Acknowledgement
This work was supported by Korea Institute of Planning and Evaluation for Technology in Food, Agriculture and Forestry(IPET) and Korea Smart Farm R&D Foundation(KosFarm) through Smart Farm Innovation Technology Development Program, funded by Ministry of Agriculture, Food and Rural Affairs(MAFRA) and Ministry of Science and ICT(MSIT), Rural Development Administration(RDA) (421037033HD020).
References
- I. Staffell, D. Scamman, A. V. Abad, P. Balcombe, P. E. Dodds, P. Ekins, N. Shah, and K. R. Ward, The role of hydrogen and fuel cells in the global energy system, Energy Environ. Sci., 12, 463-491 (2019). https://doi.org/10.1039/C8EE01157E
- A. Ajanovic, and R. Haas, Prospects and impediments for hydrogen and fuel cell vehicles in the transport sector, Int. J. Hydrog. Energy, 46, 10049-10058 (2021). https://doi.org/10.1016/j.ijhydene.2020.03.122
- J. D. Fonseca, M. Camargo, J.-M. Commenge, L. Falk, and I. D. Gil, Trends in design of distributed energy systems using hydrogen as energy vector: A systematic literature review, Int. J. Hydrog. Energy, 44, 9486-9504 (2019). https://doi.org/10.1016/j.ijhydene.2018.09.177
- H. Lund, Renewable energy strategies for sustainable development, Energy, 32, 912-919 (2007). https://doi.org/10.1016/j.energy.2006.10.017
- S. Mekhilef, R. Saidur, and A. Safari, Comparative study of different fuel cell technologies, Renew. Sustain. Energy Rev., 16, 981-989 (2012). https://doi.org/10.1016/j.rser.2011.09.020
- V. Spallina, P. Nocerino, M. C. Romano, M. van Sint Annaland, S. Campanari, and F. Gallucci, Integration of solid oxide fuel cell (SOFC) and chemical looping combustion (CLC) for ultra-high efficiency power generation and CO2 production, Int. J. Greenh. Gas Control., 71, 9-19 (2018). https://doi.org/10.1016/j.ijggc.2018.02.005
- S. C. Singhal, Advances in solid oxide fuel cell technology, Solid State Ion., 135, 305-313 (2000). https://doi.org/10.1016/S0167-2738(00)00452-5
- N. Q. Minh, Solid oxide fuel cell technology-features and applications, Solid State Ion., 174, 271-277 (2004). https://doi.org/10.1016/j.ssi.2004.07.042
- R. O'hayre, S.-W. Cha, W. Colella, and F. B. Prinz, Fuel Cell Fundamentals, 3rd ed., John Wiley & Sons, New Jersey, USA (2016).
- S. A. Saadabadi, B. Illathukandy, and P. V. Aravind, Direct internal methane reforming in biogas fuelled solid oxide fuel cell; The influence of operating parameters, Energy Sci. Eng., 9, 1232-1248 (2021). https://doi.org/10.1002/ese3.887
- N. Shi, Y. Xie, Y. Yang, S. Xue, X. Li, K. Zhu, D. Huan, R. Peng, C. Xia, and Y. Lu, Review of anodic reactions in hydrocarbon fueled solid oxide fuel cells and strategies to improve anode performance and stability, Mater. Renew. Sustain. Energy, 9, 1-18 (2020). https://doi.org/10.1007/s40243-019-0161-0
- J. Ma, C. Jiang, P. A. Connor, M. Cassidy, and J. T. Irvine, Highly efficient, coking-resistant SOFCs for energy conversion using biogas fuels, J. Mater. Chem. A, 3, 19068-19076 (2015). https://doi.org/10.1039/C5TA06421J
- L. Shu, J. Sunarso, S. S. Hashim, J. Mao, W. Zhou, and F. Liang, Advanced perovskite anodes for solid oxide fuel cells: A review, Int. J. Hydrog. Energy, 44, 31275-31304 (2019). https://doi.org/10.1016/j.ijhydene.2019.09.220
- H. Kim, Y. S. Chung, T. Kim, H. Yoon, J. G. Sung, H. K. Jung, W. B. Kim, L. B. Sammes, and J. S. Chung, Ru-doped barium strontium titanates of the cathode for the electrochemical synthesis of ammonia, Solid State Ion., 339, 115010 (2019).
