Journal of the korean academy of Pediatric Dentistry (대한소아치과학회지)

Korean Academy of Pediatric Dentistry (대한소아치과학회)
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Evaluation of Setting Time, Solubility, and Compressive Strength of Four Calcium Silicate-Based Cements

네 가지 규산 칼슘계 시멘트의 경화시간, 용해도, 압축강도 평가

  • Yuji Jang (Department of Pediatric Dentistry, College of Dentistry, Dankook University) ;
  • Yujin Kim (Department of Biomaterials Science, College of Dentistry, Dankook University) ;
  • Junghwan Lee (Department of Biomaterials Science, College of Dentistry, Dankook University) ;
  • Jongsoo Kim (Department of Pediatric Dentistry, College of Dentistry, Dankook University) ;
  • Joonhaeng Lee (Department of Pediatric Dentistry, College of Dentistry, Dankook University) ;
  • Mi Ran Han (Department of Pediatric Dentistry, College of Dentistry, Dankook University) ;
  • Jongbin Kim (Department of Pediatric Dentistry, College of Dentistry, Dankook University) ;
  • Jisun Shin (Department of Pediatric Dentistry, College of Dentistry, Dankook University)
  • 장유지 (단국대학교 치과대학 소아치과학교실) ;
  • 김유진 (단국대학교 치과대학 생체재료학교실) ;
  • 이정환 (단국대학교 치과대학 생체재료학교실) ;
  • 김종수 (단국대학교 치과대학 소아치과학교실) ;
  • 이준행 (단국대학교 치과대학 소아치과학교실) ;
  • 한미란 (단국대학교 치과대학 소아치과학교실) ;
  • 김종빈 (단국대학교 치과대학 소아치과학교실) ;
  • 신지선 (단국대학교 치과대학 소아치과학교실)
  • Received : 2023.03.18
  • Accepted : 2023.05.12
  • Published : 2023.05.31
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Abstract

This study aimed to compare the physical properties of 4 kinds of calcium silicate-based cements (CSCs): 2 kinds of powder-liquid mix type (RetroMTA® [RTMX] and Endocem® MTA Zr [EZMX]) and 2 kinds of premixed type (Well-RootTMPT [WRPR] and Endocem® MTA premixed [ECPR]) CSCs, respectively. Further, we assessed the setting times, solubility values, and compressive strengths of the cements. The shortest setting time was observed for EZMX (123.33 ± 5.77 seconds), followed by RTMX (146.67 ± 5.77 seconds), ECPR (260.00 ± 17.32 seconds), and WRPR (460.00 ± 17.32 seconds), respectively. The highest solubility was observed for WRPR (9.01 ± 0.55%), followed by RTMX (2.17 ± 0.07%), EZMX (0.55 ± 0.03%), and ECPR (0.17 ± 0.03%). Furthermore, the highest compressive strength was observed for ECPR (76.67 ± 25.67 Mpa), followed by WRPR (38.39 ± 7.25 Mpa), RTMX (35.07 ± 5.34 Mpa), and EZMX (4.07 ± 0.60 Mpa). In conclusion, the premixed type CSCs (WRPR and ECPR) exhibited longer setting times compared to the powder-liquid mix type CSCs (EZMX and RTMX). The solubility test showed that ECPR had the lowest solubility while WRPR had the highest solubility, with a statistically significant difference between them (p < 0.0083). Additionally, the compressive strength test showed that ECPR had the highest compressive strength, while EZMX had the lowest compressive strength, also with a statistically significant difference between them (p < 0.0083). ECPR is a promising material as it is premixed, eliminating the need for mixing time, and it has also demonstrated improved solubility and compressive strength, making it a potentially favorable option for clinical use.

이 연구의 목적은 4가지 규산 칼슘계 시멘트를 대상으로 물리적 특성을 비교하고 평가하는 것이다. 2종의 분말-용액 혼합형 재료인 RetroMTA® [RTMX], Endocem® MTA Zr [EZMX] 그리고 2종의 기혼합형 재료인 Well-RootTMPT [WRPR], Endocem MTA® premixed [ECPR]를 사용하여 경화시간, 용해도 및 압축강도를 비교하였다. 가장 짧은 경화 시간은 EZMX (123.33 ± 5.77초)에서 관찰되었으며, RTMX (146.67 ± 5.77초), ECPR (260.00 ± 17.32초) 및 WRPR (460.00 ± 17.32초) 순으로 증가하였다. 가장 높은 용해도는 WRPR (9.01 ± 0.55%)에서 관찰되었으며, RTMX (2.17 ± 0.07%), EZMX(0.55 ± 0.03%) 및 ECPR (0.17 ± 0.03%) 순으로 감소하였다. 또한 압축강도는 ECPR(76.67 ± 25.67 Mpa)에서 가장 높게 나타났고, WRPR (38.39 ± 7.25 Mpa), RTMX(35.07 ± 5.34 Mpa), EZMX (4.07 ± 0.60 Mpa) 순으로 감소하였다. 결론적으로 기혼합형 규산 칼슘계 시멘트들은 분말-용액 혼합형에 비해 긴 경화 시간을 나타내었다. 용해도 실험 결과 가장 낮은 용해도를 보인 ECPR과 가장 높은 용해도를 보인 WRPR에서 통계적 차이가 관찰되었다(p < 0.0083). 압축강도 실험결과 가장 낮은 압축 강도를 보인 EZMX와 가장 높은 압축 강도를 보인 ECPR에서 통계적 차이가 관찰되었다(p < 0.0083). ECPR은 분말-용액 혼합형에 비해 긴 경화 시간을 나타내지만, 미리 혼합되어 있어 혼합 시간이 필요하지 않고 용해도와 압축 강도가 개선되었으므로 임상 사용 시 선택될 수 있는 유망한 재료이다.

Keywords

Acknowledgement

This work was supported by the Basic Science Research Program funded by the Ministry of Education (NRF-2022R1I1A1A01069606).

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