과제정보
Funding for this work was mainly provided through the federal Student Work Placement Program (SWPP). The CANDU Owners Group (COG) and Canadian Nuclear Laboratories are thanked for funding initial R&D work that inspired this project. Purolite is thanked for providing all resin free-of-charge. Ms. Fiona Baker and Ms. Blerina Vata are thanked for assisting with experiments and performing UV-Vis analysis, and Mr. Ben Loder and Mr. Steven Cogswell are thanked for performing IC and SEM analysis, respectively. The authors are also grateful to Dr. Craig Stuart for input and helpful discussions.
참고문헌
- W. Cook, D. Lister, Chapter 15 - chemistry in CANDU process systems, in: Essential CANDU, UNENE, 2014.
- D. Lister, W. Cook, Chapter 14 - nuclear plant materials and corrosion, in: Essential CANDU, UNENE, 2014.
- O. Palazhchenko, W. Cook, A. Martin, D. Taylor, Heat transfer add-on to the UNB-CNER CANDU-6 PHT system material transport model, J. Power Plant Chem. 22 (6) (2020) 262-273.
- O. Palazhchenko, W. Cook, A. Martin, J. Lennox, Update on predicting RIHT using the UNB-CNER CANDU-6 PHT system model, J. Power Plant Chem. 23 (3) (2021) 122-131.
- R.E. Mesmer, D.L. Herting, Thermodynamics of ionization of D2O and D2PO4-, J. Solut. Chem. 7 (12) (1978) 901-913. https://doi.org/10.1007/BF00645300
- J. Crittenden, R. Trussell, D. Hand, K. Howe, G. Tchobanoglous, 16. Ion exchange, in: MWH's Water Treatment: Principles and Design, third ed., John Wiley & Sons, Inc., 2012, pp. 1277-1279.
- S.D. Faust, O.M. Aly, Removal of scale-forming substances, in: Chemistry of Water Treatment, Butterworth Publishers, Woburn, MA, 1983, pp. 424-425.
- L. Qui, A. Snaglewski, Lithium adsorption on magnetite, lepidocrocite, and maghemite at elevated temperatures, Nucl. Sci. Eng. 179 (2015) 199-210. https://doi.org/10.13182/NSE13-93
- S. Suryanarayan, D. Jain, Lithium control during normal operation, in: International Conference on Water Chemistry of Nuclear Reactor Systems (Nuclear Plant Chemistry Conference), 2010. Quebec City.
- H. Cady, R. Connick, The determination of the formulas of aqueous ruthenium (III) species by means of ion-exchange resin: Ru+, RuCl2+, and RuCl2, J. Am. Chem. Soc. 80 (11) (1959) 2646-2652.
- E. Sikora, V. Hadju, G. Muranszky, K.K.I. Katona, T. Kanazawa, B. Fiser, B. Viskolcz, L. Vanyorek, Application of ion-exchange resin beads to produce magnetic adsorbents, Chem. Pap. 75 (11) (2021) 1187-1195. https://doi.org/10.1007/s11696-020-01376-y
- E. Tokar, A. Matskevich, M. Palamarchuk, Y.A. Parotkina, A. Egorin, Decontamination of spent ion exchange resins contaminated with iron-oxide deposits using mineral acid solutions, J. Nucl. Sci. Technol. 53 (9) (2021) 2918-2925. https://doi.org/10.1016/j.net.2021.03.022
- J. Sawicki, P. Sefranek, S. Fisher, Depth distribution and chemical form of iron in low cross-linked crud-removing resin beds, Nucl. Instrum. Methods Phys. Res. Sect. B Beam Interact. Mater. Atoms 142 (1-2) (1998) 122-132. https://doi.org/10.1016/S0168-583X(98)00231-6
- K. Otoha, K. Izumi, T. Hayashi, Y. Morikawa, H. Murabayashi, Crud removal performance with ion exchange resins in BWR plants, J. Nucl. Sci. Technol. 33 (1) (1996) 52-61. https://doi.org/10.1080/18811248.1996.9731861
- W. Rudolph, M. Brooker, P. Tremaine, Raman spectroscopic investigation of aqueous FeSO4 in neutral and acidic solutions from 25 ℃ to303 ℃: inner- and outer-sphere complexes, J. Solut. Chem. 26 (8) (1997) 757-777. https://doi.org/10.1007/BF02767782
- J. Mehlig, R. Hulett, Spectrophotometric determination of iron with o-phenanthroline and with nitro-o-phenanthroline, Indus. Eng. Chem. Analyt. Edition 14 (11) (1942) 869-871. https://doi.org/10.1021/i560111a018
- D. Caldwell, R.B. Adams, Colorimetric determination of iron in water with o-phenanthroline, Am. Water Works Associat. 38 (6) (1946) 727-730. https://doi.org/10.1002/j.1551-8833.1946.tb16130.x
- S. Smith, D. Williams, R. Miller, Solubility of lithium carbonate at elevated temperatures, J. Chem. Eng. Data 16 (1) (1971) 74-75. https://doi.org/10.1021/je60048a022
- Product data sheet Purolite® NRW-100-Li [Online]. Available: www.purolite.com.
- Product data sheet Purolite® NRW-400 [Online]. Available: www.purolite.com.
- Product data sheet Purolite® NRW-3240-LiLC [Online]. Available: www.purolite.com.
- A.E. Harvey, J.A. Smart, E.S. Aims, Simultaneous spectrophotometric determination of iron(II) and total iron with 1,10-phenanthroline, Anal. Chem. 27 (1) (1955) 26-29. https://doi.org/10.1021/ac60097a009
- D. Barber, B. Nott, Kinetic imbalance in mixed bed ion exchange, in: Water Chemistry of Nuclear Reactor Systems 5, British Nuclear Energy Society, 1989, pp. 257-262.
- P. Tremaine, J. LeBlanc, The solubility of magnetite and the hydrolysis and oxidation of Fe2+ in water to 300 ℃, J. Solut. Chem. 9 (1980) 415-442. https://doi.org/10.1007/BF00645517
- R.J. Lemire, U. Berner, D.A. Palmer, O. Tochiyama, C. Musikas, P. Taylor, Chemical thermodynamics of iron: Part I, in: Chemical Thermodynamics, vol. 13a, Organization for Economic Co-operation and Development (OECD), 2013, pp. 125-137.
- D. Miller, R. Siriwardane, D. Mcintyre, Anion structural effects on interaction of rare earth element ions with Dowex 50W X8 cation exchange resin, J. Rare Earths 36 (2018) 879-890.
- T. Kimura, Y. Kato, H. Takeishi, G. Choppin, Comparative study on the hydration states of Cm(III) and Eu(III) in solution and in cation exchange resin, J. Alloys Compd. 271-273 (1998) 719-722. https://doi.org/10.1016/S0925-8388(98)00194-7
- I. Rhee, D. Dzombak, Binary and ternary cation exchange on strong acid cation exchange resin involving Na, Mg, and Zn in single and binary backgrounds of chloride, perchlorate, and sulfate, Langmuir 15 (1999) 6875-6883. https://doi.org/10.1021/la970031g