DOI QR코드

DOI QR Code

Mineralogical-geochemical Characteristics of Manganese Nodules in the Deep Subseafloor Sediments at Site U1371 in the Western South Pacific Gyre Area

남서태평양 환류지역 U1371 심부퇴적층에서 발견된 망가니즈단괴의 광물학적-지화학적 특성 연구

  • Yang, Kiho (Department of Oceanography, College of Natural Sciences, Pusan National University) ;
  • Jung, Jaewoo (Global Ocean Research Center, Korea Institute of Ocean Science & Technology)
  • 양기호 (부산대학교 자연과학대학 해양학과) ;
  • 정재우 (한국해양과학기술원 대양자원연구센터)
  • Received : 2022.04.17
  • Accepted : 2022.05.30
  • Published : 2022.06.30

Abstract

Manganese nodules were recovered within the deep subseafloor sediments (118.22 mbsf) at Site U1371 during International Ocean Discovery Program (IODP) expedition 329 from the South Pacific Gyre (SPG). Because most manganese nodules exist on the seabed surface, nodules present in deep sediments are uncommon. Therefore, the growth origin of manganese nodules was identified through mineralogical and geochemical analyses. The manganese nodule was divided into the concentric layer outside the manganese region and the inner part of the phosphatized region consisting of manganese oxide minerals and carbonate fluorapatite (CFA) minerals, respectively. The two-dimensional element distribution analysis of Mn, Co, Ni, Sr and Cu, Zn with low Mn/Fe ratio confirmed that manganese nodules were formed predominantly by a hydrogenetic process and a biogenic process in certain manganese layers. As a result, the manganese nodule was continuously precipitated in SPG environments of oligotrophic open paleoocean conditions and rapidly buried with siliceous ooze sediments when the SPG changed to a eutrophic environment. It has been confirmed that manganese nodules found within deep subseafloor sediments could be used as a new proxy for the reconstruction of paleooceanographic conditions.

Keywords

Acknowledgement

본 연구는 2020학년도 부산대학교 교내학술연구비(신임교수연구정착금)와 2020학년도 부산대학교 BK21 FOUR 대학원 혁신지원사업 지원과 한국해양과학기술원에서 수행중인 서태평양 공해/심해저 신 생명자원 및 퇴적물 희유금속 자원 탐사(PEA0024)사업 지원으로 이루어졌음. 본 논문의 발전을 위해 세심한 검토와 아낌없는 조언을 해주신 편집위원과 익명의 심사위원분들께 깊은 감사 드립니다.

