DOI QR코드

DOI QR Code

Effect of Temperature and pH on the Floatability of PVA and POM Microplastics

PVA와 POM 미세플라스틱 Floatability에 미치는 온도와 pH의 영향

  • Seong Chan Kim (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Mintae Kim (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Hyungjin Cho (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Eunseo Lee (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Young Min Kwon (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Byung Hyo Kim (Department of Organic Materials and Fiber Engineering, Soongsil University)
  • 김성찬 (숭실대학교 유기신소재.파이버공학과) ;
  • 김민태 (숭실대학교 유기신소재.파이버공학과) ;
  • 조형진 (숭실대학교 유기신소재.파이버공학과) ;
  • 이은서 (숭실대학교 유기신소재.파이버공학과) ;
  • 권영민 (숭실대학교 유기신소재.파이버공학과) ;
  • 김병효 (숭실대학교 유기신소재.파이버공학과)
  • Received : 2023.01.04
  • Accepted : 2023.02.12
  • Published : 2023.02.28

Abstract

Removal of microplastics is one of the most important task in the modern society because the microplastics not only adversely affect the natural environment and ecosystem, but also have internal inflammatory and carcinogenic effects on the human body. Therefore, there is an urgent need to develop a method for recovering microplastics dissolved in aquatic ecosystems. Herein, polyvinyl alcohol (PVA) and polyoxomethylene (POM) microplastics dissolved in Tancheon, Seongnam were recovered by density screening using NaCl, an eco-friendly method. The density of the experimental aqueous NaCl solution was adjusted to 1.2 g/cm3. Pulverized PVA and POM was used for experiments, and the floatability was measured by comparing the initial input amount and the recovered amount. The floatability of microplastics was compared by changing the temperature and pH. The experimental results showed that the floatability of PVA increased as the temperature increased or the solvent was acidic or basic. On the other hand, the floatability of POM is high at low temperature or neutral pH condition.

Keywords

Acknowledgement

이 논문은 대한민국 정부(과학기술정보통신부)의 재원으로 한국연구재단의 지원을 받아 수행되었음(NRF-2021R1C1C1014339).