- X. M. Ge, S. H. Chan, Q. L. Liu, and Q. Sun, Solid oxide fuel cell anode materials for direct hydrocarbon utilization, Adv. Energy Mater., 2, 1156-1181 (2012). https://doi.org/10.1002/aenm.201200342
- S. Tao, and J. T. Irvine, A redox-stable efficient anode for solid-oxide fuel cells, Nat. Mater., 2, 320-323 (2003). https://doi.org/10.1038/nmat871
- P. Vernoux, M. Guillodo, J. Fouletier, and A. Hammou, Alternative anode material for gradual methane reforming in solid oxide fuel cells, Solid State Ion., 135, 425-431 (2000). https://doi.org/10.1016/S0167-2738(00)00390-8
- N. Danilovic, A. Vincent, J.-L. Luo, K. T. Chuang, R. Hui, and A. R. Sanger, Correlation of fuel cell anode electrocatalytic and ex situ catalytic activity of perovskites La0.75Sr0.25Cr0.5X0.5O3-δ (X=Ti, Mn, Fe, Co), Chem. Mater., 22, 957-965 (2010). https://doi.org/10.1021/cm901875u
- S. McIntosh, and M. Van den Bossche, Influence of lattice oxygen stoichiometry on the mechanism of methane oxidation in SOFC anodes, Solid State Ion., 192, 453-457 (2011). https://doi.org/10.1016/j.ssi.2010.07.019
- C. Aliotta, L. Liotta, F. Deganello, V. La Parola, and A. Martorana, Direct methane oxidation on La1-xSrxCr1-yFeyO3-δ perovskitetype oxides as potential anode for intermediate temperature solid oxide fuel cells, Appl. Catal. B: Environ., 180, 424-433 (2016). https://doi.org/10.1016/j.apcatb.2015.06.012
- Y. Liu, S. Wang, J. Qian, X. Xin, Z. Zhan, and T. Wen, A novel catalytic layer material for direct dry methane solid oxide fuel cell, Int. J. Hydrog. Energy, 38, 14053-14059 (2013). https://doi.org/10.1016/j.ijhydene.2013.07.023
- F. Liu, L. Zhang, G. Huang, B. Niu, X. Li, L. Wang, J. Zhao, and Y. Jin, High performance ferrite-based anode La0.5Sr0.5Fe0.9Mo0.1O3-δ for intermediate-temperature solid oxide fuel cell, Electrochim. Acta, 255, 118-126 (2017). https://doi.org/10.1016/j.electacta.2017.09.157
- X. Zhou, N. Yan, K. T. Chuang, and J. Luo, Progress in La-doped SrTiO3 (LST)-based anode materials for solid oxide fuel cells, RSC Adv., 4, 118-131 (2014). https://doi.org/10.1039/C3RA42666A
- K. B. Yoo, B. H. Park, and G. M. Choi, Stability and performance of SOFC with SrTiO3-based anode in CH4 fuel, Solid State Ion., 225, 104-107 (2012). https://doi.org/10.1016/j.ssi.2012.05.017
- S. Sengodan, S. Choi, A. Jun, T. H. Shin, Y.-W. Ju, H. Y. Jeong, J. Shin, J. T. Irvine, and G. Kim, Layered oxygen-deficient double perovskite as an efficient and stable anode for direct hydrocarbon solid oxide fuel cells, Nat. Mater., 14, 205-209 (2015). https://doi.org/10.1038/nmat4166
- R. Dass, J.-Q. Yan, and J. Goodenough, Oxygen stoichiometry, ferromagnetism, and transport properties of La2-x NiMnO6+δ, Phys. Rev. B, 68, 064415 (2003).
