DOI QR코드

DOI QR Code

과일류의 부위별 잔류농약 함량 비교

Comparison of Pesticide Resideus in Fruits by Part

  • 문경은 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 박명기 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 배호정 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 이정희 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 이유나 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 김정선 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 강충원 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 이진희 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소) ;
  • 최옥경 (경기도보건환경연구원 농수산물검사부 안양농수산물검사소)
  • Moon, Kyeong-Eun (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Park, Myoung-Ki (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Bae, Ho-Jeong (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Lee, Jung-Hee (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Lee, Yu-Na (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Kim, Jung-Sun (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Kang, Choong-Won (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Lee, Jin-Hee (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Choi, Ok-Kyung (Anyang Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment)
  • 투고 : 2022.04.25
  • 심사 : 2022.08.10
  • 발행 : 2022.08.30

초록

본 연구에서는 경기도내 유통매장 및 온라인에서 유통 중인 과일류 18품목과 박과과채류 2품목 114건의 시료를 구입하였다. 과피와 과육을 분리한 후 GC-NPD, GC-ECD, GC-MSMS, LC-MSMS를 이용하여 341종 잔류농약 분석을 진행했다. 과일 전체(과피+과육)를 분석했을 때 48건의 시료에서 검출이 되었고 부적합은 없었으며 0.0025-0.1663 mg/kg의 검출범위를 나타냈다. 과피에서는 85건에서 0.0026-4.7185 mg/kg의 검출범위를 보이며 분리 전과 비교했을 때 높은 검출량을 보였다. 과육에서는 8건의 검출이 있었으며 검출범위는 0.0021-0.0993 mg/kg 로 나타났다. 대부분의 과피에서 농산물의 잔류허용기준 이하의 농약이 검출되었고 키위 과피에서 기준 0.05 mg/kg인 deltamethrin이 0.1020 mg/kg의 검출량을 보였다. 잔류허용기준은 과일 전체에 대한 기준이기 때문에 섭취에 부적합한 것은 아니지만 더욱 안전하고 건강한 과피 섭취를 위해 세척 후 과일 그대로를 섭취할 것을 권장하며 과피와 과육에 대한 지속적인 모니터링이 필요한 것으로 보여진다.

In this study, we tested for pesticide residues in 114 samples representing 20 different types of fruit circulating in Gyeonggido. A total of 341 pesticides were identified via a multi-residue method using GC-NPD, GC-ECD, GC-MSMS, and LC-MSMS. In whole fruit, pesticides were detected in 48 cases, with a concentration range of 0.0025-0.1663 mg/kg. In the peels, pesticides were detected in 85 cases, with a concentration range of 0.0026-4.7185 mg/kg and a higher average concentration than was found in whole fruit. In the pulp, pesticides were detected in 8 cases, with a concentration range of 0.0021-0.0993 mg/kg. In most of the peels, pesticides were detected below MRL. In the kiwi peel, deltamethrin (with an MRL of 0.05 mg/kg) was detected at 0.1020 mg/kg. Since MRLs are applied to whole fruit, these levels are not unsuitable for ingestion. However, washing is recommended before ingestion to promote healthier and safer inclusion of the peel in the diet. Continuous monitoring of the peel and pulp is indicated.

