청정기술 (Clean Technology)

  • 제28권2호
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  • Pages.97-102
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  • 2022
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  • 1598-9712(pISSN)
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  • 2288-0690(eISSN)
한국청정기술학회 (The Korean Society of Clean Technology)
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Biomass-Derived Three-Dimensionally Connected Hierarchical Porous Carbon Framework for Long-Life Lithium-Sulfur Batteries

  • Liu, Ying (Department of Chemical Engineering, Gyeongsang National University) ;
  • Lee, Dong Jun (Department of Chemical Engineering, Gyeongsang National University) ;
  • Lee, Younki (Department of Materials Engineering and Convergence Technology, Gyeongsang National University) ;
  • Raghavan, Prasanth (Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology) ;
  • Yang, Rong (International Research Center for Composite and Intelligent Manufacturing Technology, Institute of Chemical Power Sources, Xi'an University of Technology) ;
  • Ramawati, Fitria (Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University) ;
  • Ahn, Jou-Hyeon (Department of Chemical Engineering, Gyeongsang National University)
  • 투고 : 2022.02.24
  • 심사 : 2022.04.01
  • 발행 : 2022.06.30
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초록

Lithium sulfur (Li-S) batteries have attracted considerable attention as a promising candidate for next-generation power sources due to their high theoretical energy density, low cost, and eco-friendliness. However, the poor electrical conductivity of sulfur and its insoluble discharging products (Li2S2/Li2S), large volume changes, severe self-discharge, and dissolution of lithium polysulfide intermediates result in rapid capacity fading, low Coulombic efficiency, and safety risks, hindering Li-S battery commercial development. In this study, a three-dimensionally (3D) connected hierarchical porous carbon framework (HPCF) derived from waste sunflower seed shells was synthesized as a sulfur host for Li-S batteries via a chemical activation method. The natural 3D connected structure of the HPCF, originating from the raw material, can effectively enhance the conductivity and accessibility of the electrolyte, accelerating the Li+/electron transfer. Additionally, the generated micropores of the HPCF, originated from the chemical activation process, can prevent polysulfide dissolution due to the limited space, thereby improving the electrochemical performance and cycling stability. The HPCF/S cell shows a superior capacity retention of 540 mA h g-1 after 70 cycles at 0.1 C, and an excellent cycling stability at 2 C for 700 cycles. This study provides a potential biomass-derived material for low-cost long-life Li-S batteries.

키워드

과제정보

This work was supported by the 2019 Gyeongsang National University Global Research Network Fund.