References

  1. Banerjee R, Iyer SD, Dutta P (1991) Buried nodules and associated sediments from the central Indian basin. Geo-Mar Lett 11(2):103-107 https://doi.org/10.1007/BF02431037
  2. Cronan DS, Tooms JS (1967) Sub-surface concentrations of manganese nodules in Pacific sediments. Deep-Sea Res 14(1):117-119
  3. D'Hondt S, Inagaki F, Alvarez Zarikian CA, Scientists (2011) South Pacific Gyre Subseafloor life. In: Proceedings of the integrated ocean drilling program, Papeete, 9 Oct-13 Dec 2010
  4. Glasby G, Emelyanov E, Zhamoida V, Baturin G, Leipe T, Bahlo R, Bonacker P (1997) Environments of formation of ferromanganese concretions in the Baltic Sea: a critical review. Geol Soc London 119:213-237 https://doi.org/10.1144/GSL.SP.1997.119.01.14
  5. Halbach P, Segl M, Puteanus D Mangini A (1983) Co-fluxes and growth rates in ferromanganese deposits form Central Pacific seamount areas. Nature 304:716-719 https://doi.org/10.1038/304716a0
  6. Hein JR, Koschinsky A (2014) Deep-ocean ferromanganese crust and Nodules. In: Holland H, Turekian K (eds) Earth systems and environmental sciences, Treatise on geochemistry. Elsevier, Amsterdam, pp 273-291
  7. Hein JR, Koschinsky A, Bau M, Manheim FT, Kang JK, Roberts L (2000) Cobalt-rich ferromanganese crusts in the Pacific. In: Cronan DS (ed) Handbook of marine mineral deposits, CRC Press, Boca Raton, Florida, pp 239-279
  8. Hein JR, Mizell K, Koschinsky A, Conrad TA (2013) Deep-ocean mineral deposits as a source of critical metals for high- and green-technology applications: comparison with land-based resources. Ore Geol Rev 51:1-14 https://doi.org/10.1016/j.oregeorev.2012.12.001
  9. Hein JR,Konstantinova N, Mikesell M, Mizell K, Fitzsimmons JN, Lam PJ, Jensen LT, Xiang Y, Gartman A, Cherkashov G, Hutchinson DR, Till CP (2017) Arctic deep water ferromanganese-oxide deposits reflect the unique characteristics of the Arctic Ocean. Geochem Geophy Geosy 18:3771-3800 https://doi.org/10.1002/2017GC007186
  10. Heller C, Kuhn T, Versteegh GJM, Wegorzewski AV, Kasten S (2018) The geochemical behavior of metals during early diagenetic alteration of buried manganese nodules: deep sea research. Ocean Res Pap 142:16-33 https://doi.org/10.1016/j.dsr.2018.09.008
  11. Heye D, Marchig V, Meyer H (1979) The growth of buried manganese nodules: deep sea research part A. Ocean Res Pap 26(7):789-798
  12. Ito T, Komuro K (2006) Paleoceanographic setting and preservation of buried manganese deposits in DSDP/ODP cores. Resour Geol 56(4):457-470 https://doi.org/10.1111/j.1751-3928.2006.tb00298.x
  13. Jiang XD, Gong JL, Ren JB, Liu QS, Zhang J, Chou YM (2020) An interdependent relationship between microbial ecosystems and ferromanganese nodules from the Western Pacific Ocean. Sediment Geol 398:105588 https://doi.org/10.1016/j.sedgeo.2019.105588
  14. Mel'nikov ME, Avdonin VV, Pletnev SP, Sedysheva TE (2016) Buried ferromanganese nodules of the Magellan Seamounts. Lithol Miner Resour 51(1):1-12 https://doi.org/10.1134/s0024490215060073
  15. Mizell K, Hein JR (2016) Ferromanganese crusts and nodules, rocks that grow. In: White WM (ed) Encyclopedia of geochemistry. Encyclopedia of earth sciences series. Springer, Cham, pp 1-7
  16. Pattan JN, Parthiban G (2007) Do manganese nodules grow or dissolve after burial? Results from the Central Indian Ocean Basin. J Asian Earth Sci 30(5):696-705 https://doi.org/10.1016/j.jseaes.2007.03.003
  17. Sample JC, Reid MR, Tols HJ, Moore JC (1993) Carbonate cements indicate channeled fluid flow along a zone of vertical faults at the deformation front of the Cascadia accretionary wedge (northwest US coast). Geology 21:507-510 https://doi.org/10.1130/0091-7613(1993)021<0507:CCICFF>2.3.CO;2
  18. Shiraishi F, Mitsunobu S, Suzuki K, Hoshino T, Morono Y, Inagaki F (2016) Dense microbial community on a ferromanganese nodule from the ultra-oligotrophic South Pacific Gyre: implications for biogeochemical cycles. Earth Planet Sci Lett 447:10-20 https://doi.org/10.1016/j.epsl.2016.04.021
  19. Usui A, Ito T (1994) Fossil manganese deposits buried within DSDP/ODP cores, legs 1-126. Mar Geol 119(1):111-136 https://doi.org/10.1016/0025-3227(94)90144-9
  20. Usui A, Nishimura A, Mita N (1993) Composition and growth history of surficial and buried manganese nodules in the Penrhyn Basin, Southwestern Pacific. Mar Geol 114(1):133-153 https://doi.org/10.1016/0025-3227(93)90044-V
  21. Verlaan PA, Cronan DS, Morgan CL (2004) A comparative analysis of compositional variations in and between marine ferromanganese nodules and crusts in the South Pacific and their environmental controls. Prog Oceanogr 63(3):125-158 https://doi.org/10.1016/j.pocean.2004.11.001