Journal of the Korean institute of surface engineering (한국표면공학회지)

The Korean Institute of Surface Engineering (한국표면공학회)
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Copper phthalocyanine conjugated PANI coated screen printed carbon electrode for electrochemical sensing of 4-NP

  • Ramalingam Manikandan (Department of Cogno-Mechatronics Engineering, College of Nanoscience and Nanotechnology, Pusan National University) ;
  • Jang-Hee Yoon (Busan center, Korea Basic Science Institute) ;
  • Seung-Cheol Chang (Department of Cogno-Mechatronics Engineering, College of Nanoscience and Nanotechnology, Pusan National University)
  • Received : 2023.01.10
  • Accepted : 2023.01.26
  • Published : 2023.02.28
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Abstract

In this work, we synthesized a novel electrochemical sensing materials based on tetracarboxylic copper phthalocyanine (TcCuPtc) conjugated PANI (TcCuPtc@PANI). The synthesized materials were employed to modify the screen-printed carbon electrode (SPCE) for the selective sensing of 4-nitrophenol. The TcCuPtc was conjugated with conducting polymer of PANI through the electrostatic interaction and π-π electron conjugation, the polymer film of PANI to inhibit the leakage of TcCuPtc from the surface of the electrode. The prepared TcCuPtc@PANI were characterized and confirmed by scanning electron microscopy (SEM) with EDX, ATR-IR, UV-vis absorption spectroscopy, cyclic voltammetry, and differential pulse voltammetry techniques. The prepared TcCuPtc@PANI/SPCE showed an excellent electrocatalytic sensing of 4-NP in the linear concentrations from 3 to 500 nM with a LOD of 0.03 nM and a sensitivity of 8.8294 ㎂/nM cm-2. However, the prepared TcCuPtc@PANI/SPCE showed selective sensing of 4-NP in the presence of other interfering species. The practical applicability of the TcCuPtc@PANI/SPCE was employed for the sensing of 4-NP in different water samples by standard addition method and showed satisfactory recovery results.

Keywords

Acknowledgement

This work was supported by a 2-Year Research Grant of Pusan National University.

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