DOI QR코드

DOI QR Code

Effect of Cementitious Materials on Compressive Strength and Self-healing Properties of Cement Mortars Containing Chitosan-Based Polymer

  • Jae-In Lee (Dept. of Architectural Engineering, Wonkwang University) ;
  • Chae-Young Kim (Dept. of Architectural Engineering, Wonkwang University) ;
  • Joo-Ho Yoon (Dept. of Architectural Engineering, Wonkwang University) ;
  • Se-Jin Choi (Dept of Architectural Engineering, Wonkwang University)
  • 투고 : 2023.06.07
  • 심사 : 2023.09.19
  • 발행 : 2023.09.30

초록

Concrete is widely used in the construction industry; however, it has the disadvantage of deteriorating durability due to cracks occurring because of climate change and shrinkage. In addition, when cement is used as a binder, CO2 emitted during the manu-facturing process accounts for ~8% of global CO2 emissions. In this study, ecofriendly cementitious materials such as blast furnace slag powder and fly ash (FA) were used as cement substitutes in the production of mortar containing a chitosan-based polymer (CP), and their fluidity, compressive strength, and self-healing performance were examined. The 28-day compressive strength of the control sample was ~32.4 MPa (the lowest for all tested samples), while that of the sample containing 5% CP and 20% FA was ~49.6 MPa (the highest for all tested samples) and ~53.1% higher than that of the control sample. Even at a healing age of 56 days, the control sample exhibited the lowest healing performance, whereas the samples containing CP (5%, 10%) and 20% FA demonstrated excellent healing performance. After 28 days, the decrease in crack size for the control sample was minimal; however, for the sample containing only cement and CP, a significant decrease in crack size was observed even after 28 days. This study confirmed that the appropriate use of CP and cementitious materials improves not only compressive strength but also the selfhealing performance of mortar.

키워드

과제정보

This research was supported by the Basic Science Research Program through the National Research Foundation of Korea, funded by the Ministry of Education (NRF-2019R1I1A3A01049510).