- M. K. Rath, and K.-T. Lee, Characterization of novel Ba2LnMoO6 (Ln= Pr and Nd) double perovskite as the anode material for hydrocarbon-fueled solid oxide fuel cells, J. Alloys Compd., 737, 152-159 (2018). https://doi.org/10.1016/j.jallcom.2017.12.090
- Y.-H. Huang, R. I. Dass, Z.-L. Xing, and J. B. Goodenough, Double perovskites as anode materials for solid-oxide fuel cells, Science, 312, 254-257 (2006). https://doi.org/10.1126/science.1125877
- P. Zhang, Y.-H. Huang, J.-G. Cheng, Z.-Q. Mao, and J. B. Goodenough, Sr2CoMoO6 anode for solid oxide fuel cell running on H2 and CH4 fuels, J. Power Sources, 196, 1738-1743 (2011). https://doi.org/10.1016/j.jpowsour.2010.10.007
- N. Yu, T. Liu, X. Chen, M. Miao, M. Ni, and Y. Wang, Co-generation of liquid chemicals and electricity over Co-Fe alloy/perovskite anode catalyst in a propane fueled solid oxide fuel cell, Sep. Purif. Technol., 291, 120890 (2022).
- K.-Y. Lai, and A. Manthiram, Self-regenerating Co-Fe nanoparticles on perovskite oxides as a hydrocarbon fuel oxidation catalyst in solid oxide fuel cells, Chem. Mater., 30, 2515-2525 (2018). https://doi.org/10.1021/acs.chemmater.7b04569
- D. E. Fowler, A. C. Messner, E. C. Miller, B. W. Slone, S. A. Barnett, and K. R. Poeppelmeier, Decreasing the polarization resistance of (La, Sr) CrO3-δ solid oxide fuel cell anodes by combined Fe and Ru substitution, Chem. Mater., 27, 3683-3693 (2015). https://doi.org/10.1021/acs.chemmater.5b00622
- M. Qin, Y. Xiao, H. Yang, T. Tan, Z. Wang, X. Fan, and C. Yang, Ru/Nb co-doped perovskite anode: Achieving good coking resistance in hydrocarbon fuels via core-shell nanocatalysts exsolution, Appl. Catal. B: Environ., 299, 120613 (2021).
- M. Wu, H. Yu, J. Ni, and C. Ni, Coke-resistant ferrite anode decorated with in-situ exsolved ceria for carbonaceous fuel oxidation, J. Power Sources, 552, 232266 (2022).
- M. L. Faro, D. La Rosa, I. Nicotera, V. Antonucci, and A. S. Arico, Electrochemical investigation of a propane-fed solid oxide fuel cell based on a composite Ni-perovskite anode catalyst, Appl. Catal. B: Environ., 89, 49-57 (2009). https://doi.org/10.1016/j.apcatb.2008.11.019
- K.-H. Huang, and J. Yeh, A study on the multicomponent alloy systems containing equal-mole elements, M.Sc. Thesis, National Tsing Hua University, Hsinchu, China (1996).
- B. Cantor, I. Chang, P. Knight, and A. Vincent, Microstructural development in equiatomic multicomponent alloys, Mater. Sci. Eng., 375, 213-218 (2004).
