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Synthesis and Dyeing Properties of Sulfadiazine-based Antimicrobial Azo Disperse Dyes on Polyester

설파디아진계 항균성 아조 분산염료의 합성 및 폴리에스터에 대한 염색성 연구

  • Minse Kim (Department of Organic and Nano System Engineering, Konkuk University) ;
  • Yonggyun Cho (Department of Organic and Nano System Engineering, Konkuk University) ;
  • Sarang Oh (Department of Organic and Nano System Engineering, Konkuk University) ;
  • Keechul Youm (Department of Organic and Nano System Engineering, Konkuk University) ;
  • Sangcheon Kim (Department of Organic and Nano System Engineering, Konkuk University) ;
  • Ju Yeon Lee (Department of Biological Engineering, Konkuk University) ;
  • Hyung Joo Kim (Department of Biological Engineering, Konkuk University) ;
  • Joonseok Koh (Department of Organic and Nano System Engineering, Konkuk University)
  • 김민세 (건국대학교 유기나노시스템공학과) ;
  • 조용균 (건국대학교 유기나노시스템공학과) ;
  • 오사랑 (건국대학교 유기나노시스템공학과) ;
  • 염기철 (건국대학교 유기나노시스템공학과) ;
  • 김상천 (건국대학교 유기나노시스템공학과) ;
  • 이주연 (건국대학교 생물공학과) ;
  • 김형주 (건국대학교 생물공학과) ;
  • 고준석 (건국대학교 유기나노시스템공학과)
  • Received : 2023.02.03
  • Accepted : 2023.02.24
  • Published : 2023.02.28

Abstract

Sulfadiazine, an antibacterial agent, was used in combination with the different coupling components to synthesize three sulfadiazine-based azo disperse dyes with antibacterial properties. The chemical structures of the synthesized dye were verified using FT-IR spectroscopy and 1H-NMR analysis, and the spectral properties of the dyes were analyzed using a UV-Visible spectrophotometer. Among the synthesized azo dispersion dyes, the more hydrophobic dye exhibited superior build-up properties on PET fabrics. The colorfastness of PET fabrics dyed with the synthesized dyes showed excellent color fastness to washing, perspiration, and rubbing. An analysis of the antibacterial properties of S. aureus and K. pneumoniae revealed that there was no significant antibacterial activity compared to that of undyed PET. However, a dyeing with a higher concentration of a particular dye produced an increase in antimicrobial properties.

Keywords

Acknowledgement

이 논문은 2020년도 정부(산업통상자원부)의 재원으로 한국산업기술진흥원의 지원을 받아 수행된 연구임(P0012770, 2020년 산업혁신인재성장지원사업). 이 논문은 정부(과학기술정보통신부)의 재원으로 한국연구재단의 지원을 받아 수행된 연구임(No. 2021R1A2C1013362).

References

  1. S. Y. Lee, "Trands in Antimicrobial and Deodorizing Finish for Textile Products", Text. Color. Finish., 1997, 9, 57-76. 
  2. O. Yuge, "Antibacterial Finishing of Textiles", Sen'i Gakkaishi, 1984, 40, 612-617.  https://doi.org/10.2115/fiber.40.10_P612
  3. H. C. Cha, J. H. Ko, and Y. H. Kim, "Synthesis of Sulfadiazine Type Antibacterial Reactive Dyes", Text. Sci. Eng., 2007, 44, 204-210. 
  4. H. C. Cha and Y. H. Kim, "Dyeing Properties and Antibacterial Activities of Sulfadiazine Type Reactive Dyes", Text. Sci. Eng., 2008, 45, 214-219. 
  5. J. Hong, S. Yoon, M. Kim, and S. Son, "Synthesis of Blue Acid Dyes Having Antimicrobial Property and Its Application on Nylon Fiber", J. Korean Soc. Dyers Finishers, 2008, 20, 22-27.  https://doi.org/10.5764/TCF.2008.20.1.022
  6. A. Ovung and J. Bhattacharyya, "Sulfonamide Drugs: Structure, Antibacterial Property, Toxicity, and Biophysical Interactions", Biophys Rev., 2021, 13, 259-272.  https://doi.org/10.1007/s12551-021-00795-9
  7. G. Domagk, "Ein Beitrag zur chemotherapie der bakteriellen infekctionen", Deutsche Med. Wchnschr., 1935, 61, 250. 
  8. Y. G. Song, "The History of Antimicrobial Drug Development and the Current Situation", Infect Chemother., 2012, 44, 263-268.  https://doi.org/10.3947/ic.2012.44.4.263
  9. W. Baumannm, B. T. Groebel, M. Krayer, H. P. Oesch, R. Brossman, N. Kleinmeier, and A. T. Leaver, "Determination of Relative Colour Strength and Residual Colour Difference by Means of Reflectance Measurements", J. Soc. Dyers Colour., 1987, 103, 100-105.  https://doi.org/10.1111/j.1478-4408.1987.tb01101.x
  10. F. Ahmed, R. Dewani, and M. K. Pervez, "Non-destructive FT-IR Analysis of Mono Azo Dyes", Bulgarian Chemical Communications, 2016, 48, 71-77. 
  11. S. Radha and K. K. Mothilal, "Synthesis Characterization and Biological Studies of Sulfadiazine Drug Based Transition Metal Complexes", J. Chem. Pharm. Res., 2016, 8, 202-211.