New Zealand Food Authority, (2023, May 15). Substances that may be used as food additives. Retrieved from https://www.foodstandards.gov.au/code/Documents/Sched%2015%20Food%20additives%20v157.pdf
  11. World Health Organization (WHO), (2023, May 15). Evaluations of the joint FAO/WHO expert committee on food additives (JECFA), propionic acid. Retrived from https://apps.who.int/food-additives-contaminants-jecfa-database/Home/Chemical/3438
  12. World Health Organization (WHO), (2023, May 15). Evaluations of the joint FAO/WHO expert committee on food additives (JECFA), sorbic acid. Retrived from https://apps.who.int/food-additives-contaminants-jecfa-database/Home/Chemical/2443
  13. World Health Organization (WHO), (2023, May 15). Evaluations of the joint FAO/WHO expert committee on food additives (JECFA), benzoic acid. Retrived from https://apps.who.int/foodadditives-contaminants-jecfa-database/Home/Chemical/4530
  14. Ministry of Food and Drug Safety (MFDS), (2023, May 15). Food and food additves production status. Retrived from https://www.index.go.kr/unity/potal/main/EachDtlPageDetail.do;jsessionid=oYfXUN3q_FiXqIh1uH0f_tQ7Q3ODfCVhljD1kf_G.node11?i dx_cd=2864
  15. Korea Rural Economy Institute (KREI), (2023, May 15). Processed food consumer attitude survey deep dive reports. Retrieved from https://www.krei.re.kr/foodInfo/selectBbsNttView.do?key=749&bbsNo=434&nttNo=159222&searchCtgry=&searchCnd=all&searchKrwd=&pageIndex=1&integrDeptCode=
  16. Korea Consumer Agency (KCA), (2023, May 15). Beer franchise pubs safety investigation in dried fish. Retrived from https://www.kca.go.kr/smartconsumer/board/download.do?menukey=7301&fno=10009467&bid=00000146&did=1001027578
  17. Yoon, M.H., Hong, H.G., Lee, I.S., Park, M.J., Yun, S.J., Park, J.H., Kwon, Y.O., A survey of the safety in seasoned dried fishes. J. Food Hyg. Saf., 24, 143-147 (2009).
  18. Korea Food Research Institute (KFRI), (2023, May 15). Monitoring of preservatives produced naturally in fisheries products. Retrieved from https://scienceon.kisti.re.kr/srch/selectPORSrchReport.do?cn=TRKO201900003414
  19. Ministry of Food and Drug Safety (MFDS), Food Code, MFDS, Cheongju, Korea (2023).
  20. Saito, I., Oshima, H., Kawamura, N., Uno, K., Yama, M., Determination of sorbic, dehydroacetic, and propionic acids in cheese by liquid chromatography and gas chromatography. J. Assoc. Off. Anal. Chem., 70, 507-509 (1987).
  21. Azzam, K., Saad, B., Hashim, N., Rahim, A., Talib, K., Determination of propionates and propionic acid in bakery products using gas chromatography. Int. Food Res. J., 17, 1107-1112 (2010).
  22. Tungkijanansin, N., Alahmad, W., Nhujak, T., Varanusupakul, P., Simultaneous determination of benzoic acid, sorbic acid, and propionic acid in fermented food by headspace solid-phase microextraction followed by GC-FID. Food Chem., 329, 127161 (2020).
  23. Saad, B., Bari, M.F., Saleh, M.I., Ahmad, K., Talib, M.K., Simultaneous determination of preservatives (benzoic acid, sorbic acid, methylparaben and propylparaben) in foodstuffs using high-performance liquid chromatography. J. Chromatogr. A, 1073, 393-397 (2005). https://doi.org/10.1016/j.chroma.2004.10.105
  24. Guarino, C., Fuselli, F., La Mantia, A., Longo, L., Development of an RP-HPLC method for the simultaneous determination of benzoic acid, sorbic acid, natamycin and lysozyme in hard and pasta filata cheeses. Food Chem., 127, 1294-1299 (2011). https://doi.org/10.1016/j.foodchem.2011.01.086
  25. Cheng, Z., Ran, Q., Liu, J., Deng, X., Qiu, H., Jia, Z., Su, X., Rapid Determination for benzoic acid, sorbic acid, phenyl-lactic acid, phenylalanine, and saccharin sodium in vinegar by high-performance liquid chromatography-UV. Food Anal. Methods, 13, 1673-1680 (2020). https://doi.org/10.1007/s12161-020-01784-6
  26. International Councol for Harmonisation of Technical Requirements for Pharmaceuticals for Human Use (ICH), (2023, May 15). Validation of Analytical Procedures: Text and Methodology, Q2(R1). Retrieved from https://database.ich.org/sites/default/files/Q2%28R1%29%20Guideline.pdf
  27. Ministry of Food and Drug Safety (MFDS), Guidelines on standard procedures for preparing analysis method, MFDS, Cheongju, Korea (2016).
  28. Yun, S.S., Kim, J., Lee, S.J., So, J.S., Lee, M.Y., Lee, G., Lim, H.S., Kim, M., Naturally occurring benzoic, sorbic, and propionic acid in vegetables. Food Addit. Contam. Part B, 12, 167-174 (2019). https://doi.org/10.1080/19393210.2019.1579760
  29. Seo, Y., Sung, M., Hwang, J., Yoon, Y., Minimum inhibitory concentration (MIC) of propionic acid, sorbic acid, and benzoic acid against food spoilage microorganisms in animal products to use MIC as threshold for natural preservative production. Food Sci. Anim. Resour., 319-330 (2022).
  30. Kim, D.B., Jang, G.J., Yoo, M., Lee, G., Yun, S.S., Lim, H.S., Kim, M., Lee, S., Sorbic, benzoic and propionic acids in fishery products: a survey of the South Korean market. Food Addit. Contam. Part A, 35, 1071-1077 (2018). https://doi.org/10.1080/19440049.2018.1447692
  31. Noh, J.E., Kim, B.K., Kim, H.K., Kwon, J.H., Effects of γ - irradiation on the quality of seasoned cuttle during storage. J. Korean Soc. Food Cult., 19, 516-523 (2004).
  32. Gonzalez-Garcia, R.A., McCubbin, T., Navone, L., Stowers, C., Nielsen, L.K., Marcellin, E., Microbial propionic acid production. Ferment., 3, 21 (2017).
  33. Korea Health Industry Development Institute (KHIDI), (2023, May 15). Dietary intake of food additive by Korean population - Preservatives, antioxidant. Retrieved from https://scienceon.kisti.re.kr/srch/selectPORSrchReport.do?cn=TRKO201700002026
  34. Oh, C.H., Naturally occurring propionic acid analysis in seasoned cod by direct solvent extraction. J. Korean Soc. Food Sci. Nutr., 47, 742-749 (2018). https://doi.org/10.3746/jkfn.2018.47.7.742
  35. U.S. Food & Drug Administration (FDA), (2023, March 28). Code of federal regulations title 21. Retrieved from https://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr=184.1021
  36. Sieber, R., Butikofer, U., Bosset, J.O., Benzoic acid as a natural compound in cultured dairy products and cheese. Int Dairy J., 5, 227-246 (1995).
  37. Han, N., Park, S.Y., Kim, S.Y., Yoo, M.Y., Paik, H.D., Lim, S.D., Change of naturally occurring benzoic acid during skim milk fermentation by commercial cheese starters. J. Dairy Sci., 99, 8633-8637 (2016). https://doi.org/10.3168/jds.2016-10890