DOI QR코드

DOI QR Code

Effect of underlayer electroless Ni-P plating on deposition behavior of cyanide-free electroless Au plating

비시안 무전해 Au 도금의 석출거동에 미치는 하지층 무전해 Ni-P 도금 조건의 영향

  • Received : 2022.04.27
  • Accepted : 2022.09.21
  • Published : 2022.10.31

Abstract

Gold plating is used as a coating of connector in printed circuit boards, ceramic integrated circuit packages, semiconductor devices and so on, because the film has excellent electric conductivity, solderability and chemical properties such as durability to acid and other chemicals. In most cases, internal connection between device and package and external terminals for connecting packaging and printed circuit board are electroless Ni-P plating followed by immersion Au plating (ENIG) to ensure connection reliability. The deposition behavior and film properties of electroless Au plating are affected by P content, grain size and mixed impurity components in the electroless Ni-P alloy film used as the underlayer plating. In this study, the correlation between electroless nickel plating used as a underlayer layer and cyanide-free electroless Au plating using thiomalic acid as a complexing agent and aminoethanethiol as a reducing agent was investigated.

Keywords

References

  1. W. J. Daukler, D. J. Resnick, W. A. Johnson, A. W. Yanof, A new operating regime for electroplating the gold absorber on x-ray masks, Microelectron. Eng., 23 (1994) 235-238. https://doi.org/10.1016/0167-9317(94)90145-7
  2. W. Chu, M. L. Schattenburg, H. I. Smith, Low-stress gold electroplating for X-ray masks, Microelectron. Eng., 17 (1992) 223-226. https://doi.org/10.1016/0167-9317(92)90046-T
  3. T. Osaka, Y. Okinakab, J. Sasano, M. Katod, Development of new electrolytic and electroless gold plating processes for electronics applications, Sci. Technol. Adv. Mater., 7 (2006) 425-437. https://doi.org/10.1016/j.stam.2006.05.003
  4. Y. Yoneda, K. Nakamura, Packaging technology for imaging LSI, Fujitsu, 63 (2012) 489-495.
  5. Y. Ejiri, T. Sakurai, Y. Arayama, K. Suzuki, Y. Tsbomatsu, S. Hatakeyama, S. Arike, Y. Hiroyama, K. Hasegawa, Electroless Ni/Pd/Au plating for semiconductor package substrates (I) - influence of the electroless Ni plating thickness on the solder ball joint reliability, J. Japan Inst. Electron. Packag., 15 (2012) 82-95. https://doi.org/10.5104/jiep.15.82
  6. I. Kato, H. Terashima, H. Watanabe and H. Honma, Influence of electroless Ni-P film condition on wire bondability, J. Surf. Finish. Soc. Jpn., 62(1) (2011) 47-53. https://doi.org/10.4139/sfj.62.47
  7. J. Ushio, O. Miyazawa, H. Yokono, A. Tomizawa, Electronic device plated with gold by means of an electroless gold plating solution, European Patent Application EP 021789, April 29 (1987)
  8. I. Takashi, Development of a non-cyanide electroless gold plating bath, Surf. Finish. Soc. Jpn., 52 (2001) 410. https://doi.org/10.4139/sfj.52.410
  9. Y. Shindo, H. Honma, Study of non-cyanide electroless gold plating, Proceeding of the 84th Surface Finishing Society of Japan, (1991) 163.
  10. Y. Sato, T. Osawa, K. Kaieda, K. Kobayakawa, Cyanide-free electroless gold plating from a bath containing disulfitoaurate and thiourea or its derivatives, Plat. Surf. Finish., 81 (1994) 74.
  11. A. Sullivan, P. A. Kohl, The autocatalytic deposition of gold in nonalkaline, gold thiosulfate electroless bath, J. Electrochem. Soc., 142 (1995) 2250. https://doi.org/10.1149/1.2044282