키워드

참고문헌

  1. Sun, J., Chu, Y.F., Wu, X., Liu, R.H., Antioxidant and antiproliferative activities of common fruits, J. Agric. Food Chem., 50, 7449-7454 (2002). https://doi.org/10.1021/jf0207530
  2. Lichtentha, R., Marx, F., Total oxidant scavenging capacities of common european fruit and vegetable juices, J. Agric. Food Chem., 53, 103-110 (2005). https://doi.org/10.1021/jf0307550
  3. Kubola, J., Siriamornpun, S., Phytochemicals and antioxidant activity of different fruit fractions (peel, pulp, aril, and seed) of Thai gac (Momordica cochinchinensis Spreng), Food Chem., 127, 1138-1145 (2011). https://doi.org/10.1016/j.foodchem.2011.01.115
  4. Contreras-Calderron, J., Calderon-James, L., Guerra-Hernandez, E., Garcia-Villanova, B., Antioxidant capacity, phenolic content, and vitamin C in pulp, peel, and seed from 24 exotic fruits from Colombia, Food Res. Int., 44, 2047-2053 (2011). https://doi.org/10.1016/j.foodres.2010.11.003
  5. Sandra, C.R.V.L.S., Raquel, P.F.G., Ana, B., Effect of drying temperatures on the phenolic composition and antioxidant activity of pears of Rocha variety (Pyrus communis L.), J. Food Meas. Charact., 8, 105-112 (2014). https://doi.org/10.1007/s11694-014-9170-y
  6. Cha, J.Y., Kim, S.Y., Jeong, S.J., Cho, Y.S., Effects of hesperetin and naringenin on lipid concentration in orotic acid treated mice, J. Life Sci., 9, 389-394 (1999).
  7. Lim, D.K., Choi, U., Shin, D.H., Antioxidative activity of ethanol extract from Korean medicinal plants, Korean J. Food Sci. Technol., 28, 83-89 (1996).
  8. Lee, M.Y., Yoo, M.S., Whang, Y.J., Jin, Y.J., Hong, M.H., Pyo, Y.H., Vitamin C, total polyphenol, flavonoid contents and antioxidant capacity of several fruit peels, Korean J. Food Sci. Technol., 44, 540-544 (2012). https://doi.org/10.9721/KJFST.2012.44.5.540
  9. Lee, M.H., Kang, S.M., The antioxidation effect of passiflora edulis f. edulis rind extract and its influence on cell bioactivity, J. Invest Cosmetol., 14, 429-439 (2018).
  10. Lee, S.H., Lee, M.S., The study of antioxidant and antimicrobial effects on the skin extracts of citrus junos, poncirus trifoliata, Jeju citrus, J. Kor. Soc. B&A, 18, 127-140 (2017).
  11. Kim, Y.H., Anticancer, antioxidative and antiinflammatory activity of extraction from persimmon (Diospyros kaki Thunb cv. ojongsi) fresh pulp, Fresh and dried peel, MA thesis, Pusan National University, Korea (2012).
  12. Kim, I.R., Anti-oxidant and anti-inflammatory activities of peach peel extract, Korean J. Food Sci. Technol., 37, 127-133 (2021).
  13. Koh, D.Y., Choi, S.H., Ku, K.M., Effects of antioxidant and antiobesity activities through the additional consumption of peel from pre-washed apple, Korean J. Hortic. Sci., 38, 224-225 (2020).
  14. Lee, H.J., Physicochemical quality characteristics of sprouted brown rice dasik added pear peel, MA thesis, Sejong University, Korea (2017).
  15. Lim, H.S., Cha, G.H., Quality characteristics of cookies with persimmon peel powder, Korean J. Food Sci. Technol., 30, 620-630 (2014).
  16. Zhang, Y.Y., Song, K.Y., O, H.B., Joung, K.Y., Shin, S.Y., Kim, Y.S., Effect of pomegranate (Punica granatum L.) peel powder on the quality characteristics, retrogradation and antioxidant activities of sponge cake, Korean J. Food & Nutr., 30, 578-590 (2017).
  17. Fenik, J., Tankiewicz, M., Biziuk, M., Properties and determination of pesticides in fruits and vegetables, Trends Anal. Chem., 30, 814-826 (2011). https://doi.org/10.1016/j.trac.2011.02.008
  18. Lee, J.Y., Choe, W.J., Lee, H.J., Shin, Y.W., Do, J.A., Kim, W.S., Choi, D.M., Chae. K.R., Kang, C.S., Research on pesticides residue in commercial agricultural products in 2009, J. Food Hyg. Saf., 25, 192-202 (2010).
