DOI QR코드

DOI QR Code

Characterization of jute fibre reinforced pine rosin modified soy protein isolate green composites

  • Sakhare, Karishma M. (Textile Manufactures Department, Veermata Jijabai Technological Institute) ;
  • Borkar, Shashikant P. (Textile Manufactures Department, Veermata Jijabai Technological Institute)
  • 투고 : 2021.08.14
  • 심사 : 2022.01.21
  • 발행 : 2022.09.25

초록

Very slow degradation of synthetic based polymers has created a severe environmental issue that increased awareness towards research in polymers of biodegradable property. Soy protein isolate (SPI) is a natural biopolymer used as matrix in green composites but it has limitations of low mechanical properties and high water sensitivity. To enhance mechanical properties and reduce water sensitivity of Jute-SPI composites, SPI was modified with pine rosin which is also a natural cross-linking agent. 30% glycerol on the weight basis of a matrix was used as a plasticizer. The fibre volume fraction was kept constant at 0.2 whereas the pine rosin in SPI ranged from 5% to 30% of the matrix. The effects of pine rosin on mechanical, thermal, water sensitivity and surface morphology have been characterized using various techniques. The mechanical properties and water absorbency were found to be optimum for 15% pine rosin in Jute-SPI composite. Therefore, Jute-SPI composite without pine rosin and with 15% pine rosin were chosen for investigation through characterization by Fourier transforms infrared spectroscopy (FTIR), Thermo-gravimetric analysis (TGA), X-Ray diffraction (XRD) and Scanning electron microscope (SEM). The surface morphology of the composite was influenced by pine rosin which is shown in the SEM image. TGA measurement showed that the thermal properties improved due to the addition of pine rosin. Antimicrobial test showed antimicrobial property in the composite occurring 15% pine rosin. The research paper concludes that the modification of SPI resin with an optimum percentage of pine rosin enhanced mechanical, thermal as well as water-resistant properties of jute fibre reinforced composites.

키워드

과제정보

The authors would like to acknowledge the Institute of Chemical Technology, Matunga, Mumbai to avail their lab facilities and support.

