한국환경과학회지 (Journal of Environmental Science International)

  • 제32권8호
  • /
  • Pages.563-572
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  • 2023
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  • 1225-4517(pISSN)
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  • 2287-3503(eISSN)
한국환경과학회 (The Korean Environmental Sciences Society)
권호 표지
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제주 스코리아의 제올라이트화에 따른 구리와 아연 이온의 흡착 용량 변화

Variation of Copper and Zinc-Ion Adsorption Capacity via Zeolitification of Jeju Scoria

  • 이창한 (부산가톨릭대학교 환경행정학과) ;
  • 감상규 (제주대학교 환경공학과) ;
  • 허철구 (제주대학교 환경공학과)
  • Chang-Han Lee (Department of Environmental Engineering, Jeju National University) ;
  • Sang-Kyu, Kam (Department of Environmental Administration, Catholic University of Pusan) ;
  • Chul-Goo Hu (Department of Environmental Administration, Catholic University of Pusan)
  • 투고 : 2023.07.28
  • 심사 : 2023.08.21
  • 발행 : 2023.08.31
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초록

Scoria from Jeju-island (Jeju scoria) was converted into zeolitic material (Z-SA) via zeolitification using the fusion/hydrothermal method. Jeju scoria could be synthesized into Z-SA to from a surface covered with Na-A zeolite crystals, which was confirmed through an analysis of X-ray diffraction peak patterns and scanning electron microscopy images. Jeju scoria and Z-SA were employed as adsorbents to evaluate the adsorption rate and adsorption capacities for Cu2+ and Zn2+ ions. The adsorption rates and isothermal adsorption capacities could be well fitted by the pseudo-quadratic adsorption kinetics and Langmuir adsorption isotherm, respectively. The maximum adsorption capacities (qm) of Z-SA for Cu2+ and Zn2+ ions were found to be 163.36 mg/g and 120.51 mg/g, respectively, using the Langmuir adsorption isotherm. When Z-SA is synthesized from Jeju scoria via zeolitification using the fusion/hydrothermal method, Z-SA exhibits an adsorption capacity that is more than approximately 100 times the value exhibited by Jeju scoria. As a result, the synthesized Z-SA was regarded as an effective, economic adsorbent.

키워드

참고문헌

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