  12. S. Dimitrijevic, M. R. Vujasinovic, V. Trujic, Non-cyanide electrolytes for gold plating - A review, J. Electrochem. Sci., 8 (2013) 6620 - 6646.
  13. J. Han, D. Kim, Deposition behavior of cyanide-free electroless Au plating solution using thiomalic acid as complexing agent and aminoethanethiol as reducing agent and characteristics of plated Au film, J. Surf. Sci. Eng. 55(2), (2022) 102-119.
  14. J. Han, D. Kim, Analysis of cyanide free electroless Au plating solution by capillary elecrophoresis, J. Surf. Sci. Eng. 55 (2022) 120-132.
  15. J. Han, J. Lee, N. V. Phuong, D. Kim, A Newly Developed Non-Cyanide Electroless Gold Plating Method Using Thiomalic Acid as a Complexing Agent and 2-Aminoethanethiol as a Reducing Agent, Corros. Sci. Tech., 21 (2022) 89-99.
  16. D. Kim, Comparison of Deposition Behavior and Properties of Cyanide-free Electroless Au Plating on Various Underlayer Electroless Ni-P films, J. Surf. Sci. Eng. 55 (2022) 202-214.
  17. K. Nishiyama, H. Watanabe, The type and application of electroless gold plating, J. Surf. Finish. Soc. Jpn., 48 (1997) 393. https://doi.org/10.4139/sfj.48.393
  18. T. Yamamoto, H. Watanabe, K. Izawa, H. Honma, Effect of electroless nickel/displacement gold plating process on strength of solder Joint, J. Jpn. Inst. Electron. Packag., 6 (2003) 339-344. https://doi.org/10.5104/jiep.6.339
  19. A. Chinda, N. Miyamoto, O. Yoshioka, Gold plating thickness and soldering reliability of solder balls for electroless gold plated TAB tape carrier, J. Jpn. Inst. Electron. Packag., 3 (2000) 308-314. https://doi.org/10.5104/jiep.3.308
  20. F. Taniguchi, F. Ando, A. Takashima, Thermal fatigue and mechanical reliability of FBGA solder joints, J. Jpn. Inst. Electron. Packag., 4 (2001) 56-62. https://doi.org/10.5104/jiep.4.56
  21. H. Ohata, Y. Momokawa, E. Kouno, M. Tsunemasu, Y. Tanaka, The destruction mode and the life cycle times of the chip size package mounted on the circuit board by the bending test, J. Jpn. Inst. Electron. Packag., 4 (2001) 519-522. https://doi.org/10.5104/jiep.4.519
  22. H. Matsuki, H. Ibuka, H. Saka, A TEM observation of solder joints of an electronic device, J. Jpn, Inst. Metals, 64 (2000) 213-217. https://doi.org/10.2320/jinstmet1952.64.3_213
  23. Y. Kariya, K. Nakamura, M. Ohtsuka, H. Tanaka, 6th Symposium on Microjoining and Assembly Technology in Electronics,(2000) 415.
  24. T. Sugizaki, K. Tajima, T. Sasaki, H. Nakao, Y. Fukuda, T. Kimura, Effect of electroless nickel/immersion gold finishing on BGA solder joints, J. Japan Inst. Electron. Packag., 4 (2001) 124-127. https://doi.org/10.5104/jiep.4.124
  25. Electroplating Research Society, Eds., Environmental Coordinated Plating Technology, Daily Industrial Newspaper, (2006) 62.
  26. H. K. Lee, S. H. Son, H. Y. Lee, J. M. Jeon, A study on the ENIG surface finish process and its properties, J. Kor. Inst. Surf. Eng., 40 (2007) 32-38. https://doi.org/10.5695/JKISE.2007.40.1.032
  27. T. Laurila, V. Vuorinen, Combined thermodynamic-kinetic analysis of the interfacial reactions between Ni metallization and various lead-free solders, Materials 2 (2009) 1796-1834. https://doi.org/10.3390/ma2041796
  28. E. Bradley, K. Banerji, Effect of PCB finish on the reliability and wettability of ballgrid array packages. In Proc. 45th Electronic Components and Technology Conference, Las Vegas, NV, USA, May 21-24 (1995) 1028-1038.