참고문헌

  1. Aldas, M., Pavon, C., Lopez-Martinez, J. and Arrieta, M.P. (2020), "Pine Resin Derivatives as Sustainable Additives to Improve the Mechanical and Thermal Properties of Injected Moulded Thermoplastic Starch", Appl. Sci., 10(7), 2561. https://doi.org/10.3390/app10072561
  2. Avancha, S., Behera, A.K., Sen, R. and Adhikari, B. (2013), "Physical and mechanical characterization of jute reinforced soy composites", J. Reinf. Plast. Compos., 32, 1380-1390. https://doi.org/10.1177/0731684413485979
  3. Behera, A.K., Avancha, S., Basak, R.K., Sen, R. and Adhikari, B. (2012), "Fabrication and characterizations of biodegradable jute reinforced soy based green composites", Carbohydr. Polym., 88(1), 329-335. https://doi.org/10.1016/j.carbpol.2011.12.023
  4. Boopalan, M., Umapathy, M.J. and Jenyfer, P. (2012), "A Comparative Study on the Mechanical Properties of Jute and Sisal Fiber Reinforced Polymer Composites", Silicon, 4(3), 145-149. https://doi.org/10.1007/s12633-012-9110-6
  5. Chabba, S. and Netravali, A.N. (2005), "Green composites Part 1: Characterization of flax fabric and glutaraldehyde modified soy protein concentrate composites", J. Mater. Sci., 40, 6263-6273. https://doi.org/10.1007/s10853-005-3142-x
  6. Chabba, S. and Netravali, A.N. (2005), "Green" composites Part 2: Characterization of flax yarn and glutaraldehyde/poly (vinyl alcohol) modified soy protein concentrate composites", J. Mater. Sci., 40(23), 6275-6282. https://doi.org/10.1007/s10853-005-3143-9
  7. Chabba, S., Matthews, G.F. and Netravali, A.N. (2005), "Green" composites using cross-linked soy flour and flax yarns", Green Chem., 7(8), 576-581. https://doi.org/10.1039/b410817e
  8. Deepmala, K.M., Singh, V.K., Chauhan, S. and Jain, N. (2017), "Soy Protein Based Green Composite", A Review. Research & Reviews: J. Mater. Sci., 5, 66-77. https://doi.org/10.4172/2321-6212.1000171
  9. Elbadry, E.A., Aly-Hassan, M.S. and Hamada H. (2012), "Mechanical Properties of Natural Jute Fabric/Jute Mat Fiber Reinforced Polymer Matrix Hybrid Composites", Hindawi Publish. Corp. Adv. Mech. Eng., 1- 12. https://doi.org/10.1155/2012/354547
  10. Gennusa, M.L., Massana, P.L., Montero, J.I., Pena, F.J., Rieradevall, J., Ferrante, P., Scaccianoce G. and Sorrentino, G. (2017), "Composite building materials: Thermal and mechanical performances of samples realized with hay and natural resins", Sustain., 9(3), 373. https://doi.org/10.3390/su9030373
  11. Gholampour, A. and Ozbakkaloglu, T. (2020), "A review of natural fiber composites: properties, modifification and processing techniques, characterization, applications", J. Mater. Sci., 55, 829-892. https://doi.org/10.1007/s10853-019-03990-y
  12. Koshy, R.R., Mary, S.K., Thomas, S. and Pothan, L.A. (2015), "Environment friendly green composites based on soy protein isolate - A review", Food Hydrocolloids, 50, 174-192. https://doi.org/10.1016/j.foodhyd.2015.04.023
  13. Kugler, S., Ossowicz, P., Malarczyk-Matusiak, K. and Wierzbicka, E. (2019), "Advances in Rosin-Based Chemicals: the Latest Recipes, Applications and Future Trends", Molecules, 24(9), 1651. https://doi.org/10.3390/molecules24091651
  14. Lodha, P. and Netravali A.N. (2005), "Thermal and mechanical properties of environment-friendly "green" plastics from stearic acid modified-soy protein isolate", Industrial Crops and Products, 21, 49-64. https://doi.org/10.1016/j.indcrop.2003.12.006
  15. Manickavasagam, V., Vijaya Ramnath, B. and Elanchezhia, C. (2015), "A Review on Natural and Bamboo Fiber Composites", Int. J. Adv. Res. Sci. Eng. Technol., 2(11), 1076-1080.
  16. Mohanty, A.K., Tummala, P., Liu, W., Misra, M., Mulukutla, P.V. and Drzal, L.T. (2005), "Injection Molded Biocomposites from Soy Protein Based Bioplastic and Short Industrial Hemp Fiber", J. Polym. Environ., 13(3), 279-285. https://doi.org/10.1007/s10924-005-4762-6
  17. O'Flynn, T.D., Hogan, S.A., Daly, D.F.M., O'Mahony, J.A. and McCarthy, N.A. (2021), "Rheological and Solubility Properties of Soy Protein Isolate", Molecules, 26(10), 1-15. https://doi.org/10.3390/molecules26103015
  18. Patil, N.V., Rahman, M.M. and Netravali, A.N. (2017), "Green composites using bioresins from agro-wastes and modified sisal fibers", Polym. Compos., 40, 99-108. https://doi.org/10.1002/pc.24607
  19. Preece, K.E., Hooshyar, N. and Zuidam, N.J. (2017), "Whole soybean protein extraction processes: A review", Innov. Food Sci. Emerg. Technol., 43, 163-172. https://doi.org/10.1016/j.ifset.2017.07.024
  20. Reddy, N. and Yang, Y. (2011), "Completely biodegradable soy protein-jute biocomposites developed using water without any chemicals as plasticizer", Industrial Crops and Products, 33(1), 35-41. https://doi.org/10.1016/j.indcrop.2010.08.007