참고문헌

  1. Bulut, H.A., & Sahin, R. (2017). "A study on mechanical properties of polymer concrete containing electronic plastic waste", Compos Struct, 178(15), 50-62.  https://doi.org/10.1016/j.compstruct.2017.06.058
  2. Chen, M., Zhong, H., & Zhang, M. (2020). "Flexural fatigue behavior of recycled tyre polymer fibre reinforced concrete", Cem Concr Compos, 105, 103441. 
  3. Choi, S.J., Bae, S.H., Lee, J.I., Bang, E.J & Ko, H.M. (2021). "Strength, carbonation resistance, and chloride-ion penetrability of cement mortars containing catechol-functionalized chitosan polymer", Materials, 14(21), 6395. 
  4. Choi, S.J., Bae, S.H., Choi, H.Y., & Ko, H.M. (2022). "Engineering characteristics of cement composite containing a chitosanbased polymer and steel slag aggregates", Polymers, 14(3), 626. 
  5. Choi, S.J., Bae, S.H., Lee, J.I., Bang, E.J., Choi, H.Y., & Ko, H.M. (2022). "Effect of bio-inspired polymer types on engineering characteristics of cement composites", Polymers, 14(9), 1808. 
  6. Duan, Y., Wang, Q., Long, Z., & Wang, X. (2023). "Investigating the impact of fly ash on the strength and micro-structure of concrete during steam curing and subsequent stages", Materials, 16(4), 1326. 
  7. Herath, C., Gunasekara, C., Law, D.W., & Sujeeva, S. (2020). "Performance on high-volume fly ash concrete incorporating additives: A systemic literature review", Constr Build Mater, 258, 12606 
  8. KS L 5105. (2007). Testing method for compressive strength of hydration cement mortar, Korea Industrial Standards, Seoul, Korea Standards & Certification Information Center. 
  9. Kim, M.O. (2020). "Influence of polymer types on the mechanical properties of polymer modified cement mortars", Appl Sci, 10(3), 1061. 
  10. KCI-CT114. (2021). Constant water head permeability test method for the evaluation of self-healing performance of mortars, Korea Concrete Institute. 
  11. Kim, C.G., Choi, Y.W., Choi, S., & Oh, S.R. (2022). "A study on the healing performance of mortar with microcapsules using silicate-based inorganic materials", Materials, 15(24), 8907. 
  12. Liu, Q., Lu, Z., Hu, X., Chen, B., Li, Z., Liang, R., & Sun, G. (2021). "A mechanical strong polymer-cement composite fabricated by in situ polymerization within the cement matrix", J Build Eng, 42, 103048. 
  13. Lee, J.I., Kim, C.Y., & Choi, S.J. (2022). "An experimental study on engineering properties of self-healing mortar according to PCC (Powder Compacted Capsule) size and mixing ratio", J Korean Recycled Constr Resour Inst, 10(4), 514-522. 
  14. Lee, J.I., Bae, S.H., Kim, J.H., & Choi, S.J. (2022). "Effect of cementitious materials on the engineering properties of lightweight aggregate mortars containing recycled water", Materials, 15(5), 1967. 
  15. Lee, J.I., Kim, C.Y., Yoon, J.H., & Choi, S.J. (2023). "Mechanical properties of cement mortar containing ground waste newspaper as cementitious material", Materials, 16(4), 1374. 
  16. Lee, J.I., & Choi, S.J. (2023). "Effect of replacement ratio of ferronickel slag aggregate on characteristics of cementitious mortars at different curing temperatures", Case Stud Constr Mater, 18, e01882. 
  17. Lee, J.I., & Choi, S.J. (2023). "Mechanics and Durability Characteristics of Cement Mortar Using Cementitious Materials-based Capsule and Amorphous Metallic Fibers", J.AIK, 39, 5, 207-214.  https://doi.org/10.5659/JAIK.2023.39.5.207
  18. Luan, C., Yuan, L., Wang, J., Zhou, Z. (2023) "Uncovering the Mechanism of the Role of Fly Ash in the Self-Healing Ability of Mortar with Different Curing Ages", Materials, 16, 9, 3453. 
  19. Mohammed, H., Ortoneda, P.M., Nakoutim I., & Bras, V. (2020). "Experimental characteristics of non-encapsulated bio-based concrete with self-healing capacity", Constr Build Mater, 256, 119411. 
  20. Nie, S., Zhou, J., Yang, F., Lan, M., Li, J., Zhang, Z., Chen, Z., Xu, M., Li, H., & Sanjayan, J.G. (2022). "Analysis of theoretical carbon dioxide emissions from cement production: Methodology and application", J Clean Prod, 334, 130270. 
  21. Shahsacarim R., & Hwang, S.H. (2018). "Morphogenesis of cement hydrate: From natural C-S-H to synthetic C-S-H", Cement Based Materials. In Tech. 
  22. Teh S.H., Weidmann, T., Castel, A., & De, B.J. (2017). "Hybrid life cycle assessment of greenhouse gas emissions from cement, concrete and geopolymer concrete in Australia, J. Clean, Prod, 152(20), 312-320.  https://doi.org/10.1016/j.jclepro.2017.03.122
  23. Tan, Y., Chen, H., Wang, Z., Xue, C., & He, R. (2019). " Performance of cement mortar incorporating superabsorbent polymer (SAP) using different dosing method", Materials, 12(10), 1619. 
  24. Wang, P., Xie, M., & Liu, L. (2022). "Study on early shrinkage and mechanical properties of concrete with various cementitious materials, Buildings, 12(10), 1543. 
  25. Yalcinkaya, C., & Copuroglu, O. (2021). "Hydration heat, strength and microstructure characteristics of UHPC containing blast furnace slag", J Build Eng, 34, 10915. 
  26. Zhang, X., Fang, H., Du, M., Shi, M., & Zhang, C. (2021). "Experimental study on the mechanical properties of the fiber cement mortar containing polyurethane", Adv Mater Sci Eng, 2021, 9956897