참고문헌

  1. Tao, X., Wang, J., Liu, C., Wang, H., Yao, H., Zheng, G., Swh, Z. W., Cai, Q., Li, W., Zhou, G., Zu, C., and Cui, Y., "Balancing surface adsorption and diffusion of lithiumpolysulfides on nonconductive oxides for lithium-sulfur battery design," Nat. Commun., 7, 11203 (2016). https://doi.org/10.1038/ncomms11203
  2. Armand, M., and Tarascon, J. M., "Building better batteries," Nature, 451, 652-657 (2008). https://doi.org/10.1038/451652a
  3. Carter, R., Oakes, L., Muralidharan, N., Cohn, A. P., Douglas, A., and Pint, C. L., "Polysulfide anchoring mechanism revealed by atomic layer deposition of V2O5 and sulfur-filled carbon nanotubes for lithium-sulfur batteries," ACS Appl. Mater. Interfaces, 9, 7185-7192 (2017). https://doi.org/10.1021/acsami.6b16155
  4. Jayaprakash, N., Shen, J., Moganty, S. S., Corona, A., and Archer, L. A., "Porous hollow carbon @sulfur composites for high-power lithium-sulfur batteries," Angew. Chem. Int. Ed., 50, 5904-5908 (2011). https://doi.org/10.1002/anie.201100637
  5. She, Z.W., Li, W., Cha, J.J., Zheng, G., Yang, Y., Mcdowell, M. T., Hsu, P. C., and Cui, Y., "Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries," Nat. Commun., 4, 1331-1336 (2013). https://doi.org/10.1038/ncomms2327
  6. He, Y., Chang, Z., Wu, S., and Zhou, H., "Effective strategies for long-cycle life lithium-sulfur batteries," J. Mater. Chem. A, 6, 6155-6182 (2018). https://doi.org/10.1039/C8TA01115J
  7. Liu, Y., Zhao, X., Chauhan, G. S., and Ahn, J. H., "Nanostructured nitrogen-doped mesoporous carbon derived from polyacrylonitrile for advanced lithium sulfur batteries," Appl. Surf. Sci., 380, 151-158 (2016). https://doi.org/10.1016/j.apsusc.2016.01.261
  8. Yang, D., Zhou, H., Liu, H., and Han, B., "Hollow N-doped carbon polyhedrons with hierarchically porous shell for confinement of polysulfides in lithium-sulfur batteries," iScience, 13, 243-253 (2019). https://doi.org/10.1016/j.isci.2019.02.019
  9. Gao, X., Huang, Y., Gao, H., Batool, S., Lu, M., Li, X., and Zhang, Y., "Sulfur double encapsulated in a porous hollow carbon aerogel with interconnected micropores for advanced lithium-sulfur batteries," J. Alloy. Compd., 834, 155190 (2020). https://doi.org/10.1016/j.jallcom.2020.155190
  10. Li, X., Cheng, X., Gao, M., Ren, D., Liu, Y., Guo, Z., Shang, C., Sun, L., and Pan, H., "Amylose-derived macrohollow core and microporous shell carbon spheres as sulfur host for superior lithium-sulfur battery cathodes," ACS Appl. Mater. Inter., 9, 10717-10729 (2017). https://doi.org/10.1021/acsami.7b00672
  11. Yang, R., Liu, S., Liu, Y., Liu, L., Chen, L., Yu, W., Yan, Y., Feng, Z., and Xu, Y., "Decalcified fish scale-based sponge-like nitrogen-doped porous carbon for lithium-sulfur batteries," Ionics, 27, 165-174 (2021). https://doi.org/10.1007/s11581-020-03798-w
  12. Lee, S.Y., Choi, Y., Kim, J. K., Lee, S. J., Bae, J. S., and Jeong, E. D., "Biomass-garlic-peel-derived porous carbon framework as a sulfur host for lithium-sulfur batteries," J. Ind. Eng. Chem., 94, 272-281 (2021). https://doi.org/10.1016/j.jiec.2020.10.046
  13. Xue, M., Lu, W., Chen, C., Tan, Y., Li, B., and Zhang, C., "Optimized synthesis of banana peel derived porous carbon and its application in lithium sulfur batteries," Mater. Res. Bull., 112, 269-280 (2019). https://doi.org/10.1016/j.materresbull.2018.12.035
  14. Shaukat, R. A., Saqib, Q. M., Khan, M. U., Chougale, M. Y., and Bae, J., "Bio-waste sunflower husks powder based recycled triboelectric nanogenerator for energy harvesting," Energy Rep., 7, 724-731 (2021). https://doi.org/10.1016/j.egyr.2021.01.036
  15. Cubitto, M. A., and Gentili, A. R., "Bioremediation of crude oil-contaminated soil by immobilized bacteria on an agroindustrial waste-sunflower seed husks," Bioremediat. J., 19, 277-286 (2015). https://doi.org/10.1080/10889868.2014.995376
  16. Liu, Y., Li, X., Sun, Y., Yang, R., Lee, Y., and Ahn, J. H., "Macro-microporous carbon with a three-dimensional channel skeleton derived from waste sunflower seed shells for sustainable room-temperature sodium sulfur batteries," J. Alloy. Compd., 853, 157316 (2021). https://doi.org/10.1016/j.jallcom.2020.157316
  17. Liu, Y., Li, X., Sun, Y., Yang, R., Lee, Y., and Ahn, J. H., "Dual-porosity carbon derived from waste bamboo char for room-temperature sodium-sulfur batteries using carbonate-based electrolyte," Ionics, 27, 199-206 (2021). https://doi.org/10.1007/s11581-020-03801-4
  18. Zhou, J., Guo, Y., Liang, C., Yang, J., Wang, J., and Nuli, Y., "Confining small sulfur molecules in peanut shell-derived microporous graphitic carbon for advanced lithium sulfur battery," Electrochim. Acta, 273, 127-135 (2018). https://doi.org/10.1016/j.electacta.2018.04.021
  19. Li, Z., Yuan, L., Yi, Z., Sun, Y., Liu, Y., Jiang, Y., Shen, Y., Xin, Y., Zhang, Z., and Huang, Y., "Insight into the electrode mechanism in lithium-sulfur batteries with ordered microporous carbon confined sulfur as the cathode," Adv. Energy Mater., 4, 1301473 (2014). https://doi.org/10.1002/aenm.201301473
  20. Liu, Y., Li, X., Sun, Y., Heo, J., Lee, Y., Lim, D. H., Ahn, H. J., Cho, K. K., Yang, R., and Ahn, J. H., "Porous graphitic carbon derived from biomass for advanced lithium sulfur batteries," Sci. Adv. Mater., 12, 1627-1633 (2020).