Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Effects of Chloride and Sulfate Ions on Corrosion Behaviors of Structural Materials Based on Design of Experiment

실험계획에 기반한 수돗물 성분(Chloride and Sulfate Ions)의 구조재료 부식 영향성 고찰

  • Dong-In Lim (Aero Technology Research Institute, Republic of Korea Air Force) ;
  • Heng-Su Noh (Aero Technology Research Institute, Republic of Korea Air Force) ;
  • Hyeok-Jun Kwon (Department of Materials Science and Engineering, Yonsei University) ;
  • Sung-Ryul Park (Aero Technology Research Institute, Republic of Korea Air Force) ;
  • Man-Sik Jo (Aero Technology Research Institute, Republic of Korea Air Force) ;
  • Doo-Youl Lee (Department of Defense Science, Korea National Defense University)
  • Received : 2022.12.01
  • Accepted : 2023.04.13
  • Published : 2023.06.30
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Abstract

Corrosion management of an aircraft and its engine relies on rinsing and cleaning using tap water. Few studies have reported effects of tap water species on corrosion behaviors of structural materials. In this study, a series of experiments were conducted based on the design of experiment. Solutions with different levels of chloride and sulfate ions were prepared using a full factorial design. Two structural materials (aluminum alloy and steel) were used for an alternate immersion test. Weight loss was then measured. In addition, a silver specimen was utilized as a sensor for chloride deposition measurement. The silver specimen was examined using the electrochemical reduction method, XPS, and SEM-EDS. Surface analysis revealed that levels of chloride and sulfate ions were sufficient for the formation of silver chloride and silver surface. Statistical analysis of weight loss and chloride deposition rate showed significant differences in measured values. Concentration of chloride ions greatly affected corrosion behaviors of structural materials. Sulfate ion hindered the adsorption reaction. These results emphasize the importance of controlling ion concentration of tap water used for cleaning and rinsing an aircraft.

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