  19. Kim, J.B., Song, B.H., Chun, J.C., Im, G.J., Im, Y.B., Effect of sprayable formulations on pesticide adhesion and persistence in several crops, Korean. J. Pestic. Sci., 1, 35-40 (1997).
  20. Yang, Y.S., Seo, J.M., Kim, J.P., Oh, M.S., Chung, J.K., Kim, E.S., A survey on pesticide residues of imported agricultural products circulated in Gwangju, J. Food Hyg. Saf., 21, 52-59 (2006).
  21. Elena, D., Assunta, Z., Alessandra, T.Z., Caterina, L.R., Maurizio, B., Lc/Esi/Ms/Ms determination of postharvest fungicide residues in citrus juices, LWT-Food Sci. Technol., 43, 1301-1306 (2010). https://doi.org/10.1016/j.lwt.2010.04.010
  22. Annual report national agricultural products quality management service 2019 (2020).
  23. Choi, S.J., Monitoring and risk assessment of pesticide residues in vegetables in jeonam province of Korea, ma thesis, The Graduate School Sunchon National University, Korea (2021).
  24. Woo, H.D., Lee, J.K., Han, G.D., Consumer awareness survey on safety management of pesticide residue, Food Sci. Nutr., 43, 24-40 (2010).
  25. Chung, S.J., Kim, H.Y., Kim, J.H., Yeom, M.S., Cho, J.H., Lee, S.Y., Monitoring of pesticide residues and risk assessment in some fruits on the market in Incheon, Korea, Korean J. Environ. Agric., 33, 111-120 (2014). https://doi.org/10.5338/KJEA.2014.33.2.111
  26. An, J.M., Chang, S.Y., Lim, H.J., Park, J.O., Kim, I.S., Hwang, H.R., Park, D.H., Kim, I.R., Kang, M.G., Reduction of pesticide residues in Korean melon after washing and peeling, Korean J. Pestic. Sci., 24, 51-62 (2020) https://doi.org/10.7585/kjps.2020.24.1.51
  27. Kim, D.W., Jin, S.H., Lee, J.M., Kim, S.M., Kim, Y.R., Park, J.T., Ko, K.H., Ha, W.W., Kim, D.S., Monitoring of pesticide residues in immature citrus fruits and the characteristics by processing methods, Korean J. Pestic. Sci., 22, 300-315 (2018). https://doi.org/10.7585/kjps.2018.22.4.300
  28. Ministry of food and drug safety (2021) Food Code.
  29. National institute of food and drug safety evaluation (NIFDS) (2016). Guidelines on standard procedures for preparing analysis method.
  30. Report of geonggi province institute of health and envionment, 2003. Removal efficiencies of residual pesticides by different washing in agriculture products, Suwon, Korea.
  31. Lee, H.D., Kyung, K.S., Kwon, H.Y., Ihm, Y.B., Kim, J.B., Park, S.S., Kim J.E., Residue characteristics of hexaconazole and chlorothalonil in several fruits, Korean. J. Pestic. Sci., 8, 107-111 (2004).
  32. Cho, Y.S., Kang, J.B., Kim, Y.H., Jeong, J.A., Huh, J.W., Lee, S.H., Lim, Y.S., Bae, H.J., Kang, H.G., Lee, J.H., Jung, E.S., Lee, B.H., Park, Y.B., Lee, J.B., A survey on pesticide residues of imported fruits circulated in Gyeonggido, Korean. J. Pestic. Sci., 16, 195-201 (2012). https://doi.org/10.7585/kjps.2012.16.3.195
  33. Report of Seoul Institute of Health and Envionment, 2015. Monitoring of pesticide residues in peel, fruit and pulp of tropical, citrus, and pome fruits, Seoul, Korea.
  34. Seok, D.R., Residue and penetration patterns of the fungicides, azoxystrobin and chlorothalonil in apples, MA thesis, Kyungpook National University, Korea (2014).
  35. Li, Y., Jiao, B., Zhao, Q., Wang, C., Gong, Y., Zhang, Y., Chen, W., Effect of commercial processing on pesticide residues in orange products, Eur. Food Res. Technol., 234, 449-456 (2012). https://doi.org/10.1007/s00217-011-1651-1
  36. Report of busan institute of health and environment, 2004. Study on the removal efficiency of pesticide residues in fruits and vegetables at home, Busan, Korea.