- J. W. Yeh, S. K. Chen, S. J. Lin, J. Y. Gan, T. S. Chin, T. T. Shun, C. H. Tsau, and S. Y. Chang, Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes, Adv. Eng. Mater., 6, 299-303 (2004). https://doi.org/10.1002/adem.200300567
- S. Senthil Kumar, and S. T. Aruna, Hydrocarbon compatible sofc anode catalysts and their syntheses: A review, Sustain. Chem., 2, 707-763 (2021). https://doi.org/10.3390/suschem2040039
- J. K. Pedersen, T. A. Batchelor, A. Bagger, and J. Rossmeisl, High-entropy alloys as catalysts for the CO2 and CO reduction reactions, ACS Catal., 10, 2169-2176 (2020). https://doi.org/10.1021/acscatal.9b04343
- T. Chen, W. G. Wang, H. Miao, T. Li, and C. Xu, Evaluation of carbon deposition behavior on the nickel/yttrium-stabilized zirconia anode-supported fuel cell fueled with simulated syngas, J. Power Sources, 196, 2461-2468 (2011). https://doi.org/10.1016/j.jpowsour.2010.11.095
- P. Zhang, Z. Yang, Y. Jin, C. Liu, Z. Lei, F. Chen, and S. Peng, Progress report on the catalyst layers for hydrocarbon-fueled SOFCs, Int. J. Hydrog. Energy, 46, 39369-39386 (2021). https://doi.org/10.1016/j.ijhydene.2021.09.198
- K. X. Lee, B. Hu, P. K. Dubey, M. Anisur, S. Belko, A. N. Aphale, and P. Singh, High-entropy alloy anode for direct internal steam reforming of methane in SOFC, Int. J. Hydrog. Energy, 47, 38372-38385 (2022). https://doi.org/10.1016/j.ijhydene.2022.09.018
- D. Chen, Y. Huan, G. Ma, M. Ma, X. Wang, X. Xie, J. Leng, X. Hu, and T. Wei, High-entropy alloys FeCoNiCuX (X = Al, Mo)-Ce0.8Sm0.2O2 as high-performance solid oxide fuel cell anodes, ACS Appl. Energy Mater., 6, 1076-1084 (2023). https://doi.org/10.1021/acsaem.2c03655
- H. Iwahara, Y. Asakura, K. Katahira, and M. Tanaka, Prospect of hydrogen technology using proton-conducting ceramics, Solid State Ion., 168, 299-310 (2004). https://doi.org/10.1016/j.ssi.2003.03.001
- L. Yang, S. Wang, K. Blinn, M. Liu, Z. Liu, Z. Cheng, and M. Liu, Enhanced sulfur and coking tolerance of a mixed ion conductor for SOFCs: BaZr0.1Ce0.7Y0.2-xYbxO3-δ, Science, 326, 126-129 (2009). https://doi.org/10.1126/science.1174811
- E. Fabbri, L. Bi, D. Pergolesi, and E. Traversa, Towards the next generation of solid oxide fuel cells operating below 600 ℃ with chemically stable proton-conducting electrolytes, Adv. Mater., 24, 195-208 (2012). https://doi.org/10.1002/adma.201103102
- B. Beyribey, H. Kim, and J. Persky, Electrochemical characterization of BaCe0.7Zr0.1Y0.16Zn0.04O3-δ electrolyte synthesized by combustion spray pyrolysis, Ceram. Int., 47, 1976-1979 (2021). https://doi.org/10.1016/j.ceramint.2020.09.028
- L. Yang, Y. Choi, W. Qin, H. Chen, K. Blinn, M. Liu, P. Liu, J. Bai, T. A. Tyson, and M. Liu, Promotion of water-mediated carbon removal by nanostructured barium oxide/nickel interfaces in solid oxide fuel cells, Nat. Commun., 2, 357 (2011).