References

  1. Y. Choi, H. J. Choi, and S. W. Rhee, "Current Status and Improvements on Management of Plastic Waste in Korea", J. Kor. Inst. Resources Recycling, 2018, 27, 3-15. 
  2. S.-M. Kim, S.-H. Baek, Y. Han, T. Davaadorj, B.-H. Go, and H.-S. Jeon, "Current Research Trends for Treatment of Miocroplastics", J. Kor. Inst. Resources Recycling, 2020, 29, 15-27.  https://doi.org/10.7844/kirr.2020.29.5.15
  3. M. S. Kang and H. J. Kim, "Microplastics in Foods: the Hazardous Characteristics and Risk on Human Health", Food Sci. Ind., 2021, 54, 2-10.  https://doi.org/10.23093/FSI.2021.54.1.002
  4. R. Geyer, J. R. Jambeck, and K. L. Law, "Production, Use, and Fate of All Plastics Ever Made", Sci. Adv., 2017, 3, doi: 10.1126/sciadv.1700782. 
  5. R. C. Thompson, Y. Olsen, R. P. Mitchell, A. Davis, S. J. Rowland, A. W. G. John, D. McGonigle, and A. E. Russell, "Lost at Sea: Where is all the Plastic?", Science, 2014, 304, 838-839.  https://doi.org/10.1126/science.1094559
  6. X. Lim, "Microplastics are Everywhere - But are They Harmful?", Nature, 2021, 593, 22-25.  https://doi.org/10.1038/d41586-021-01143-3
  7. A. D. Vethaak and J. Legler, "Microplastics and Human Health", Science, 2021, 371, 671-674.  https://doi.org/10.1126/science.abe5041
  8. K. Blackburn and D. Green, "The Potential Effects of Microplastics on Human Health: What is Known and What is Unknown", Ambio, 2022, 51, 518-530.  https://doi.org/10.1007/s13280-021-01589-9
  9. M.-K. Kim and K.-D. Zoh, "A Review on Occurrence and Environmental Risk Assessment for Microplastics in Freshwater Systems", Kor. J. Public Health, 2019, 56, 10-24.  https://doi.org/10.17262/KJPH.2019.06.56.1.10
  10. H. Wang, Y. Zhang, and C. Wang, "Surface Modification and Selective Flotation of Waste Plastics for Effective Recycling - a Review", Sep. Purif. Technol., 2019, 226, 75-94.  https://doi.org/10.1016/j.seppur.2019.05.052
  11. Y. Cho and Y. B. G. Cho, "Status and Future Prospects for Plastics Recycling", J. Kor. Inst. Resources Recycling, 2020, 29, 31-44.  https://doi.org/10.7844/KIRR.2020.29.4.31
  12. Z. Akdogan and B. Guven, "Micro-plastics in the Environment: A Critical Review of Current Understanding and Identification of Future Research Needs", Environ. Pollution, 2019, 254, 1-24.  https://doi.org/10.1016/j.envpol.2019.113011
  13. H.-W. Yu, Y. S. Kim, S. Lee, J. Yoo, and J. Choi, "A Review on Analytical Methods and Occurrences for Microplastics in Freshwater", J. Environ. Anal. Health Toxicol., 2020, 23, 183-193.  https://doi.org/10.1080/10937404.2020.1755402
  14. X. Lv, Q. Dong, Z. Zuo, Y. Liu, X. Huang, and W.-M. Wu, "Microplastics in a Municipal Wastewater Treatment Plant: Fate, Dynamic Distribution, Removal Efficiencies, and Control Strategies", J. Cleaner Prod., 2019, 225, 579-586.  https://doi.org/10.1016/j.jclepro.2019.03.321
  15. X. Zhang, J. Chen, and J. Li, "The Removal of Microplastics in the Wastewater Treatment Process and Their Potential Impact on Anaerobic Digestion due to Pollutants Association", Chemosphere, 2020, 251, 126360. 
  16. L. M. Hernandez, N. Yousefi, and N. Tufenkji, "Are There Nanoplastics in your Personal Care Products?", Environ. Sci. Technol. Lett., 2017, 4, 280-285.  https://doi.org/10.1021/acs.estlett.7b00187
  17. H. Hidayaturrahman and T.-G. Lee, "A Study on Characteristics of Microplastic in Wastewater of South Korea: Identification, Quantification, and Fate of Microplastics during Treatment Process", Marine Pollution Bull., 2019, 146, 696-702.  https://doi.org/10.1016/j.marpolbul.2019.06.071
  18. B. Ma, W. Xue, Y. Ding, C. Hu, H. Liu, and J. Qu, "Removal Characteristics of Microplastics by Fe-based Coagulants during Drinking Water Treatment", J. Environ. Sci., 2019, 78, 267-275.  https://doi.org/10.1016/j.jes.2018.10.006
  19. M. Kedzierski, V. L. Tilly, P. Bourseau, H. Bellegou, G. Cesar, O. Sire, and S. Bruzzaud, "Microplastics Elutriation from Sandy Sediments: A Granulometric Approach", Marine Pollution Bull., 2016, 107, 315-325.  https://doi.org/10.1016/j.marpolbul.2016.03.041
  20. M. S. Negari, S. O. Movahed, and A. Ahmadpour, "Separation of Polyvinylchloride (PVC), Polystyrene (PS) and Polyethylene Terephthalate (PET) Granules Using Various Chemical Agents by Flotation Technique", Sep. Purif. Technol., 2018, 194, 368-376.  https://doi.org/10.1016/j.seppur.2017.11.062
  21. B. Quinn, F. Murphy, and C. Ewins, "Validation of Density Separation for the Rapid Recovery of Microplastics from Sediment", Anal. Methods, 2017, 9, 1491-1498.  https://doi.org/10.1039/C6AY02542K
  22. W. Sun, L. Chen, and J. Wan, "Degradation of PVA (polyvinyl alcohol) in Wastewater by Advanced Oxidation Processes", J. Adv. Oxidation Technol., 2017, 20, 20170018. 
  23. C. Zeri, A. Adamopoulou, A. Koi, N. Koutsikos, E. Lytras, and E. Dimitriou, "Rivers and Wastewater-Treatment Plants as Microplastic Pathways to Eastern Mediterranean Waters: First Records for the Aegean Sea, Greece", Sustainability, 2021, 13, 5328. 
  24. H.-S. Lee and Y.-J. Kim, "Consideration on Quantitative and Qualitative Analysis for Microplastic in Various Madia", J. Kor. Soc. Water Management, 2017, 34, 537-545.  https://doi.org/10.9786/kswm.2017.34.6.537
  25. W. M. Hosnyu and P. A. Khalaf-Alaa, "Potentiometric Study and Biological Activity of Some Metal Ion", Int. J. Electrochem. Sci., 2013, 8, 1520-1533. https://doi.org/10.1016/S1452-3981(23)14116-2