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Influence of Inductively Coupled Oxygen Plasma on the Surface of Poly(ether sulfone)

  • Lee, Do Kyung (School of Advanced Materials Science and Chemical Engineering, Daegu Catholic University) ;
  • Sohn, Young-Soo (Department of Biomedical Engineering, Daegu Catholic University)
  • Received : 2022.06.30
  • Accepted : 2022.07.24
  • Published : 2022.07.31

Abstract

The effect of inductively coupled plasma (ICP) treatment with O2 gas on the surface properties of poly(ether sulfone) (PES) was investigated. X-ray photoelectron spectroscopy (XPS) was used to analyze the chemical characteristics of the O2 plasma-treated PES films. The surface roughness of the pristine and O2 plasma-treated PES films for different RF powers of the ICP was determined using an atomic force microscope (AFM). The contact angles of the PES films were also measured, using which the surface free energies were calculated. The O1s XPS spectra of the PES films revealed that the number of polar functional groups increased following the O2 plasma treatment. The AFM analysis showed the average surface roughness increased from 1.01 to 4.48 nm as the RF power of the ICP was increased. The contact angle measurements revealed that the PES films became more hydrophilic as the RF power of the ICP was increased. The total surface energy increased with the RF power of the ICP, resulting from the increased polar energy component.

Keywords

Acknowledgement

This work was supported by research grants from Daegu Catholic University in 2021.

References

  1. K. E. Cheon, D. Y. Lee, Y. R. Cho, P. K. Song, and G. H. Lee, "Effect of Sputtering Conditions on the Mechanical Property and the Permeability of IZO Grown by DC Magnetron Sputtering for Application to Flexible OLEDs", J. Korean Phys. Soc., Vol. 53, No. 1, pp. 396-401, 2008. https://doi.org/10.3938/jkps.53.396
  2. J. Li, L. Hu, J. Liu, L. Wang, T. J. Marks, and G. Gruner, "Indium tin oxide modified transparent nanotube thin films as effective anodes for flexible organic light-emitting diodes", Appl. Phys. Lett.., Vol. 93, No. 8, pp. 083306(1)-083306(12), 2008.
  3. D. C. Han, Y. C. Choi, H. J. Shin, S. Son, J. H. Kim, S. H. Sohn, and D. K. Lee, "Surface modification of poly(ethylene terephthalate) polymeric films by inductively coupled oxygen plasma", Mol. Cryst. Liq. Cryst., Vol. 532, No. 1, pp. 148-155, 2010.
  4. D. C. Han, Y. C. Choi, H. J. Shin, G. Kwak, K.-S. Ahn, J. H. Kim, and D. K. Lee, "Surface properties of poly(ethylene terephthalate) films modified by inductively coupled plasma with Ar/N2 mixture gases", Mol. Cryst. Liq. Cryst., Vol. 539, No.1, pp. 210-217, 2011.
  5. N. T. Vo, P. J. Yoo, G.-R. Yi, M. Schroeder, and D. Kim, "Transparent poly(ether sulfone) nanocomposite film with low thermal expansion coefficient for flexible display substrates", Compos. B Eng., Vol. 224, pp. 109164(1)-109164(12), 2021.
  6. L. Wang, T. Gong, W. Ming, X. Qiao, W. Ye, L. Zhang, and C. J. Pan, "One step preparation of multifunctional poly (ether sulfone) thin films with potential for wound dressing", Biomater. Adv., Vol. 136, pp. 212758(1)-109164(11), 2022.
  7. J. S. Eom and S. H. Kim, "Plasma surface treatment of polyimide for adhesive Cu/80Si20Cr/PI flexible copper clad laminate", J. Thin Solid Films, Vol. 516, No. 14, pp. 4530-4534, 2008. https://doi.org/10.1016/j.tsf.2008.01.022
  8. G. Primc, D. Lojen, A. Vesel, M. Mozetic, and R. Zaplotnik, "Oxygen atom density in a large reactor powered by four inductively coupled plasma sources", Vacuum, Vol. 199, pp. 110964(1)-110964(7), 2022.
  9. A. Rudawska and E. Jacniacka, "Analysis for determining surface free energy uncertainty by the Owen-Wendt method", Int. J. Adhes. Adhes., Vol. 29, No. 4, pp. 451-457, 2009. https://doi.org/10.1016/j.ijadhadh.2008.09.008
  10. R. N. Wenzel, "Resistance of solid surfaces to wetting by water", Ind. Eng. Chem., Vol. 28, No. 8, pp. 988-992, 1936. https://doi.org/10.1021/ie50320a024
  11. https://en.wikipedia.org/wiki/Contact_angle (retrieved on June. 17, 2022).
  12. C. Y. Tong, Y. S. Chang, B. S. Ooi, and D. J. C. Chan, "Physico-chemistry and adhesion kinetics of algal biofilm on polyethersulfone (PES) membrane with different surface wettability", J. Environ. Chem. Eng., Vol. 9, No. 6, pp. 106531(1)-106531(14), 2021.
  13. https://www.brighton-science.com/blog/what-is-the-difference-between-surface-free-energy-and-surface-energy (retrieved on June. 18, 2022).
  14. I. Mrsic, T. Bauerle, S. Ulitzsch, G. Lorenz, K. Rebner, A. Kandelbauer, and T. Chasse, "Oxygen plasma surface treatment of polymer films-Pellethane 55DE and EPR-gVTMS", Appl. Surf. Sci., Vol. 536, pp. 147782(1)- 147782(11), 2021. https://doi.org/10.1016/j.apsusc.2020.147782