- W. G. Coors, Protonic ceramic fuel cells for high-efficiency operation with methane, J. Power Sources, 118, 150-156 (2003). https://doi.org/10.1016/S0378-7753(03)00072-7
- Y. Feng, J. Luo, and K. T. Chuang, Propane dehydrogenation in a proton-conducting fuel cell, J. Phys. Chem. C, 112, 9943-9949 (2008). https://doi.org/10.1021/jp710141c
- Y. Feng, J.-L. Luo, and K. T. Chuang, Carbon deposition during propane dehydrogenation in a fuel cell, J. Power Sources, 167, 486-490 (2007). https://doi.org/10.1016/j.jpowsour.2007.02.052
- C. Duan, J. Tong, M. Shang, S. Nikodemski, M. Sanders, S. Ricote, A. Almansoori, and R. O'Hayre, Readily processed protonic ceramic fuel cells with high performance at low temperatures, Science, 349, 1321-1326 (2015). https://doi.org/10.1126/science.aab3987
- C. Duan, R. J. Kee, H. Zhu, C. Karakaya, Y. Chen, S. Ricote, A. Jarry, E. J. Crumlin, D. Hook, and R. Braun, Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells, Nature, 557, 217-222 (2018). https://doi.org/10.1038/s41586-018-0082-6
- S. Liu, K. T. Chuang, and J.-L. Luo, Double-layered perovskite anode with in situ exsolution of a Co-Fe alloy to cogenerate ethylene and electricity in a proton-conducting ethane fuel cell, ACS Catal., 6, 760-768 (2016). https://doi.org/10.1021/acscatal.5b02296
- B. Hua, N. Yan, M. Li, Y.-q. Zhang, Y.-f. Sun, J. Li, T. Etsell, P. Sarkar, K. Chuang, and J.-L. Luo, Novel layered solid oxide fuel cells with multiple-twinned Ni0.8Co0.2 nanoparticles: the key to thermally independent CO2 utilization and power-chemical cogeneration, Energy Environ. Sci., 9, 207-215 (2016). https://doi.org/10.1039/C5EE03017J
- X.-Z. Fu, J.-L. Luo, A. R. Sanger, Z.-R. Xu, and K. T. Chuang, Fabrication of bi-layered proton conducting membrane for hydrocarbon solid oxide fuel cell reactors, Electrochim. Acta, 55, 1145-1149 (2010). https://doi.org/10.1016/j.electacta.2009.10.010
- M. Li, B. Hua, J.-l. Luo, J. Pu, B. Chi, and L. Jian, Carbon-tolerant Ni-based cermet anodes modified by proton conducting yttrium-and ytterbium-doped barium cerates for direct methane solid oxide fuel cells, J. Mater. Chem. A, 3, 21609-21617 (2015). https://doi.org/10.1039/C5TA06488K
- L. Wang, Y. Fan, J. Li, L. Shao, X. Xi, X.-Z. Fu, and J.-L. Luo, La0.5Sr0.5Fe0.9Mo0.1O3-δ-CeO2 anode catalyst for Co-Producing electricity and ethylene from ethane in proton-conducting solid oxide fuel cells, Ceram. Int., 47, 24106-24114 (2021). https://doi.org/10.1016/j.ceramint.2021.05.121
- P. Qiu, S. Sun, X. Yang, F. Chen, C. Xiong, L. Jia, and J. Li, A review on anode on-cell catalyst reforming layer for direct methane solid oxide fuel cells, Int. J. Hydrog. Energy, 46, 25208-25224 (2021). https://doi.org/10.1016/j.ijhydene.2021.05.040
- A. D. Ballarini, S. R. de Miguel, E. L. Jablonski, O. A. Scelza, and A. A. Castro, Reforming of CH4 with CO2 on Pt-supported catalysts, Catal. Today, 107-108, 481-486 (2005). https://doi.org/10.1016/j.cattod.2005.07.058
- A. K. Avetisov, J. R. Rostrup-Nielsen, V. L. Kuchaev, J. H. Bak Hansen, A. G. Zyskin, and E. N. Shapatina, Steady-state kinetics and mechanism of methane reforming with steam and carbon dioxide over Ni catalyst, J. Mol. Catal. A: Chem., 315, 155-162 (2010). https://doi.org/10.1016/j.molcata.2009.06.013
- M. A. Nieva, M. M. Villaverde, A. Monzon, T. F. Garetto, and A. J. Marchi, Steam-methane reforming at low temperature on nickel-based catalysts, Chem. Eng. J., 235, 158-166 (2014). https://doi.org/10.1016/j.cej.2013.09.030
- N. A. K. Aramouni, J. G. Touma, B. A. Tarboush, J. Zeaiter, and M. N. Ahmad, Catalyst design for dry reforming of methane: Analysis review, Renew. Sustain. Energy Rev., 82, 2570- 2585 (2018). https://doi.org/10.1016/j.rser.2017.09.076
- Z. Zhan, and S. A. Barnett, An octane-fueled solid oxide fuel cell, Science, 308, 844-847 (2005). https://doi.org/10.1126/science.1109213
- W. Wang, R. Ran, and Z. Shao, Combustion-synthesized Ru-Al2O3 composites as anode catalyst layer of a solid oxide fuel cell operating on methane, Int. J. Hydrog. Energy, 36, 755-764 (2011). https://doi.org/10.1016/j.ijhydene.2010.09.048
- W. Wang, W. Zhou, R. Ran, R. Cai, and Z. Shao, Methane-fueled SOFC with traditional nickel-based anode by applying Ni/Al2O3 as a dual-functional layer, Electrochem. Commun., 11, 194-197 (2009). https://doi.org/10.1016/j.elecom.2008.11.014
- Z. Lyu, Y. Wang, Y. Zhang, and M. Han, Solid oxide fuel cells fueled by simulated biogas: Comparison of anode modification by infiltration and reforming catalytic layer, Chem. Eng. J., 393, 124755 (2020).