  21. Singh, H., Inder Preet Singh, J., Singh, S., Dhawan, V. and Tiwari, S.K. (2018), "A Brief Review of Jute Fibre and Its Composites", Mater. Today Proceedings, 5(14), 28427-28437. https://doi.org/10.1016/j.matpr.2018.10.129
  22. Sousa, D., Biscaia, S., Viana, T., Gaspar, M., Mahendra, V., Mohan, S., Mateus, A. and Mitchell, G.R. (2019), "Rosin Based Composites for Additive Manufacturing", Appl. Mech. Mater., 890, 70-76. https://doi.org/10.4028/www.scientific.net/amm.890.70
  23. Won, J.S., Lee, J.E., Jin, D.Y. and Lee, S.G. (2015), "Mechanical Properties and Biodegradability of the Kenaf/Soy Protein Isolate-PVA Biocomposites", Int. J. Polym. Sci., 1-11. http://dx.doi.org/10.1155/2015/860617
  24. Joseph, P.V., Mathew, G., Joseph, K., Groeninckx, G. and Thomas, S. (2003), "Dynamic mechanical properties of short sisal fibre reinforced polypropylene composites", Compos. Part A. Appl. Sci. Manuf., 34(3), 275-290. https://doi.org/10.1016/s1359-835x(02)00020-9
  25. Kanerva, M., Puolakka, A., Takala, T.M., Elert, A.M., Myllari, V., Jonkkari, I., Sarlin, E., Seitsonen J., Ruokolainen J., Saris, P. and Vuorinen, J. (2019), "Antibacterial polymer fibres by rosin compounding and meltspinning", Mater. Today Commun., 20, 1-9. https://doi.org/10.1016/j.mtcomm.2019.05.003
  26. Karmarkar, A., Chauhan, S.S., Modak, J.M. and Chanda, M. (2007), "Mechanical properties of wood-fiber reinforced polypropylene composites: Effect of a novel compatibilizer with isocyanate functional group", Compos. Part A. Appl. Sci. Manuf., 38(2), 227-233. https://doi.org/10.1016/j.compositesa.2006.05.005
  27. Kormin, S., Kormin, F. and Beg, M.D.H. (2019), "Effect of plasticizer on physical and mechanical properties of ldpe/sago starch blend", International Conference on Mechanical and Manufacturing Engineering, Johor Bahru, Malaysia, August.
  28. Krinski, T.L. (1992), Emerging Technologies for Materials and Chemicals from Biomass, American Chemical Society, Washington, USA.
  29. Lam, E.U., Pliego, M.G.G., Perez, V.G.M. and Ramirez, A.M. (2012), "Determination of Mechanical Properties of Biodegradable Composites Made by Pine Resin Corn Fibers and Henequen Fibers", Key Eng. Mater., 517, 422-429. https://doi.org/10.4028/www.scientific.net/KEM.517.422
  30. Llevot, A., Grau, E., Carlotti, S., Grelier, S. and Cramail, H. (2015), "Dimerization of abietic acid for the design of renewable polymers by ADMET", Eur. Polym. J., 67, 409-417. http://dx.doi.org/10.1016/j.eurpolymj.2014.10.021
  31. Niu, X., Liu, Y., Song, Y., Han, J. and Pan, H. (2018), "Rosin modified cellulose nanofiber as a reinforcing and co-antimicrobial agents in polylactic acid /chitosan composite film for food packaging", Carbohydr. Polym., 183, 102-109. https://doi.org/10.1016/j.carbpol.2017.11.079
  32. Rahman, M.R., Huque, M.M., Islam, M.N. and Hasan, M. (2008), "Improvement of physico-mechanical properties of jute fiber reinforced polypropylene composites by post-treatment", Composites Part A. Applied Science and Manufacturing, 39(11), 1739-1747. https://doi.org/10.1016/j.compositesa.2008.08.002
  33. Rana, A.K., Basak, R.K., Mitra, B.C., Lawther, M. and Banerjee, A.N. (1997), "Studies of acetylation of jute using simplified procedure and its characterization", J. Appl. Polym. Sci., 64(8), 1517-1523. https://doi.org/10.1002/(sici)1097-4628(19970523)64:8<1517::aid-app9>3.0.co;2-k
  34. Ribeiro, R., Alves, J.L. and Marques, A.T. (2018), "Sustainable composites based on pine resin and flax fiber", Proceedings of the 3rd International Conference on Natural Fibers, Braga, Portugal, June.
  35. Sharma, L. and Singh, C. (2016), "Composite film developed from the blends of sesame protein isolate and gum rosin and their properties thereof", Polym. Compos., 39(5), 1480-1487. https://doi.org/10.1002/pc.24088
  36. Verma, A., Singh, C., Singh, V.K. and Jain, N. (2019), "Fabrication and characterization of chitosan-coated sisal fiber - Phytagel modified soy protein-based green composite", J. Compos. Mater., 53, 2481-2504. https://doi.org/10.1177/0021998319831748
  37. Vevere, L., Fridrihsone, A., Kirpluks, M. and Cabulis, U. (2020), "A review of wood biomass-based fatty acids and rosin acids use in polymeric materials", Polymers, 12(11), 2706. https://doi.org/10.3390/polym12112706
  38. Wilbon, P.A., Chu, F. and Tang, C. (2012), "Progress in Renewable Polymers from Natural Terpenes, Terpenoids, and Rosin", Macromol. Rapid Commun., 34(1), 8-37. https://doi.org/10.1002/marc.201200513
  39. Wiyono, B., Tachibana, S. and Tinambunan, D. (2006), "Chemical composition of pine resin. Rosin and turpentine oil from west java", J. Forestry Res., 3(1), 7-17. https://doi.org/10.20886/ijfr.2006.3.1.7-17