- S. D. Angeli, G. Monteleone, A. Giaconia, and A. A. Lemonidou, State-of-the-art catalysts for CH4 steam reforming at low temperature, Int. J. Hydrog. Energy, 39, 1979-1997 (2014). https://doi.org/10.1016/j.ijhydene.2013.12.001
- C. Jin, C. Yang, F. Zhao, A. Coffin, and F. Chen, Direct-methane solid oxide fuel cells with Cu1.3Mn1.7O4 spinel internal reforming layer, Electrochem. Commun., 12, 1450-1452 (2010). https://doi.org/10.1016/j.elecom.2010.08.006
- X.-F. Ye, S. Wang, Z. Wang, L. Xiong, X. Sun, and T. Wen, Use of a catalyst layer for anode-supported SOFCs running on ethanol fuel, J. Power Sources, 177, 419-425 (2008). https://doi.org/10.1016/j.jpowsour.2007.11.054
- P. Frontera, A. Macario, A. Aloise, P. Antonucci, G. Giordano, and J. Nagy, Effect of support surface on methane dry-reforming catalyst preparation, Catal. Today, 218, 18-29 (2013). https://doi.org/10.1016/j.cattod.2013.04.029
- T. Wei, L. Jia, H. Zheng, B. Chi, J. Pu, and J. Li, LaMnO3-based perovskite with in-situ exsolved Ni nanoparticles: a highly active, performance stable and coking resistant catalyst for CO2 dry reforming of CH4, Appl. Catal. A: Gen., 564, 199-207 (2018). https://doi.org/10.1016/j.apcata.2018.07.031
- Z. Tao, M. Fu, and Y. Liu, A mini-review of carbon-resistant anode materials for solid oxide fuel cells, Sustain. Energy Fuels, 5, 5420-5430 (2021). https://doi.org/10.1039/D1SE01300A
- P. Li, B. Yu, J. Li, X. Yao, Y. Zhao, and Y. Li, Improved activity and stability of Ni-Ce0.8Sm0.2O1.9 anode for solid oxide fuel cells fed with methanol through addition of molybdenum, J. Power Sources, 320, 251-256 (2016). https://doi.org/10.1016/j.jpowsour.2016.04.100
- B. Hua, M. Li, J.-l. Luo, J. Pu, B. Chi, and J. Li, Carbon-resistant Ni-Zr0.92Y0.08O2-δ supported solid oxide fuel cells using Ni-Cu-Fe alloy cermet as on-cell reforming catalyst and mixed methanesteam as fuel, J. Power Sources, 303, 340-346 (2016). https://doi.org/10.1016/j.jpowsour.2015.11.029
- Z. Wang, Z. Wang, W. Yang, R. Peng, and Y. Lu, Carbon-tolerant solid oxide fuel cells using NiTiO3 as an anode internal reforming layer, J. Power Sources, 255, 404-409 (2014). https://doi.org/10.1016/j.jpowsour.2014.01.014
- Y.-F. Sun, J.-H. Li, S.-H. Cui, K.T. Chuang, and J.-L. Luo, Carbon deposition and sulfur tolerant La0.4Sr0.5Ba0.1TiO3-La0.4Ce0.6O1.8 anode catalysts for solid oxide fuel cells, Electrochim. Acta, 151, 81-88 (2015). https://doi.org/10.1016/j.electacta.2014.11.076